From structure topology to chemical composition. VIII. Titanium silicates: the crystal chemistry of mosandrite from type locality of Låven (Skådön), Langesundsfjorden, Larvik, Vestfold, Norway
The crystal structure of mosandrite, ideally Na(2)Ca(4)REETi(Si(2)O(7))(2)OF(3), a = 7.4184(8), b = 5.6789(6), c 18.873(2) angstrom, B = 101.410(2)degrees, V = 779.35(5) angstrom(3), space group P2(1)/c, Z = 2, D(calc) = 3.363 g.cm(-3), from the type locality, Laven (Skadon), Langesundsfjorden, Larv...
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Online Access: | http://hdl.handle.net/2318/128793 https://doi.org/10.1180/minmag.2008.072.4.887 http://minmag.geoscienceworld.org/content/72/4/887.abstract |
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ftunivtorino:oai:iris.unito.it:2318/128793 2023-10-29T02:36:48+01:00 From structure topology to chemical composition. VIII. Titanium silicates: the crystal chemistry of mosandrite from type locality of Låven (Skådön), Langesundsfjorden, Larvik, Vestfold, Norway Sokolova E CAMARA ARTIGAS, Fernando Sokolova E Cámara F 2008 http://hdl.handle.net/2318/128793 https://doi.org/10.1180/minmag.2008.072.4.887 http://minmag.geoscienceworld.org/content/72/4/887.abstract eng eng info:eu-repo/semantics/altIdentifier/wos/WOS:000262262400003 volume:72 firstpage:887 lastpage:897 numberofpages:11 journal:MINERALOGICAL MAGAZINE http://hdl.handle.net/2318/128793 doi:10.1180/minmag.2008.072.4.887 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-64549150144 http://minmag.geoscienceworld.org/content/72/4/887.abstract mosandrite rinkite crystal structure EMP analysi chemical formula Ti disilicate mineral Group I type locality info:eu-repo/semantics/article 2008 ftunivtorino https://doi.org/10.1180/minmag.2008.072.4.887 2023-10-03T22:18:23Z The crystal structure of mosandrite, ideally Na(2)Ca(4)REETi(Si(2)O(7))(2)OF(3), a = 7.4184(8), b = 5.6789(6), c 18.873(2) angstrom, B = 101.410(2)degrees, V = 779.35(5) angstrom(3), space group P2(1)/c, Z = 2, D(calc) = 3.363 g.cm(-3), from the type locality, Laven (Skadon), Langesundsfjorden, Larvik, Vestfold, Norway, has been refined to R(1) = 6.33% on the basis of 1113 unique reflections |F(o) >= 4 sigma F|. Electron microprobe analysis gave the empirical formula Na(1.99)(Ca(3.93)Sr(0.02))(Sigma 3.95)(Ce(0.41)La(0.16)Nd(0.13)Pr(0.04)Sm(0.02)Dy(0.01)Y(0.13))(Sigma 0.90) (Ti(0.86)(4+)Nb(0.08)Zr(0.05))(Sigma 0.99)(Si(2)O(7))(2)(F(1.20)O(0.80))(Sigma 2.00)F(2), Z = 2, calculated on the basis of 18 (O + F) a.p.f.u. The crystal structure of mosandrite is a framework of TS (titanium silicate) blocks. The TS block consists of HOH sheets (H-heteropolyhedral, O-octahedral). The TS block in mosandrite exhibits linkage and stereochemistry typical for Group 1 (Ti = 1 a.p.f.u.) Ti-disilicate minerals: two H sheets connect to the O sheet such that two (Si(2)O(7)) groups link to the trans edges of a Na polyhedron of the O sheet. The O sheet cations give Na(NaCa)Ti (4 a.p.f.u.). The TS blocks link via common vertices of Si(2)O(7)) groups and common vertices and edges of Ca-dominant M(H) and A(P) polyhedra. Two adjacent TS blocks are related by the glide plane c(y). Composition and topology of the TS block in mosandrite and rinkite are identical. The crystal structure of mosandrite from the type locality is topologically and chemically identical to that of rinkite from the type locality of Kangerdluarssuk, Greenland. Article in Journal/Newspaper Greenland Università degli studi di Torino: AperTo (Archivio Istituzionale ad Accesso Aperto) Mineralogical Magazine 72 4 887 897 |
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Open Polar |
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Università degli studi di Torino: AperTo (Archivio Istituzionale ad Accesso Aperto) |
op_collection_id |
ftunivtorino |
language |
English |
topic |
mosandrite rinkite crystal structure EMP analysi chemical formula Ti disilicate mineral Group I type locality |
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mosandrite rinkite crystal structure EMP analysi chemical formula Ti disilicate mineral Group I type locality Sokolova E CAMARA ARTIGAS, Fernando From structure topology to chemical composition. VIII. Titanium silicates: the crystal chemistry of mosandrite from type locality of Låven (Skådön), Langesundsfjorden, Larvik, Vestfold, Norway |
topic_facet |
mosandrite rinkite crystal structure EMP analysi chemical formula Ti disilicate mineral Group I type locality |
description |
The crystal structure of mosandrite, ideally Na(2)Ca(4)REETi(Si(2)O(7))(2)OF(3), a = 7.4184(8), b = 5.6789(6), c 18.873(2) angstrom, B = 101.410(2)degrees, V = 779.35(5) angstrom(3), space group P2(1)/c, Z = 2, D(calc) = 3.363 g.cm(-3), from the type locality, Laven (Skadon), Langesundsfjorden, Larvik, Vestfold, Norway, has been refined to R(1) = 6.33% on the basis of 1113 unique reflections |F(o) >= 4 sigma F|. Electron microprobe analysis gave the empirical formula Na(1.99)(Ca(3.93)Sr(0.02))(Sigma 3.95)(Ce(0.41)La(0.16)Nd(0.13)Pr(0.04)Sm(0.02)Dy(0.01)Y(0.13))(Sigma 0.90) (Ti(0.86)(4+)Nb(0.08)Zr(0.05))(Sigma 0.99)(Si(2)O(7))(2)(F(1.20)O(0.80))(Sigma 2.00)F(2), Z = 2, calculated on the basis of 18 (O + F) a.p.f.u. The crystal structure of mosandrite is a framework of TS (titanium silicate) blocks. The TS block consists of HOH sheets (H-heteropolyhedral, O-octahedral). The TS block in mosandrite exhibits linkage and stereochemistry typical for Group 1 (Ti = 1 a.p.f.u.) Ti-disilicate minerals: two H sheets connect to the O sheet such that two (Si(2)O(7)) groups link to the trans edges of a Na polyhedron of the O sheet. The O sheet cations give Na(NaCa)Ti (4 a.p.f.u.). The TS blocks link via common vertices of Si(2)O(7)) groups and common vertices and edges of Ca-dominant M(H) and A(P) polyhedra. Two adjacent TS blocks are related by the glide plane c(y). Composition and topology of the TS block in mosandrite and rinkite are identical. The crystal structure of mosandrite from the type locality is topologically and chemically identical to that of rinkite from the type locality of Kangerdluarssuk, Greenland. |
author2 |
Sokolova E Cámara F |
format |
Article in Journal/Newspaper |
author |
Sokolova E CAMARA ARTIGAS, Fernando |
author_facet |
Sokolova E CAMARA ARTIGAS, Fernando |
author_sort |
Sokolova E |
title |
From structure topology to chemical composition. VIII. Titanium silicates: the crystal chemistry of mosandrite from type locality of Låven (Skådön), Langesundsfjorden, Larvik, Vestfold, Norway |
title_short |
From structure topology to chemical composition. VIII. Titanium silicates: the crystal chemistry of mosandrite from type locality of Låven (Skådön), Langesundsfjorden, Larvik, Vestfold, Norway |
title_full |
From structure topology to chemical composition. VIII. Titanium silicates: the crystal chemistry of mosandrite from type locality of Låven (Skådön), Langesundsfjorden, Larvik, Vestfold, Norway |
title_fullStr |
From structure topology to chemical composition. VIII. Titanium silicates: the crystal chemistry of mosandrite from type locality of Låven (Skådön), Langesundsfjorden, Larvik, Vestfold, Norway |
title_full_unstemmed |
From structure topology to chemical composition. VIII. Titanium silicates: the crystal chemistry of mosandrite from type locality of Låven (Skådön), Langesundsfjorden, Larvik, Vestfold, Norway |
title_sort |
from structure topology to chemical composition. viii. titanium silicates: the crystal chemistry of mosandrite from type locality of låven (skådön), langesundsfjorden, larvik, vestfold, norway |
publishDate |
2008 |
url |
http://hdl.handle.net/2318/128793 https://doi.org/10.1180/minmag.2008.072.4.887 http://minmag.geoscienceworld.org/content/72/4/887.abstract |
genre |
Greenland |
genre_facet |
Greenland |
op_relation |
info:eu-repo/semantics/altIdentifier/wos/WOS:000262262400003 volume:72 firstpage:887 lastpage:897 numberofpages:11 journal:MINERALOGICAL MAGAZINE http://hdl.handle.net/2318/128793 doi:10.1180/minmag.2008.072.4.887 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-64549150144 http://minmag.geoscienceworld.org/content/72/4/887.abstract |
op_doi |
https://doi.org/10.1180/minmag.2008.072.4.887 |
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