An intercomparison of total column-averaged nitrous oxide between ground-based FTIR TCCON and NDACC measurements at seven sites and comparisons with the GEOS-Chem model
Nitrous oxide (N 2 O) is an important greenhouse gas and it can also generate nitric oxide, which depletes ozone in the stratosphere. It is a common target species of ground-based Fourier transform infrared (FTIR) nearinfrared (TCCON) and mid-infrared (NDACC) measurements. Both TCCON and NDACC netwo...
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ftunivwollongong:oai:ro.uow.edu.au:smhpapers1-1614 2023-05-15T17:48:28+02:00 An intercomparison of total column-averaged nitrous oxide between ground-based FTIR TCCON and NDACC measurements at seven sites and comparisons with the GEOS-Chem model Zhou, Minqiang Langerock, Bavo Wells, Kelley Millet, Dylan B Vigouroux, C Sha, Mahesh Kumar Hermans, Christian Metzger, J -M Kivi, Rigel Heikkinen, Pauli Smale, D Pollard, David F Jones, Nicholas B Deutscher, Nicholas M Blumenstock, Thomas Schneider, Matthias Palm, Mathias Notholt, Justus Hannigan, James W de Maziere, Martine 2019-01-01T08:00:00Z application/pdf https://ro.uow.edu.au/smhpapers1/600 https://ro.uow.edu.au/cgi/viewcontent.cgi?article=1614&context=smhpapers1 unknown Research Online https://ro.uow.edu.au/smhpapers1/600 https://ro.uow.edu.au/cgi/viewcontent.cgi?article=1614&context=smhpapers1 Faculty of Science, Medicine and Health - Papers: Part B article 2019 ftunivwollongong 2021-08-23T22:25:24Z Nitrous oxide (N 2 O) is an important greenhouse gas and it can also generate nitric oxide, which depletes ozone in the stratosphere. It is a common target species of ground-based Fourier transform infrared (FTIR) nearinfrared (TCCON) and mid-infrared (NDACC) measurements. Both TCCON and NDACC networks provide a longterm global distribution of atmospheric N 2 O mole fraction. In this study, the dry-air column-averaged mole fractions of N 2 O (XN 2 O) from the TCCON and NDACC measurements are compared against each other at seven sites around the world (Ny-Ålesund, Sodankylä, Bremen, Izaña, Réunion, Wollongong, Lauder) in the time period of 2007-2017. The mean differences in XN 2 O between TCCON and NDACC (NDACC-TCCON) at these sites are between -3:32 and 1.37 ppb (-1:1 %-0.5 %) with standard deviations between 1.69 and 5.01 ppb (0.5 %-1.6 %), which are within the uncertainties of the two datasets. The NDACC N 2 O retrieval has good sensitivity throughout the troposphere and stratosphere, while the TCCON retrieval underestimates a deviation from the a priori in the troposphere and overestimates it in the stratosphere. As a result, the TCCON XN 2 O measurement is strongly affected by its a priori profile. Trends and seasonal cycles of XN 2 O are derived from the TCCON and NDACC measurements and the nearby surface flask sample measurements and compared with the results from GEOS-Chem model a priori and a posteriori simulations. The trends and seasonal cycles from FTIR measurement at Ny-Ålesund and Sodankylä are strongly affected by the polar winter and the polar vortex. The a posteriori N 2 O fluxes in the model are optimized based on surface N 2 O measurements with a 4D-Var inversion method. The XN 2 O trends from the GEOS-Chem a posteriori simulation (0:97-0:02 (1) ppb yr-1) are close to those from the NDACC (0:93- 0:04 ppb yr-1) and the surface flask sample measurements (0:93-0:02 ppb yr-1). The XN 2 O trend from the TCCON measurements is slightly lower (0:81-0:04 ppb yr-1) due to the underestimation of the trend in TCCON a priori simulation. The XN 2 O trends from the GEOS-Chem a priori simulation are about 1.25 ppb yr-1, and our study confirms that the N 2 O fluxes from the a priori inventories are overestimated. The seasonal cycles of XN 2 O from the FTIR measurements and the model simulations are close to each other in the Northern Hemisphere with a maximum in August-October and a minimum in February-April. However, in the Southern Hemisphere, the modeled XN 2 O values show a minimum in February-April while the FTIR XN 2 O retrievals show different patterns. By comparing the partial column-averaged N 2 O from the model and NDACC for three vertical ranges (surface-8, 8-17, 17-50 km), we find that the discrepancy in the XN 2 O seasonal cycle between the model simulations and the FTIR measurements in the Southern Hemisphere is mainly due to their stratospheric differences. Article in Journal/Newspaper Ny Ålesund Ny-Ålesund Sodankylä University of Wollongong, Australia: Research Online Ny-Ålesund Sodankylä ENVELOPE(26.600,26.600,67.417,67.417) |
institution |
Open Polar |
collection |
University of Wollongong, Australia: Research Online |
op_collection_id |
ftunivwollongong |
language |
unknown |
description |
Nitrous oxide (N 2 O) is an important greenhouse gas and it can also generate nitric oxide, which depletes ozone in the stratosphere. It is a common target species of ground-based Fourier transform infrared (FTIR) nearinfrared (TCCON) and mid-infrared (NDACC) measurements. Both TCCON and NDACC networks provide a longterm global distribution of atmospheric N 2 O mole fraction. In this study, the dry-air column-averaged mole fractions of N 2 O (XN 2 O) from the TCCON and NDACC measurements are compared against each other at seven sites around the world (Ny-Ålesund, Sodankylä, Bremen, Izaña, Réunion, Wollongong, Lauder) in the time period of 2007-2017. The mean differences in XN 2 O between TCCON and NDACC (NDACC-TCCON) at these sites are between -3:32 and 1.37 ppb (-1:1 %-0.5 %) with standard deviations between 1.69 and 5.01 ppb (0.5 %-1.6 %), which are within the uncertainties of the two datasets. The NDACC N 2 O retrieval has good sensitivity throughout the troposphere and stratosphere, while the TCCON retrieval underestimates a deviation from the a priori in the troposphere and overestimates it in the stratosphere. As a result, the TCCON XN 2 O measurement is strongly affected by its a priori profile. Trends and seasonal cycles of XN 2 O are derived from the TCCON and NDACC measurements and the nearby surface flask sample measurements and compared with the results from GEOS-Chem model a priori and a posteriori simulations. The trends and seasonal cycles from FTIR measurement at Ny-Ålesund and Sodankylä are strongly affected by the polar winter and the polar vortex. The a posteriori N 2 O fluxes in the model are optimized based on surface N 2 O measurements with a 4D-Var inversion method. The XN 2 O trends from the GEOS-Chem a posteriori simulation (0:97-0:02 (1) ppb yr-1) are close to those from the NDACC (0:93- 0:04 ppb yr-1) and the surface flask sample measurements (0:93-0:02 ppb yr-1). The XN 2 O trend from the TCCON measurements is slightly lower (0:81-0:04 ppb yr-1) due to the underestimation of the trend in TCCON a priori simulation. The XN 2 O trends from the GEOS-Chem a priori simulation are about 1.25 ppb yr-1, and our study confirms that the N 2 O fluxes from the a priori inventories are overestimated. The seasonal cycles of XN 2 O from the FTIR measurements and the model simulations are close to each other in the Northern Hemisphere with a maximum in August-October and a minimum in February-April. However, in the Southern Hemisphere, the modeled XN 2 O values show a minimum in February-April while the FTIR XN 2 O retrievals show different patterns. By comparing the partial column-averaged N 2 O from the model and NDACC for three vertical ranges (surface-8, 8-17, 17-50 km), we find that the discrepancy in the XN 2 O seasonal cycle between the model simulations and the FTIR measurements in the Southern Hemisphere is mainly due to their stratospheric differences. |
format |
Article in Journal/Newspaper |
author |
Zhou, Minqiang Langerock, Bavo Wells, Kelley Millet, Dylan B Vigouroux, C Sha, Mahesh Kumar Hermans, Christian Metzger, J -M Kivi, Rigel Heikkinen, Pauli Smale, D Pollard, David F Jones, Nicholas B Deutscher, Nicholas M Blumenstock, Thomas Schneider, Matthias Palm, Mathias Notholt, Justus Hannigan, James W de Maziere, Martine |
spellingShingle |
Zhou, Minqiang Langerock, Bavo Wells, Kelley Millet, Dylan B Vigouroux, C Sha, Mahesh Kumar Hermans, Christian Metzger, J -M Kivi, Rigel Heikkinen, Pauli Smale, D Pollard, David F Jones, Nicholas B Deutscher, Nicholas M Blumenstock, Thomas Schneider, Matthias Palm, Mathias Notholt, Justus Hannigan, James W de Maziere, Martine An intercomparison of total column-averaged nitrous oxide between ground-based FTIR TCCON and NDACC measurements at seven sites and comparisons with the GEOS-Chem model |
author_facet |
Zhou, Minqiang Langerock, Bavo Wells, Kelley Millet, Dylan B Vigouroux, C Sha, Mahesh Kumar Hermans, Christian Metzger, J -M Kivi, Rigel Heikkinen, Pauli Smale, D Pollard, David F Jones, Nicholas B Deutscher, Nicholas M Blumenstock, Thomas Schneider, Matthias Palm, Mathias Notholt, Justus Hannigan, James W de Maziere, Martine |
author_sort |
Zhou, Minqiang |
title |
An intercomparison of total column-averaged nitrous oxide between ground-based FTIR TCCON and NDACC measurements at seven sites and comparisons with the GEOS-Chem model |
title_short |
An intercomparison of total column-averaged nitrous oxide between ground-based FTIR TCCON and NDACC measurements at seven sites and comparisons with the GEOS-Chem model |
title_full |
An intercomparison of total column-averaged nitrous oxide between ground-based FTIR TCCON and NDACC measurements at seven sites and comparisons with the GEOS-Chem model |
title_fullStr |
An intercomparison of total column-averaged nitrous oxide between ground-based FTIR TCCON and NDACC measurements at seven sites and comparisons with the GEOS-Chem model |
title_full_unstemmed |
An intercomparison of total column-averaged nitrous oxide between ground-based FTIR TCCON and NDACC measurements at seven sites and comparisons with the GEOS-Chem model |
title_sort |
intercomparison of total column-averaged nitrous oxide between ground-based ftir tccon and ndacc measurements at seven sites and comparisons with the geos-chem model |
publisher |
Research Online |
publishDate |
2019 |
url |
https://ro.uow.edu.au/smhpapers1/600 https://ro.uow.edu.au/cgi/viewcontent.cgi?article=1614&context=smhpapers1 |
long_lat |
ENVELOPE(26.600,26.600,67.417,67.417) |
geographic |
Ny-Ålesund Sodankylä |
geographic_facet |
Ny-Ålesund Sodankylä |
genre |
Ny Ålesund Ny-Ålesund Sodankylä |
genre_facet |
Ny Ålesund Ny-Ålesund Sodankylä |
op_source |
Faculty of Science, Medicine and Health - Papers: Part B |
op_relation |
https://ro.uow.edu.au/smhpapers1/600 https://ro.uow.edu.au/cgi/viewcontent.cgi?article=1614&context=smhpapers1 |
_version_ |
1766154544807411712 |