Distribution of dissolved and particulate metals in Antarctic sea ice
Samples were collected in East Antarctic sea ice in late winter/early austral spring 2007 to assess thedistributions of Al, Cr, Mn, Cu, Zn, Mo, Cd and Ba. Total dissolved (b0.2 m) and particulate (N0.2 m)concentrations were measured by Inductively Coupled Plasma-Sector Field Mass Spectrometry (ICP-S...
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ftunivtasecite:oai:ecite.utas.edu.au:76022 2023-05-15T14:02:30+02:00 Distribution of dissolved and particulate metals in Antarctic sea ice Lannuzel, D Bowie, AR Van Der Merwe, P Townsend, AT Schoemann, V 2011 application/pdf https://doi.org/10.1016/j.marchem.2011.01.004 http://ecite.utas.edu.au/76022 en eng Elsevier Science Bv http://ecite.utas.edu.au/76022/1/lannuzel et al., 2011a.pdf http://dx.doi.org/10.1016/j.marchem.2011.01.004 http://purl.org/au-research/grants/arc/DP0985361 Lannuzel, D and Bowie, AR and Van Der Merwe, P and Townsend, AT and Schoemann, V, Distribution of dissolved and particulate metals in Antarctic sea ice, Marine Chemistry: An International Journal for Studies of All Chemical Aspects of The Marine Environment, 124, (1-4) pp. 134-146. ISSN 0304-4203 (2011) [Refereed Article] http://ecite.utas.edu.au/76022 Earth Sciences Oceanography Chemical Oceanography Refereed Article PeerReviewed 2011 ftunivtasecite https://doi.org/10.1016/j.marchem.2011.01.004 2019-12-13T21:42:32Z Samples were collected in East Antarctic sea ice in late winter/early austral spring 2007 to assess thedistributions of Al, Cr, Mn, Cu, Zn, Mo, Cd and Ba. Total dissolved (b0.2 m) and particulate (N0.2 m)concentrations were measured by Inductively Coupled Plasma-Sector Field Mass Spectrometry (ICP-SFMS) insnow, pack ice and fast ice. Particulate concentrations were also determined in underlying seawater for theseelements. The concentrations of particulate metals were one to two orders of magnitude higher in sea ice thanin snow and seawater, except for Mo and Cr. Barite maxima in sea ice vertical profiles at all sites may indicateheterotrophic activity. Particulate Al and Mn distributions suggest a signal from Antarctica's shelf sediments.Dissolved metals were one order of magnitude higher in sea ice as compared to snow, although they were notenriched in sea ice as compared to data reported in the literature for Antarctic surface waters. An analysis ofdissolved-to-total metal ratios showed that all studied metals were found almost exclusively in the dissolvedphase in Antarctic pack ice. Dissolved metals distributions indicate that spatial variability does not seem to bestrong. Our results also demonstrate that dissolved Al, Cr, Mo and Ba behaved conservatively with bulk icesalinity gradients. This would confirm the main source of trace metals to Antarctic sea ice comes fromseawater and not from direct atmospheric deposition. Dissolved bioactive metals Mn, Cu, Zn and Cdconcentrations were scattered when plotted against bulk ice salinity, but did not show a seasonal decrease norreach limitation status. Finally, seasonal ice melt does not seem to contribute significantly to the supply ofdissolved bioactive metals, other than Fe, to Antarctic surface waters. Article in Journal/Newspaper Antarc* Antarctic Sea ice eCite UTAS (University of Tasmania) Antarctic Austral Marine Chemistry 124 1-4 134 146 |
institution |
Open Polar |
collection |
eCite UTAS (University of Tasmania) |
op_collection_id |
ftunivtasecite |
language |
English |
topic |
Earth Sciences Oceanography Chemical Oceanography |
spellingShingle |
Earth Sciences Oceanography Chemical Oceanography Lannuzel, D Bowie, AR Van Der Merwe, P Townsend, AT Schoemann, V Distribution of dissolved and particulate metals in Antarctic sea ice |
topic_facet |
Earth Sciences Oceanography Chemical Oceanography |
description |
Samples were collected in East Antarctic sea ice in late winter/early austral spring 2007 to assess thedistributions of Al, Cr, Mn, Cu, Zn, Mo, Cd and Ba. Total dissolved (b0.2 m) and particulate (N0.2 m)concentrations were measured by Inductively Coupled Plasma-Sector Field Mass Spectrometry (ICP-SFMS) insnow, pack ice and fast ice. Particulate concentrations were also determined in underlying seawater for theseelements. The concentrations of particulate metals were one to two orders of magnitude higher in sea ice thanin snow and seawater, except for Mo and Cr. Barite maxima in sea ice vertical profiles at all sites may indicateheterotrophic activity. Particulate Al and Mn distributions suggest a signal from Antarctica's shelf sediments.Dissolved metals were one order of magnitude higher in sea ice as compared to snow, although they were notenriched in sea ice as compared to data reported in the literature for Antarctic surface waters. An analysis ofdissolved-to-total metal ratios showed that all studied metals were found almost exclusively in the dissolvedphase in Antarctic pack ice. Dissolved metals distributions indicate that spatial variability does not seem to bestrong. Our results also demonstrate that dissolved Al, Cr, Mo and Ba behaved conservatively with bulk icesalinity gradients. This would confirm the main source of trace metals to Antarctic sea ice comes fromseawater and not from direct atmospheric deposition. Dissolved bioactive metals Mn, Cu, Zn and Cdconcentrations were scattered when plotted against bulk ice salinity, but did not show a seasonal decrease norreach limitation status. Finally, seasonal ice melt does not seem to contribute significantly to the supply ofdissolved bioactive metals, other than Fe, to Antarctic surface waters. |
format |
Article in Journal/Newspaper |
author |
Lannuzel, D Bowie, AR Van Der Merwe, P Townsend, AT Schoemann, V |
author_facet |
Lannuzel, D Bowie, AR Van Der Merwe, P Townsend, AT Schoemann, V |
author_sort |
Lannuzel, D |
title |
Distribution of dissolved and particulate metals in Antarctic sea ice |
title_short |
Distribution of dissolved and particulate metals in Antarctic sea ice |
title_full |
Distribution of dissolved and particulate metals in Antarctic sea ice |
title_fullStr |
Distribution of dissolved and particulate metals in Antarctic sea ice |
title_full_unstemmed |
Distribution of dissolved and particulate metals in Antarctic sea ice |
title_sort |
distribution of dissolved and particulate metals in antarctic sea ice |
publisher |
Elsevier Science Bv |
publishDate |
2011 |
url |
https://doi.org/10.1016/j.marchem.2011.01.004 http://ecite.utas.edu.au/76022 |
geographic |
Antarctic Austral |
geographic_facet |
Antarctic Austral |
genre |
Antarc* Antarctic Sea ice |
genre_facet |
Antarc* Antarctic Sea ice |
op_relation |
http://ecite.utas.edu.au/76022/1/lannuzel et al., 2011a.pdf http://dx.doi.org/10.1016/j.marchem.2011.01.004 http://purl.org/au-research/grants/arc/DP0985361 Lannuzel, D and Bowie, AR and Van Der Merwe, P and Townsend, AT and Schoemann, V, Distribution of dissolved and particulate metals in Antarctic sea ice, Marine Chemistry: An International Journal for Studies of All Chemical Aspects of The Marine Environment, 124, (1-4) pp. 134-146. ISSN 0304-4203 (2011) [Refereed Article] http://ecite.utas.edu.au/76022 |
op_doi |
https://doi.org/10.1016/j.marchem.2011.01.004 |
container_title |
Marine Chemistry |
container_volume |
124 |
container_issue |
1-4 |
container_start_page |
134 |
op_container_end_page |
146 |
_version_ |
1766272784827154432 |