Ring opening polymerization of macrocyclic oligoesters derived from renewable sources
Macrocyclic oligoesters (MCOs) derived from biomass such as those prepared from alkylene alkanedioates and 2,5-furandicarboxylates are suitable compounds for ring opening polymerization (ROP) to produce high molecular weight bio-based polyesters. The synthetic procedures that have been recently deve...
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Online Access: | http://hdl.handle.net/2117/331103 https://doi.org/10.1039/C9PY01927H |
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ftupcatalunyair:oai:upcommons.upc.edu:2117/331103 2024-09-15T17:47:46+00:00 Ring opening polymerization of macrocyclic oligoesters derived from renewable sources Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon Muñoz Guerra, Sebastián Universitat Politècnica de Catalunya. Departament d'Enginyeria Química Universitat Politècnica de Catalunya. POL - Polímers Industrials Avançats i Biopolímers Tecnològics 2020-03-17 11 p. application/pdf http://hdl.handle.net/2117/331103 https://doi.org/10.1039/C9PY01927H eng eng https://pubs-rsc-org.recursos.biblioteca.upc.edu/en/content/articlelanding/2020/py/d0py00258e#!divAbstract Martinez de Ilarduya, A.; Muñoz, S. Ring opening polymerization of macrocyclic oligoesters derived from renewable sources. "Polymer chemistry", 17 Març 2020, vol. 11, núm. 30, p. 4850-4860. 1759-9954 http://hdl.handle.net/2117/331103 doi:10.1039/C9PY01927H Attribution-NonCommercial-NoDerivs 3.0 Spain http://creativecommons.org/licenses/by-nc-nd/3.0/es/ Open Access Àrees temàtiques de la UPC::Enginyeria química Ring opening polymerization Macrocyclic oligoesters Macrolactones Entropically driven ROP Cyclodepolymerization Circular economy Polímers -- Reciclatge Plàstics Article 2020 ftupcatalunyair https://doi.org/10.1039/C9PY01927H 2024-07-25T10:59:38Z Macrocyclic oligoesters (MCOs) derived from biomass such as those prepared from alkylene alkanedioates and 2,5-furandicarboxylates are suitable compounds for ring opening polymerization (ROP) to produce high molecular weight bio-based polyesters. The synthetic procedures that have been recently developed to obtain these MCOs in good yields, their ROP either alone or together with other cyclic compounds, and their recovery by cyclodepolymerization of the final polyesters are the main topics covered in this review. Both organometallic compounds and enzymes such as Candida antarctica lipase B are the catalytic systems used for all reactions. This synthetic approach based on ROP of MCOs derived from renewable sources opens a green pathway for a circular economy in plastics. Postprint (author's final draft) Article in Journal/Newspaper Antarc* Antarctica Universitat Politècnica de Catalunya, BarcelonaTech: UPCommons - Global access to UPC knowledge Polymer Chemistry 11 30 4830 4849 |
institution |
Open Polar |
collection |
Universitat Politècnica de Catalunya, BarcelonaTech: UPCommons - Global access to UPC knowledge |
op_collection_id |
ftupcatalunyair |
language |
English |
topic |
Àrees temàtiques de la UPC::Enginyeria química Ring opening polymerization Macrocyclic oligoesters Macrolactones Entropically driven ROP Cyclodepolymerization Circular economy Polímers -- Reciclatge Plàstics |
spellingShingle |
Àrees temàtiques de la UPC::Enginyeria química Ring opening polymerization Macrocyclic oligoesters Macrolactones Entropically driven ROP Cyclodepolymerization Circular economy Polímers -- Reciclatge Plàstics Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon Muñoz Guerra, Sebastián Ring opening polymerization of macrocyclic oligoesters derived from renewable sources |
topic_facet |
Àrees temàtiques de la UPC::Enginyeria química Ring opening polymerization Macrocyclic oligoesters Macrolactones Entropically driven ROP Cyclodepolymerization Circular economy Polímers -- Reciclatge Plàstics |
description |
Macrocyclic oligoesters (MCOs) derived from biomass such as those prepared from alkylene alkanedioates and 2,5-furandicarboxylates are suitable compounds for ring opening polymerization (ROP) to produce high molecular weight bio-based polyesters. The synthetic procedures that have been recently developed to obtain these MCOs in good yields, their ROP either alone or together with other cyclic compounds, and their recovery by cyclodepolymerization of the final polyesters are the main topics covered in this review. Both organometallic compounds and enzymes such as Candida antarctica lipase B are the catalytic systems used for all reactions. This synthetic approach based on ROP of MCOs derived from renewable sources opens a green pathway for a circular economy in plastics. Postprint (author's final draft) |
author2 |
Universitat Politècnica de Catalunya. Departament d'Enginyeria Química Universitat Politècnica de Catalunya. POL - Polímers Industrials Avançats i Biopolímers Tecnològics |
format |
Article in Journal/Newspaper |
author |
Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon Muñoz Guerra, Sebastián |
author_facet |
Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon Muñoz Guerra, Sebastián |
author_sort |
Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon |
title |
Ring opening polymerization of macrocyclic oligoesters derived from renewable sources |
title_short |
Ring opening polymerization of macrocyclic oligoesters derived from renewable sources |
title_full |
Ring opening polymerization of macrocyclic oligoesters derived from renewable sources |
title_fullStr |
Ring opening polymerization of macrocyclic oligoesters derived from renewable sources |
title_full_unstemmed |
Ring opening polymerization of macrocyclic oligoesters derived from renewable sources |
title_sort |
ring opening polymerization of macrocyclic oligoesters derived from renewable sources |
publishDate |
2020 |
url |
http://hdl.handle.net/2117/331103 https://doi.org/10.1039/C9PY01927H |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_relation |
https://pubs-rsc-org.recursos.biblioteca.upc.edu/en/content/articlelanding/2020/py/d0py00258e#!divAbstract Martinez de Ilarduya, A.; Muñoz, S. Ring opening polymerization of macrocyclic oligoesters derived from renewable sources. "Polymer chemistry", 17 Març 2020, vol. 11, núm. 30, p. 4850-4860. 1759-9954 http://hdl.handle.net/2117/331103 doi:10.1039/C9PY01927H |
op_rights |
Attribution-NonCommercial-NoDerivs 3.0 Spain http://creativecommons.org/licenses/by-nc-nd/3.0/es/ Open Access |
op_doi |
https://doi.org/10.1039/C9PY01927H |
container_title |
Polymer Chemistry |
container_volume |
11 |
container_issue |
30 |
container_start_page |
4830 |
op_container_end_page |
4849 |
_version_ |
1810497316786798592 |