Nature of alkali-carbonate fluids in the sub-continental lithospheric mantle
Mantle xenoliths sampled by kimberlite and alkali basalt magmas show a range of metasomatic styles, but direct evidence for the nature of the metasomatising fl uids is often elusive. It has been suggested that carbonate-rich melts produced by partial melting of carbonated peridotites and eclogites p...
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Geological Society of America
2012
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ftunivqespace:oai:espace.library.uq.edu.au:UQ:dbabf7c 2023-05-15T18:45:07+02:00 Nature of alkali-carbonate fluids in the sub-continental lithospheric mantle Giuliani, A. Kamenetsky, V. S. Phillips, D. Kendrick, M. A. Wyatt, B. A. Goemann, K. 2012-11-01 https://espace.library.uq.edu.au/view/UQ:dbabf7c eng eng Geological Society of America doi:10.1130/G33221.1 issn:0091-7613 issn:1943-2682 orcid:0000-0002-6541-4162 Geology 1907 Geology Journal Article 2012 ftunivqespace https://doi.org/10.1130/G33221.1 2020-12-08T06:41:03Z Mantle xenoliths sampled by kimberlite and alkali basalt magmas show a range of metasomatic styles, but direct evidence for the nature of the metasomatising fl uids is often elusive. It has been suggested that carbonate-rich melts produced by partial melting of carbonated peridotites and eclogites play an important role in modifying the composition of the lithospheric mantle. These mantle-derived carbonate melts are often inferred to be enriched in alkali elements; however, alkali-rich carbonate fl uids have only been reported as micro-inclusions in diamonds and as unique melts involved in the formation of the Udachnaya-East kimberlite (Yakutia, Russia). In this paper we present the fi rst direct evidence for alkali-carbonate melts in the shallow lithospheric mantle (~110-115 km), above the diamond stability fi eld. These alkali-carbonate melts are preserved in primary multiphase inclusions hosted by large metasomatic ilmenite grains contained in a polymict mantle xenolith from the Bultfontein kimberlite (Kimberley, South Africa). The inclusions host abundant carbonates (magnesite, dolomite, and K-Na-Ca carbonates), kalsilite, phlogopite, K-Na titanates, and phosphates, with lesser amounts of olivine, chlorides, and alkali sulfates. Textural and chemical observations indicate that the alkali-carbonate melt likely derived from primary or precursor kimberlite magmas. Our fi ndings extend the evidence for alkali-carbonate melts/fl uids permeating the Earth mantle outside the diamond stability fi eld and provide new insights into the chemical features of previously hypothesized melts. As metasomatism by alkali-rich carbonate melts is often reported to affect mantle xenoliths, and predicted from experimental studies, the fl uid type documented here likely represent a major metasomatising agent in the Earth's lithospheric mantle. Article in Journal/Newspaper Yakutia The University of Queensland: UQ eSpace Geology 40 11 967 970 |
institution |
Open Polar |
collection |
The University of Queensland: UQ eSpace |
op_collection_id |
ftunivqespace |
language |
English |
topic |
Geology 1907 Geology |
spellingShingle |
Geology 1907 Geology Giuliani, A. Kamenetsky, V. S. Phillips, D. Kendrick, M. A. Wyatt, B. A. Goemann, K. Nature of alkali-carbonate fluids in the sub-continental lithospheric mantle |
topic_facet |
Geology 1907 Geology |
description |
Mantle xenoliths sampled by kimberlite and alkali basalt magmas show a range of metasomatic styles, but direct evidence for the nature of the metasomatising fl uids is often elusive. It has been suggested that carbonate-rich melts produced by partial melting of carbonated peridotites and eclogites play an important role in modifying the composition of the lithospheric mantle. These mantle-derived carbonate melts are often inferred to be enriched in alkali elements; however, alkali-rich carbonate fl uids have only been reported as micro-inclusions in diamonds and as unique melts involved in the formation of the Udachnaya-East kimberlite (Yakutia, Russia). In this paper we present the fi rst direct evidence for alkali-carbonate melts in the shallow lithospheric mantle (~110-115 km), above the diamond stability fi eld. These alkali-carbonate melts are preserved in primary multiphase inclusions hosted by large metasomatic ilmenite grains contained in a polymict mantle xenolith from the Bultfontein kimberlite (Kimberley, South Africa). The inclusions host abundant carbonates (magnesite, dolomite, and K-Na-Ca carbonates), kalsilite, phlogopite, K-Na titanates, and phosphates, with lesser amounts of olivine, chlorides, and alkali sulfates. Textural and chemical observations indicate that the alkali-carbonate melt likely derived from primary or precursor kimberlite magmas. Our fi ndings extend the evidence for alkali-carbonate melts/fl uids permeating the Earth mantle outside the diamond stability fi eld and provide new insights into the chemical features of previously hypothesized melts. As metasomatism by alkali-rich carbonate melts is often reported to affect mantle xenoliths, and predicted from experimental studies, the fl uid type documented here likely represent a major metasomatising agent in the Earth's lithospheric mantle. |
format |
Article in Journal/Newspaper |
author |
Giuliani, A. Kamenetsky, V. S. Phillips, D. Kendrick, M. A. Wyatt, B. A. Goemann, K. |
author_facet |
Giuliani, A. Kamenetsky, V. S. Phillips, D. Kendrick, M. A. Wyatt, B. A. Goemann, K. |
author_sort |
Giuliani, A. |
title |
Nature of alkali-carbonate fluids in the sub-continental lithospheric mantle |
title_short |
Nature of alkali-carbonate fluids in the sub-continental lithospheric mantle |
title_full |
Nature of alkali-carbonate fluids in the sub-continental lithospheric mantle |
title_fullStr |
Nature of alkali-carbonate fluids in the sub-continental lithospheric mantle |
title_full_unstemmed |
Nature of alkali-carbonate fluids in the sub-continental lithospheric mantle |
title_sort |
nature of alkali-carbonate fluids in the sub-continental lithospheric mantle |
publisher |
Geological Society of America |
publishDate |
2012 |
url |
https://espace.library.uq.edu.au/view/UQ:dbabf7c |
genre |
Yakutia |
genre_facet |
Yakutia |
op_relation |
doi:10.1130/G33221.1 issn:0091-7613 issn:1943-2682 orcid:0000-0002-6541-4162 |
op_doi |
https://doi.org/10.1130/G33221.1 |
container_title |
Geology |
container_volume |
40 |
container_issue |
11 |
container_start_page |
967 |
op_container_end_page |
970 |
_version_ |
1766236088131649536 |