Essential features of the polytypic charoite-96 structure compared to charoite-90
Charoite, ideally (K,Sr,Ba,Mn) 15-16(Ca,Na) 32[(Si 70(O,OH) 180)](OH,F) 4•nH 2O, is a rock-forming mineral from the Murun massif in Yakutia, Sakha Republic, Siberia, Russia, where it occurs in a unique alkaline intrusion. Charoite occurs as four different polytypes, which are commonly intergrown in...
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ftunivsiena:oai:usiena-air.unisi.it:11365/841655 2024-04-21T08:10:52+00:00 Essential features of the polytypic charoite-96 structure compared to charoite-90 Rozhdestvenskaya, I. V. MUGNAIOLI, E. Czank, M. Depmeier, W. Kolb, U. Merlino, S. Rozhdestvenskaya, I. V. Mugnaioli, E. Czank, M. Depmeier, W. Kolb, U. Merlino, S. 2011 STAMPA http://hdl.handle.net/11365/841655 https://doi.org/10.1180/minmag.2011.075.6.2833 eng eng info:eu-repo/semantics/altIdentifier/wos/WOS:000298307000009 volume:75 issue:6 firstpage:2833 lastpage:2846 numberofpages:14 journal:MINERALOGICAL MAGAZINE http://hdl.handle.net/11365/841655 doi:10.1180/minmag.2011.075.6.2833 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-83455196954 charoite polytype crystal structure analysi electron crystallography electron diffraction electron diffraction tomography info:eu-repo/semantics/article 2011 ftunivsiena https://doi.org/10.1180/minmag.2011.075.6.2833 2024-03-28T00:46:28Z Charoite, ideally (K,Sr,Ba,Mn) 15-16(Ca,Na) 32[(Si 70(O,OH) 180)](OH,F) 4•nH 2O, is a rock-forming mineral from the Murun massif in Yakutia, Sakha Republic, Siberia, Russia, where it occurs in a unique alkaline intrusion. Charoite occurs as four different polytypes, which are commonly intergrown in nanocrystalline fibres. We report the structure of charoite-96 (a = 32.11(6), b = 19.77(4), c = 7.23(1) Å, β = 95.85(9)°, V = 4565(24) Å 3, space group P2 1/m), which was solved ab initio by direct methods on the basis of 2676 unique electron diffraction reflections collected by automated diffraction tomography and refined to R 1/wR 2 = 0.34/0.37. The structure of charoite-96 is related to that of the charoite-90, which was also solved recently. Both structures are composed of three different types of dreier silicate chains running along [001] and separated by ribbons of edge-sharing Ca-and Na-centred octahedra. In the structure of charoite-96, adjacent blocks formed by three different silicate chains and stacked along the x axis, are shifted by a translation of 1⁄2 c. The shifts involve a hybrid dreier quadruple chain, [Si 17O 43] 18- and a double dreier chain, [Si 6O 17] 10-. In charoite-90 adjacent blocks are stacked without shifts. © 2011 Mineralogical Society. Article in Journal/Newspaper Sakha Sakha Republic Yakutia Siberia Università degli Studi di Siena: USiena air Mineralogical Magazine 75 6 2833 2846 |
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Università degli Studi di Siena: USiena air |
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language |
English |
topic |
charoite polytype crystal structure analysi electron crystallography electron diffraction electron diffraction tomography |
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charoite polytype crystal structure analysi electron crystallography electron diffraction electron diffraction tomography Rozhdestvenskaya, I. V. MUGNAIOLI, E. Czank, M. Depmeier, W. Kolb, U. Merlino, S. Essential features of the polytypic charoite-96 structure compared to charoite-90 |
topic_facet |
charoite polytype crystal structure analysi electron crystallography electron diffraction electron diffraction tomography |
description |
Charoite, ideally (K,Sr,Ba,Mn) 15-16(Ca,Na) 32[(Si 70(O,OH) 180)](OH,F) 4•nH 2O, is a rock-forming mineral from the Murun massif in Yakutia, Sakha Republic, Siberia, Russia, where it occurs in a unique alkaline intrusion. Charoite occurs as four different polytypes, which are commonly intergrown in nanocrystalline fibres. We report the structure of charoite-96 (a = 32.11(6), b = 19.77(4), c = 7.23(1) Å, β = 95.85(9)°, V = 4565(24) Å 3, space group P2 1/m), which was solved ab initio by direct methods on the basis of 2676 unique electron diffraction reflections collected by automated diffraction tomography and refined to R 1/wR 2 = 0.34/0.37. The structure of charoite-96 is related to that of the charoite-90, which was also solved recently. Both structures are composed of three different types of dreier silicate chains running along [001] and separated by ribbons of edge-sharing Ca-and Na-centred octahedra. In the structure of charoite-96, adjacent blocks formed by three different silicate chains and stacked along the x axis, are shifted by a translation of 1⁄2 c. The shifts involve a hybrid dreier quadruple chain, [Si 17O 43] 18- and a double dreier chain, [Si 6O 17] 10-. In charoite-90 adjacent blocks are stacked without shifts. © 2011 Mineralogical Society. |
author2 |
Rozhdestvenskaya, I. V. Mugnaioli, E. Czank, M. Depmeier, W. Kolb, U. Merlino, S. |
format |
Article in Journal/Newspaper |
author |
Rozhdestvenskaya, I. V. MUGNAIOLI, E. Czank, M. Depmeier, W. Kolb, U. Merlino, S. |
author_facet |
Rozhdestvenskaya, I. V. MUGNAIOLI, E. Czank, M. Depmeier, W. Kolb, U. Merlino, S. |
author_sort |
Rozhdestvenskaya, I. V. |
title |
Essential features of the polytypic charoite-96 structure compared to charoite-90 |
title_short |
Essential features of the polytypic charoite-96 structure compared to charoite-90 |
title_full |
Essential features of the polytypic charoite-96 structure compared to charoite-90 |
title_fullStr |
Essential features of the polytypic charoite-96 structure compared to charoite-90 |
title_full_unstemmed |
Essential features of the polytypic charoite-96 structure compared to charoite-90 |
title_sort |
essential features of the polytypic charoite-96 structure compared to charoite-90 |
publishDate |
2011 |
url |
http://hdl.handle.net/11365/841655 https://doi.org/10.1180/minmag.2011.075.6.2833 |
genre |
Sakha Sakha Republic Yakutia Siberia |
genre_facet |
Sakha Sakha Republic Yakutia Siberia |
op_relation |
info:eu-repo/semantics/altIdentifier/wos/WOS:000298307000009 volume:75 issue:6 firstpage:2833 lastpage:2846 numberofpages:14 journal:MINERALOGICAL MAGAZINE http://hdl.handle.net/11365/841655 doi:10.1180/minmag.2011.075.6.2833 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-83455196954 |
op_doi |
https://doi.org/10.1180/minmag.2011.075.6.2833 |
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