Distinct sulfur saturation histories within the Palaeogene Magilligan Sill, Northern Ireland: implications for Ni – Cu – platinum group element mineralisation in the North Atlantic Igneous Province

The ∼60 m thick Magilligan Sill is part of the British Palaeogene Igneous Province in the North Atlantic. The sill comprises layers of dolerite and olivine gabbro, and it intrudes a thick sequence of Mesozoic mudstones and marls, which are locally baked at the sill margins. Since 2014, the sill has...

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Main Authors: Lindsay, Jordan James, Hughes, Hannah S. R., Smyth, Dermot, McDonald, Iain, Boyce, Adrian J., Andersen, Jens C. Ø.
Format: Article in Journal/Newspaper
Language:unknown
Published: NRC Research Press (a division of Canadian Science Publishing) 2019
Subjects:
Online Access:http://hdl.handle.net/1807/95549
http://www.nrcresearchpress.com/doi/abs/10.1139/cjes-2018-0141
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author Lindsay, Jordan James
Hughes, Hannah S. R.
Smyth, Dermot
McDonald, Iain
Boyce, Adrian J.
Andersen, Jens C. Ø.
author_facet Lindsay, Jordan James
Hughes, Hannah S. R.
Smyth, Dermot
McDonald, Iain
Boyce, Adrian J.
Andersen, Jens C. Ø.
author_sort Lindsay, Jordan James
collection University of Toronto: Research Repository T-Space
description The ∼60 m thick Magilligan Sill is part of the British Palaeogene Igneous Province in the North Atlantic. The sill comprises layers of dolerite and olivine gabbro, and it intrudes a thick sequence of Mesozoic mudstones and marls, which are locally baked at the sill margins. Since 2014, the sill has been an exploration target for orthomagmatic Ni – Cu – platinum group element (PGE) sulfide mineralisation analogous to the Noril’sk-Talnakh intrusion in Russia. We present new petrological, geochemical, and S isotope data to assess the prospectivity of the sill and the underlying magmatic plumbing system. Most sulfides in the dolerite portions of the sill are <50 μm in size and comprise only pyrite with PGE abundances below the detection limit. In the olivine gabbros, >150 μm size pentlandite, chalcopyrite, and pyrrhotite grains contain <4 ppm total PGE, 1460 ppm Co, and 88 ppm Ag. Pyrite from the dolerites have δ34S ranging from −10.0‰ to +3.4‰ and olivine gabbro sulfides range from −2.5‰ to −1.1‰, suggesting widespread crustal contamination. The S/Se ratios of sulfides in the dolerites and olivine gabbros range from 3500 to 19 500 and from 1970 to 3710, respectively, indicating that the latter may have come from upstream in the magma plumbing system. The Magilligan Sill records multiple injections of mafic magma into an inflating sill package, each with distinct mechanisms towards S saturation. Whilst the sulfide minerals in the sill do not constitute significant mineralisation themselves, detailed in situ studies highlight a divergence in S saturation histories and suggest that a larger volume of olivine gabbro sulfides at depth may be prospective. The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author.
format Article in Journal/Newspaper
genre North Atlantic
genre_facet North Atlantic
geographic Talnakh
geographic_facet Talnakh
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institution Open Polar
language unknown
long_lat ENVELOPE(88.205,88.205,69.470,69.470)
op_collection_id ftunivtoronto
op_relation 0008-4077
http://hdl.handle.net/1807/95549
http://www.nrcresearchpress.com/doi/abs/10.1139/cjes-2018-0141
publishDate 2019
publisher NRC Research Press (a division of Canadian Science Publishing)
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spelling ftunivtoronto:oai:localhost:1807/95549 2025-01-16T23:39:25+00:00 Distinct sulfur saturation histories within the Palaeogene Magilligan Sill, Northern Ireland: implications for Ni – Cu – platinum group element mineralisation in the North Atlantic Igneous Province Lindsay, Jordan James Hughes, Hannah S. R. Smyth, Dermot McDonald, Iain Boyce, Adrian J. Andersen, Jens C. Ø. 2019-02-02 http://hdl.handle.net/1807/95549 http://www.nrcresearchpress.com/doi/abs/10.1139/cjes-2018-0141 unknown NRC Research Press (a division of Canadian Science Publishing) 0008-4077 http://hdl.handle.net/1807/95549 http://www.nrcresearchpress.com/doi/abs/10.1139/cjes-2018-0141 Article 2019 ftunivtoronto 2020-06-17T12:25:26Z The ∼60 m thick Magilligan Sill is part of the British Palaeogene Igneous Province in the North Atlantic. The sill comprises layers of dolerite and olivine gabbro, and it intrudes a thick sequence of Mesozoic mudstones and marls, which are locally baked at the sill margins. Since 2014, the sill has been an exploration target for orthomagmatic Ni – Cu – platinum group element (PGE) sulfide mineralisation analogous to the Noril’sk-Talnakh intrusion in Russia. We present new petrological, geochemical, and S isotope data to assess the prospectivity of the sill and the underlying magmatic plumbing system. Most sulfides in the dolerite portions of the sill are <50 μm in size and comprise only pyrite with PGE abundances below the detection limit. In the olivine gabbros, >150 μm size pentlandite, chalcopyrite, and pyrrhotite grains contain <4 ppm total PGE, 1460 ppm Co, and 88 ppm Ag. Pyrite from the dolerites have δ34S ranging from −10.0‰ to +3.4‰ and olivine gabbro sulfides range from −2.5‰ to −1.1‰, suggesting widespread crustal contamination. The S/Se ratios of sulfides in the dolerites and olivine gabbros range from 3500 to 19 500 and from 1970 to 3710, respectively, indicating that the latter may have come from upstream in the magma plumbing system. The Magilligan Sill records multiple injections of mafic magma into an inflating sill package, each with distinct mechanisms towards S saturation. Whilst the sulfide minerals in the sill do not constitute significant mineralisation themselves, detailed in situ studies highlight a divergence in S saturation histories and suggest that a larger volume of olivine gabbro sulfides at depth may be prospective. The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author. Article in Journal/Newspaper North Atlantic University of Toronto: Research Repository T-Space Talnakh ENVELOPE(88.205,88.205,69.470,69.470)
spellingShingle Lindsay, Jordan James
Hughes, Hannah S. R.
Smyth, Dermot
McDonald, Iain
Boyce, Adrian J.
Andersen, Jens C. Ø.
Distinct sulfur saturation histories within the Palaeogene Magilligan Sill, Northern Ireland: implications for Ni – Cu – platinum group element mineralisation in the North Atlantic Igneous Province
title Distinct sulfur saturation histories within the Palaeogene Magilligan Sill, Northern Ireland: implications for Ni – Cu – platinum group element mineralisation in the North Atlantic Igneous Province
title_full Distinct sulfur saturation histories within the Palaeogene Magilligan Sill, Northern Ireland: implications for Ni – Cu – platinum group element mineralisation in the North Atlantic Igneous Province
title_fullStr Distinct sulfur saturation histories within the Palaeogene Magilligan Sill, Northern Ireland: implications for Ni – Cu – platinum group element mineralisation in the North Atlantic Igneous Province
title_full_unstemmed Distinct sulfur saturation histories within the Palaeogene Magilligan Sill, Northern Ireland: implications for Ni – Cu – platinum group element mineralisation in the North Atlantic Igneous Province
title_short Distinct sulfur saturation histories within the Palaeogene Magilligan Sill, Northern Ireland: implications for Ni – Cu – platinum group element mineralisation in the North Atlantic Igneous Province
title_sort distinct sulfur saturation histories within the palaeogene magilligan sill, northern ireland: implications for ni – cu – platinum group element mineralisation in the north atlantic igneous province
url http://hdl.handle.net/1807/95549
http://www.nrcresearchpress.com/doi/abs/10.1139/cjes-2018-0141