Geology, mineralogy, S and Sr isotope geochemistry, and fluid inclusion analysis of barite associated with the Lemarchant Zn–Pb–Cu–Ag–Au-rich volcanogenic massive sulphide deposit, Newfoundland, Canada
Barite in the ~513 Ma Lemarchant VMS deposit, Newfoundland, consists of granular and bladed barite intimately associated with mineralization. Regardless of type, the barite is homogeneous at bulk rock and mineral scale containing predominantly Ba, S, Ca, with minor Sr and Na. The barite has homogene...
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ftunivtoronto:oai:localhost:1807/98609 2023-05-15T17:22:03+02:00 Geology, mineralogy, S and Sr isotope geochemistry, and fluid inclusion analysis of barite associated with the Lemarchant Zn–Pb–Cu–Ag–Au-rich volcanogenic massive sulphide deposit, Newfoundland, Canada Lajoie, Marie-Ève Piercey, Stephen J. Conliffe, James Layton-Matthews, Dan 2019-02-12 http://hdl.handle.net/1807/98609 http://www.nrcresearchpress.com/doi/abs/10.1139/cjes-2018-0161 unknown NRC Research Press (a division of Canadian Science Publishing) 0008-4077 http://hdl.handle.net/1807/98609 http://www.nrcresearchpress.com/doi/abs/10.1139/cjes-2018-0161 Article 2019 ftunivtoronto 2020-06-17T12:28:56Z Barite in the ~513 Ma Lemarchant VMS deposit, Newfoundland, consists of granular and bladed barite intimately associated with mineralization. Regardless of type, the barite is homogeneous at bulk rock and mineral scale containing predominantly Ba, S, Ca, with minor Sr and Na. The barite has homogeneous sulphur isotope compositions (δ34Smean = 27‰), similar to Cambrian seawater sulphate (25-35‰), and Sr isotope compositions (87Sr/86Sr = 0.70699 to 0.70751). These results are consistent with barite having formed from fluid-fluid mixing between Cambrian seawater and VMS-related hydrothermal fluids. The 87Sr/86Sr values in the barite are lower than mid-Cambrian seawater, which suggests that some of the Sr was derived from underlying Neoproterozoic basement. Fluid inclusions in bladed barite are low-salinity, CO2-rich inclusions with homogenization temperatures between 245°-250°C, and average salinity of 1.2 wt.% NaCl equivalent. Estimated minimum trapping pressures of between 1.7 to 2.0 kbars were calculated from aqueous-carbonic fluid inclusion assemblages. The fluid inclusion results reflect regional metamorphic reequilibration during younger Silurian regional metamorphism, rather than primary fluid signatures, despite the preservation of primary barite and fluid-inclusion textures. These results illustrate that barite in VMS deposits records the physicochemical processes associated with VMS formation and the sources of fluids in ancient VMS deposits, as well as seawater sulphate and basement isotopic compositions. The results herein are not only relevant for the Lemarchant deposit but other barite-rich VMS deposits, globally. The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author. Article in Journal/Newspaper Newfoundland University of Toronto: Research Repository T-Space Canada |
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Open Polar |
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University of Toronto: Research Repository T-Space |
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ftunivtoronto |
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unknown |
description |
Barite in the ~513 Ma Lemarchant VMS deposit, Newfoundland, consists of granular and bladed barite intimately associated with mineralization. Regardless of type, the barite is homogeneous at bulk rock and mineral scale containing predominantly Ba, S, Ca, with minor Sr and Na. The barite has homogeneous sulphur isotope compositions (δ34Smean = 27‰), similar to Cambrian seawater sulphate (25-35‰), and Sr isotope compositions (87Sr/86Sr = 0.70699 to 0.70751). These results are consistent with barite having formed from fluid-fluid mixing between Cambrian seawater and VMS-related hydrothermal fluids. The 87Sr/86Sr values in the barite are lower than mid-Cambrian seawater, which suggests that some of the Sr was derived from underlying Neoproterozoic basement. Fluid inclusions in bladed barite are low-salinity, CO2-rich inclusions with homogenization temperatures between 245°-250°C, and average salinity of 1.2 wt.% NaCl equivalent. Estimated minimum trapping pressures of between 1.7 to 2.0 kbars were calculated from aqueous-carbonic fluid inclusion assemblages. The fluid inclusion results reflect regional metamorphic reequilibration during younger Silurian regional metamorphism, rather than primary fluid signatures, despite the preservation of primary barite and fluid-inclusion textures. These results illustrate that barite in VMS deposits records the physicochemical processes associated with VMS formation and the sources of fluids in ancient VMS deposits, as well as seawater sulphate and basement isotopic compositions. The results herein are not only relevant for the Lemarchant deposit but other barite-rich VMS deposits, globally. The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author. |
format |
Article in Journal/Newspaper |
author |
Lajoie, Marie-Ève Piercey, Stephen J. Conliffe, James Layton-Matthews, Dan |
spellingShingle |
Lajoie, Marie-Ève Piercey, Stephen J. Conliffe, James Layton-Matthews, Dan Geology, mineralogy, S and Sr isotope geochemistry, and fluid inclusion analysis of barite associated with the Lemarchant Zn–Pb–Cu–Ag–Au-rich volcanogenic massive sulphide deposit, Newfoundland, Canada |
author_facet |
Lajoie, Marie-Ève Piercey, Stephen J. Conliffe, James Layton-Matthews, Dan |
author_sort |
Lajoie, Marie-Ève |
title |
Geology, mineralogy, S and Sr isotope geochemistry, and fluid inclusion analysis of barite associated with the Lemarchant Zn–Pb–Cu–Ag–Au-rich volcanogenic massive sulphide deposit, Newfoundland, Canada |
title_short |
Geology, mineralogy, S and Sr isotope geochemistry, and fluid inclusion analysis of barite associated with the Lemarchant Zn–Pb–Cu–Ag–Au-rich volcanogenic massive sulphide deposit, Newfoundland, Canada |
title_full |
Geology, mineralogy, S and Sr isotope geochemistry, and fluid inclusion analysis of barite associated with the Lemarchant Zn–Pb–Cu–Ag–Au-rich volcanogenic massive sulphide deposit, Newfoundland, Canada |
title_fullStr |
Geology, mineralogy, S and Sr isotope geochemistry, and fluid inclusion analysis of barite associated with the Lemarchant Zn–Pb–Cu–Ag–Au-rich volcanogenic massive sulphide deposit, Newfoundland, Canada |
title_full_unstemmed |
Geology, mineralogy, S and Sr isotope geochemistry, and fluid inclusion analysis of barite associated with the Lemarchant Zn–Pb–Cu–Ag–Au-rich volcanogenic massive sulphide deposit, Newfoundland, Canada |
title_sort |
geology, mineralogy, s and sr isotope geochemistry, and fluid inclusion analysis of barite associated with the lemarchant zn–pb–cu–ag–au-rich volcanogenic massive sulphide deposit, newfoundland, canada |
publisher |
NRC Research Press (a division of Canadian Science Publishing) |
publishDate |
2019 |
url |
http://hdl.handle.net/1807/98609 http://www.nrcresearchpress.com/doi/abs/10.1139/cjes-2018-0161 |
geographic |
Canada |
geographic_facet |
Canada |
genre |
Newfoundland |
genre_facet |
Newfoundland |
op_relation |
0008-4077 http://hdl.handle.net/1807/98609 http://www.nrcresearchpress.com/doi/abs/10.1139/cjes-2018-0161 |
_version_ |
1766108311862640640 |