Phase equilibria and methane enrichment of clathrate hydrates of mine ventilation air + tetrabutylphosphonium bromide
This paper reports the experimentally measured phase equilibrium conditions for the clathrate hydrates formed from simulated mine ventilation air (0.50 vol % CH + 99.50 vol % air) in the presence of 0, 5, 20, 37.1, and 50 wt % of tetrabutylphosphonium bromide (TBPB). These equilibrium conditions wer...
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American Chemical Society
2014
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ftunivqespace:oai:espace.library.uq.edu.au:UQ:328901 2023-05-15T17:12:02+02:00 Phase equilibria and methane enrichment of clathrate hydrates of mine ventilation air + tetrabutylphosphonium bromide Du, Jianwei Li, Huijuan Wang, Liguang 2014-01-01 https://espace.library.uq.edu.au/view/UQ:328901/lwang2_iecr.pdf https://espace.library.uq.edu.au/view/UQ:328901 eng eng American Chemical Society doi:10.1021/ie5000664 issn:0888-5885 issn:1520-5045 orcid:0000-0002-6153-2209 1092846 Ventilation air Gas hydrate Gas separation Methane hydrate 1500 Chemical Engineering 1600 Chemistry 2209 Industrial and Manufacturing Engineering Journal Article 2014 ftunivqespace https://doi.org/10.1021/ie5000664 2020-12-15T01:26:34Z This paper reports the experimentally measured phase equilibrium conditions for the clathrate hydrates formed from simulated mine ventilation air (0.50 vol % CH + 99.50 vol % air) in the presence of 0, 5, 20, 37.1, and 50 wt % of tetrabutylphosphonium bromide (TBPB). These equilibrium conditions were measured at the temperature range of 281.62-292.49 K and pressure range of 1.92-18.55 MPa by using an isochoric equilibrium step-heating pressure search method. The results showed that addition of TBPB allowed the hydrate dissociation condition for mine ventilation air to become milder, and at a given temperature, the lowest hydrate dissociation pressure was achieved at 37.1 wt % TBPB, corresponding to the stoichiometric composition for TBPB·32H O. For each TBPB concentration tested, the semilogarithmic plots of hydrate dissociation pressure versus reciprocal absolute temperature can be satisfactorily fitted to two straight lines intersecting at 6.5 MPa. The slopes of these fitted straight lines are indifferent to changes in TBPB concentration. Gas composition analysis by gas chromatography also found that in the presence of 37.1 wt % TBPB, CH could be enriched approximately 3.5-fold in the hydrate phase. Article in Journal/Newspaper Methane hydrate The University of Queensland: UQ eSpace Industrial & Engineering Chemistry Research 53 19 8182 8187 |
institution |
Open Polar |
collection |
The University of Queensland: UQ eSpace |
op_collection_id |
ftunivqespace |
language |
English |
topic |
Ventilation air Gas hydrate Gas separation Methane hydrate 1500 Chemical Engineering 1600 Chemistry 2209 Industrial and Manufacturing Engineering |
spellingShingle |
Ventilation air Gas hydrate Gas separation Methane hydrate 1500 Chemical Engineering 1600 Chemistry 2209 Industrial and Manufacturing Engineering Du, Jianwei Li, Huijuan Wang, Liguang Phase equilibria and methane enrichment of clathrate hydrates of mine ventilation air + tetrabutylphosphonium bromide |
topic_facet |
Ventilation air Gas hydrate Gas separation Methane hydrate 1500 Chemical Engineering 1600 Chemistry 2209 Industrial and Manufacturing Engineering |
description |
This paper reports the experimentally measured phase equilibrium conditions for the clathrate hydrates formed from simulated mine ventilation air (0.50 vol % CH + 99.50 vol % air) in the presence of 0, 5, 20, 37.1, and 50 wt % of tetrabutylphosphonium bromide (TBPB). These equilibrium conditions were measured at the temperature range of 281.62-292.49 K and pressure range of 1.92-18.55 MPa by using an isochoric equilibrium step-heating pressure search method. The results showed that addition of TBPB allowed the hydrate dissociation condition for mine ventilation air to become milder, and at a given temperature, the lowest hydrate dissociation pressure was achieved at 37.1 wt % TBPB, corresponding to the stoichiometric composition for TBPB·32H O. For each TBPB concentration tested, the semilogarithmic plots of hydrate dissociation pressure versus reciprocal absolute temperature can be satisfactorily fitted to two straight lines intersecting at 6.5 MPa. The slopes of these fitted straight lines are indifferent to changes in TBPB concentration. Gas composition analysis by gas chromatography also found that in the presence of 37.1 wt % TBPB, CH could be enriched approximately 3.5-fold in the hydrate phase. |
format |
Article in Journal/Newspaper |
author |
Du, Jianwei Li, Huijuan Wang, Liguang |
author_facet |
Du, Jianwei Li, Huijuan Wang, Liguang |
author_sort |
Du, Jianwei |
title |
Phase equilibria and methane enrichment of clathrate hydrates of mine ventilation air + tetrabutylphosphonium bromide |
title_short |
Phase equilibria and methane enrichment of clathrate hydrates of mine ventilation air + tetrabutylphosphonium bromide |
title_full |
Phase equilibria and methane enrichment of clathrate hydrates of mine ventilation air + tetrabutylphosphonium bromide |
title_fullStr |
Phase equilibria and methane enrichment of clathrate hydrates of mine ventilation air + tetrabutylphosphonium bromide |
title_full_unstemmed |
Phase equilibria and methane enrichment of clathrate hydrates of mine ventilation air + tetrabutylphosphonium bromide |
title_sort |
phase equilibria and methane enrichment of clathrate hydrates of mine ventilation air + tetrabutylphosphonium bromide |
publisher |
American Chemical Society |
publishDate |
2014 |
url |
https://espace.library.uq.edu.au/view/UQ:328901/lwang2_iecr.pdf https://espace.library.uq.edu.au/view/UQ:328901 |
genre |
Methane hydrate |
genre_facet |
Methane hydrate |
op_relation |
doi:10.1021/ie5000664 issn:0888-5885 issn:1520-5045 orcid:0000-0002-6153-2209 1092846 |
op_doi |
https://doi.org/10.1021/ie5000664 |
container_title |
Industrial & Engineering Chemistry Research |
container_volume |
53 |
container_issue |
19 |
container_start_page |
8182 |
op_container_end_page |
8187 |
_version_ |
1766068795318730752 |