| Summary: | The evolution of the Cenozoic cryosphere from unipolar to bipolar over the past 30 million years (Myr) is broadly known. Highly resolved records of carbonate (CaCO3) content provide insight into the evolution of regional and global climate, cryosphere, and carbon cycle dynamics. Here, we generate the first Southeast Atlantic CaCO3 content record spanning the last 30gMyr, derived from X-ray fluorescence (XRF) ln(Cag/gFe) data collected at Ocean Drilling Program Site 1264 (Walvis Ridge, SE Atlantic Ocean). We present a comprehensive and continuous depth and age model for the entirety of Site 1264 (g1/4g316gm; 30gMyr). This constitutes a key reference framework for future palaeoclimatic and palaeoceanographic studies at this location. We identify three phases with distinctly different orbital controls on Southeast Atlantic CaCO3 deposition, corresponding to major developments in climate, the cryosphere and the carbon cycle: (1) strong g1/4g110gkyr eccentricity pacing prevails during Oligocene-Miocene global warmth (g1/4g30-13gMa), (2) increased eccentricity-modulated precession pacing appears after the middle Miocene Climate Transition (mMCT) (g1/4g14-8gMa), and (3) pervasive obliquity pacing appears in the late Miocene (g1/4g7.7-3.3gMa) following greater importance of high-latitude processes, such as increased glacial activity and high-latitude cooling. The lowest CaCO3 content (92g%-94g%) occurs between 18.5 and 14.5gMa, potentially reflecting dissolution caused by widespread early Miocene warmth and preceding Antarctic deglaciation across the Miocene Climatic Optimum (g1/4g17-14.5gMa) by 1.5gMyr. The emergence of precession pacing of CaCO3 deposition at Site 1264 after g1/4g14gMa could signal a reorganisation of surface and/or deep-water circulation in this region following Antarctic reglaciation at the mMCT. The increased sensitivity to precession at Site 1264 between 14 and 13gMa is associated with an increase in mass accumulation rates (MARs) and reflects increased regional CaCO3 productivity and/or recurrent ...
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