A method for continuous 239 Pu determinations in Arctic and Antarctic ice cores
Atmospheric nuclear weapons testing (NWT) resulted in the injection of plutonium (Pu) into the atmosphere and subsequent global deposition. We present a new method for continuous semiquantitative measurement of 239 Pu in ice cores, which was used to develop annual records of fallout from NWT in ten...
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Online Access: | https://doi.org/10.1021/acs.est.6b01108 http://www.ncbi.nlm.nih.gov/pubmed/27244483 http://ecite.utas.edu.au/114873 |
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ftunivtasecite:oai:ecite.utas.edu.au:114873 2023-05-15T13:49:03+02:00 A method for continuous 239 Pu determinations in Arctic and Antarctic ice cores Arienzo, MM McConnell, JR Chellman, N Criscitiello, AS Curran, M Fritzsche, D Kipfstuhl, S Mulvaney, R Nolan, M Opel, T Sigl, M Steffensen, JP 2016 https://doi.org/10.1021/acs.est.6b01108 http://www.ncbi.nlm.nih.gov/pubmed/27244483 http://ecite.utas.edu.au/114873 en eng Amer Chemical Soc http://dx.doi.org/10.1021/acs.est.6b01108 Arienzo, MM and McConnell, JR and Chellman, N and Criscitiello, AS and Curran, M and Fritzsche, D and Kipfstuhl, S and Mulvaney, R and Nolan, M and Opel, T and Sigl, M and Steffensen, JP, A method for continuous 239 Pu determinations in Arctic and Antarctic ice cores, Environmental Science and Technology, 50, (13) pp. 7066-7073. ISSN 0013-936X (2016) [Refereed Article] http://www.ncbi.nlm.nih.gov/pubmed/27244483 http://ecite.utas.edu.au/114873 Earth Sciences Geochemistry Isotope Geochemistry Refereed Article PeerReviewed 2016 ftunivtasecite https://doi.org/10.1021/acs.est.6b01108 2019-12-13T22:14:43Z Atmospheric nuclear weapons testing (NWT) resulted in the injection of plutonium (Pu) into the atmosphere and subsequent global deposition. We present a new method for continuous semiquantitative measurement of 239 Pu in ice cores, which was used to develop annual records of fallout from NWT in ten ice cores from Greenland and Antarctica. The 239 Pu was measured directly using an inductively coupled plasmasector field mass spectrometer, thereby reducing analysis time and increasing depth-resolution with respect to previous methods. To validate this method, we compared our one year averaged results to published 239 Pu records and other records of NWT. The 239 Pu profiles from the Arctic ice cores reflected global trends in NWT and were in agreement with discrete Pu profiles from lower latitude ice cores. The 239 Pu measurements in the Antarctic ice cores tracked low latitude NWT, consistent with previously published discrete records from Antarctica. Advantages of the continuous 239 Pu measurement method are (1) reduced sample preparation and analysis time; (2) no requirement for additional ice samples for NWT fallout determinations; (3) measurements are exactly coregistered with all other chemical, elemental, isotopic, and gas measurements from the continuous analytical system; and (4) the long half-life means the 239 Pu record is stable through time. Article in Journal/Newspaper Antarc* Antarctic Antarctica Arctic Arctic Greenland eCite UTAS (University of Tasmania) Antarctic Arctic Greenland The Antarctic Environmental Science & Technology 50 13 7066 7073 |
institution |
Open Polar |
collection |
eCite UTAS (University of Tasmania) |
op_collection_id |
ftunivtasecite |
language |
English |
topic |
Earth Sciences Geochemistry Isotope Geochemistry |
spellingShingle |
Earth Sciences Geochemistry Isotope Geochemistry Arienzo, MM McConnell, JR Chellman, N Criscitiello, AS Curran, M Fritzsche, D Kipfstuhl, S Mulvaney, R Nolan, M Opel, T Sigl, M Steffensen, JP A method for continuous 239 Pu determinations in Arctic and Antarctic ice cores |
topic_facet |
Earth Sciences Geochemistry Isotope Geochemistry |
description |
Atmospheric nuclear weapons testing (NWT) resulted in the injection of plutonium (Pu) into the atmosphere and subsequent global deposition. We present a new method for continuous semiquantitative measurement of 239 Pu in ice cores, which was used to develop annual records of fallout from NWT in ten ice cores from Greenland and Antarctica. The 239 Pu was measured directly using an inductively coupled plasmasector field mass spectrometer, thereby reducing analysis time and increasing depth-resolution with respect to previous methods. To validate this method, we compared our one year averaged results to published 239 Pu records and other records of NWT. The 239 Pu profiles from the Arctic ice cores reflected global trends in NWT and were in agreement with discrete Pu profiles from lower latitude ice cores. The 239 Pu measurements in the Antarctic ice cores tracked low latitude NWT, consistent with previously published discrete records from Antarctica. Advantages of the continuous 239 Pu measurement method are (1) reduced sample preparation and analysis time; (2) no requirement for additional ice samples for NWT fallout determinations; (3) measurements are exactly coregistered with all other chemical, elemental, isotopic, and gas measurements from the continuous analytical system; and (4) the long half-life means the 239 Pu record is stable through time. |
format |
Article in Journal/Newspaper |
author |
Arienzo, MM McConnell, JR Chellman, N Criscitiello, AS Curran, M Fritzsche, D Kipfstuhl, S Mulvaney, R Nolan, M Opel, T Sigl, M Steffensen, JP |
author_facet |
Arienzo, MM McConnell, JR Chellman, N Criscitiello, AS Curran, M Fritzsche, D Kipfstuhl, S Mulvaney, R Nolan, M Opel, T Sigl, M Steffensen, JP |
author_sort |
Arienzo, MM |
title |
A method for continuous 239 Pu determinations in Arctic and Antarctic ice cores |
title_short |
A method for continuous 239 Pu determinations in Arctic and Antarctic ice cores |
title_full |
A method for continuous 239 Pu determinations in Arctic and Antarctic ice cores |
title_fullStr |
A method for continuous 239 Pu determinations in Arctic and Antarctic ice cores |
title_full_unstemmed |
A method for continuous 239 Pu determinations in Arctic and Antarctic ice cores |
title_sort |
method for continuous 239 pu determinations in arctic and antarctic ice cores |
publisher |
Amer Chemical Soc |
publishDate |
2016 |
url |
https://doi.org/10.1021/acs.est.6b01108 http://www.ncbi.nlm.nih.gov/pubmed/27244483 http://ecite.utas.edu.au/114873 |
geographic |
Antarctic Arctic Greenland The Antarctic |
geographic_facet |
Antarctic Arctic Greenland The Antarctic |
genre |
Antarc* Antarctic Antarctica Arctic Arctic Greenland |
genre_facet |
Antarc* Antarctic Antarctica Arctic Arctic Greenland |
op_relation |
http://dx.doi.org/10.1021/acs.est.6b01108 Arienzo, MM and McConnell, JR and Chellman, N and Criscitiello, AS and Curran, M and Fritzsche, D and Kipfstuhl, S and Mulvaney, R and Nolan, M and Opel, T and Sigl, M and Steffensen, JP, A method for continuous 239 Pu determinations in Arctic and Antarctic ice cores, Environmental Science and Technology, 50, (13) pp. 7066-7073. ISSN 0013-936X (2016) [Refereed Article] http://www.ncbi.nlm.nih.gov/pubmed/27244483 http://ecite.utas.edu.au/114873 |
op_doi |
https://doi.org/10.1021/acs.est.6b01108 |
container_title |
Environmental Science & Technology |
container_volume |
50 |
container_issue |
13 |
container_start_page |
7066 |
op_container_end_page |
7073 |
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1766250691402137600 |