Modelling acid attack of oilwell cement exposed to carbonated brine
A diffusion-reaction model for the carbonation process of oilwell cement exposed to carbonated brine under CO2 geological storage conditions is presented. The formulation consists of two main diffusion/reaction field equations for the concentrations of aqueous calcium and carbon species in the pore...
Published in: | International Journal of Greenhouse Gas Control |
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Language: | English |
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John Gale
2018
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Online Access: | http://hdl.handle.net/2117/114308 https://doi.org/10.1016/j.ijggc.2017.11.015 |
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ftupcatalunyair:oai:upcommons.upc.edu:2117/114308 2024-09-15T18:01:38+00:00 Modelling acid attack of oilwell cement exposed to carbonated brine Liaudat, Joaquín Martínez Estévez, Ariadna López Garello, Carlos María Carol, Ignacio Universitat Politècnica de Catalunya. Departament d'Enginyeria Civil i Ambiental Universitat Politècnica de Catalunya. MECMAT - Mecànica de Materials 2018-01 12 p. application/pdf http://hdl.handle.net/2117/114308 https://doi.org/10.1016/j.ijggc.2017.11.015 eng eng John Gale https://www.sciencedirect.com/science/article/pii/S1750583617302694 Liaudat, J., Martinez, A., Lopez, C., Carol, I. Modelling acid attack of oilwell cement exposed to carbonated brine. "International journal of greenhouse gas control", Gener 2018, vol. 68, p. 191-202. 1750-5836 http://hdl.handle.net/2117/114308 doi:10.1016/j.ijggc.2017.11.015 Attribution-NonCommercial-NoDerivs 3.0 Spain http://creativecommons.org/licenses/by-nc-nd/3.0/es/ Open Access Àrees temàtiques de la UPC::Desenvolupament humà i sostenible::Enginyeria ambiental::Tractament d'emissions i olors Carbon sequestration Carbonation Carbon sequestration Well cementCO2 carbonic acid Chemical model Finite Element Method Anhídrid carbònic -- Aspectes ambientals Article 2018 ftupcatalunyair https://doi.org/10.1016/j.ijggc.2017.11.015 2024-07-25T11:07:44Z A diffusion-reaction model for the carbonation process of oilwell cement exposed to carbonated brine under CO2 geological storage conditions is presented. The formulation consists of two main diffusion/reaction field equations for the concentrations of aqueous calcium and carbon species in the pore solution of the hardened cement paste, complemented by two diffusion-only field equations for chloride and alkalis concentrations, and by a number of chemical kinetics and chemical equilibrium equations. The volume fraction distribution of the solid constituents of the hardened cement paste and the reaction products evolve with the progress of the reaction, determining the diffusivity properties of the material. The model is used to simulate experimental tests performed by Duguid and Scherer (2010), leading to promising results indicating that the fundamental aspects of the phenomenon are captured. Peer Reviewed Postprint (author's final draft) Article in Journal/Newspaper Carbonic acid Universitat Politècnica de Catalunya, BarcelonaTech: UPCommons - Global access to UPC knowledge International Journal of Greenhouse Gas Control 68 191 202 |
institution |
Open Polar |
collection |
Universitat Politècnica de Catalunya, BarcelonaTech: UPCommons - Global access to UPC knowledge |
op_collection_id |
ftupcatalunyair |
language |
English |
topic |
Àrees temàtiques de la UPC::Desenvolupament humà i sostenible::Enginyeria ambiental::Tractament d'emissions i olors Carbon sequestration Carbonation Carbon sequestration Well cementCO2 carbonic acid Chemical model Finite Element Method Anhídrid carbònic -- Aspectes ambientals |
spellingShingle |
Àrees temàtiques de la UPC::Desenvolupament humà i sostenible::Enginyeria ambiental::Tractament d'emissions i olors Carbon sequestration Carbonation Carbon sequestration Well cementCO2 carbonic acid Chemical model Finite Element Method Anhídrid carbònic -- Aspectes ambientals Liaudat, Joaquín Martínez Estévez, Ariadna López Garello, Carlos María Carol, Ignacio Modelling acid attack of oilwell cement exposed to carbonated brine |
topic_facet |
Àrees temàtiques de la UPC::Desenvolupament humà i sostenible::Enginyeria ambiental::Tractament d'emissions i olors Carbon sequestration Carbonation Carbon sequestration Well cementCO2 carbonic acid Chemical model Finite Element Method Anhídrid carbònic -- Aspectes ambientals |
description |
A diffusion-reaction model for the carbonation process of oilwell cement exposed to carbonated brine under CO2 geological storage conditions is presented. The formulation consists of two main diffusion/reaction field equations for the concentrations of aqueous calcium and carbon species in the pore solution of the hardened cement paste, complemented by two diffusion-only field equations for chloride and alkalis concentrations, and by a number of chemical kinetics and chemical equilibrium equations. The volume fraction distribution of the solid constituents of the hardened cement paste and the reaction products evolve with the progress of the reaction, determining the diffusivity properties of the material. The model is used to simulate experimental tests performed by Duguid and Scherer (2010), leading to promising results indicating that the fundamental aspects of the phenomenon are captured. Peer Reviewed Postprint (author's final draft) |
author2 |
Universitat Politècnica de Catalunya. Departament d'Enginyeria Civil i Ambiental Universitat Politècnica de Catalunya. MECMAT - Mecànica de Materials |
format |
Article in Journal/Newspaper |
author |
Liaudat, Joaquín Martínez Estévez, Ariadna López Garello, Carlos María Carol, Ignacio |
author_facet |
Liaudat, Joaquín Martínez Estévez, Ariadna López Garello, Carlos María Carol, Ignacio |
author_sort |
Liaudat, Joaquín |
title |
Modelling acid attack of oilwell cement exposed to carbonated brine |
title_short |
Modelling acid attack of oilwell cement exposed to carbonated brine |
title_full |
Modelling acid attack of oilwell cement exposed to carbonated brine |
title_fullStr |
Modelling acid attack of oilwell cement exposed to carbonated brine |
title_full_unstemmed |
Modelling acid attack of oilwell cement exposed to carbonated brine |
title_sort |
modelling acid attack of oilwell cement exposed to carbonated brine |
publisher |
John Gale |
publishDate |
2018 |
url |
http://hdl.handle.net/2117/114308 https://doi.org/10.1016/j.ijggc.2017.11.015 |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_relation |
https://www.sciencedirect.com/science/article/pii/S1750583617302694 Liaudat, J., Martinez, A., Lopez, C., Carol, I. Modelling acid attack of oilwell cement exposed to carbonated brine. "International journal of greenhouse gas control", Gener 2018, vol. 68, p. 191-202. 1750-5836 http://hdl.handle.net/2117/114308 doi:10.1016/j.ijggc.2017.11.015 |
op_rights |
Attribution-NonCommercial-NoDerivs 3.0 Spain http://creativecommons.org/licenses/by-nc-nd/3.0/es/ Open Access |
op_doi |
https://doi.org/10.1016/j.ijggc.2017.11.015 |
container_title |
International Journal of Greenhouse Gas Control |
container_volume |
68 |
container_start_page |
191 |
op_container_end_page |
202 |
_version_ |
1810438742661398528 |