Retrieval of xCO 2 from ground-based mid-infrared (NDACC) solar absorption spectra and comparison to TCCON
High-resolution solar absorption spectra, taken within the Network for the Detection of Atmospheric Composition Change Infrared Working Group (NDACC-IRWG) in the mid-infrared spectral region, are used to infer partial or total column abundances of many gases. In this paper we present the retrieval o...
Main Authors: | , , , , , |
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Format: | Article in Journal/Newspaper |
Language: | unknown |
Published: |
Research Online
2016
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Subjects: | |
Online Access: | https://ro.uow.edu.au/smhpapers/3555 https://ro.uow.edu.au/cgi/viewcontent.cgi?article=4578&context=smhpapers |
Summary: | High-resolution solar absorption spectra, taken within the Network for the Detection of Atmospheric Composition Change Infrared Working Group (NDACC-IRWG) in the mid-infrared spectral region, are used to infer partial or total column abundances of many gases. In this paper we present the retrieval of a column-averaged mole fraction of carbon dioxide from NDACC-IRWG spectra taken with a Fourier transform infrared (FTIR) spectrometer at the site in Ny-Ålesund, Spitsbergen. The retrieved time series is compared to colocated standard TCCON (Total Carbon Column Observing Network) measurements of column-averaged dry-air mole fractions of CO2 (denoted by xCO2). Comparing the NDACC and TCCON retrievals, we find that the sensitivity of the NDACC retrieval is lower in the troposphere (by a factor of 2) and higher in the stratosphere, compared to TCCON. Thus, the NDACC retrieval is less sensitive to tropospheric changes (e.g., the seasonal cycle) in the column average. |
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