Rare earth elements and yttrium in a stalagmite from Central China and potential paleoclimatic implications
In a pilot study, the rare earth elements and yttrium (REE when discussed without Y or REY with Y) were measured by inductively-coupled plasma mass spectrometry (ICP-MS) on a stalagmite (SJ3) from northeast Sichuan, Central China. This stalagmite was dated by the thermal ionization mass spectrometry...
Published in: | Palaeogeography, Palaeoclimatology, Palaeoecology |
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ftunivqespace:oai:espace.library.uq.edu.au:UQ:167111 2023-05-15T17:37:05+02:00 Rare earth elements and yttrium in a stalagmite from Central China and potential paleoclimatic implications Zhou, Z. H. Wang, Q. Zhao, J. X. Zheng, L. N. Guan, H. Z. Feng, Y. X. Greig, A. 2008-12-01 https://espace.library.uq.edu.au/view/UQ:167111 eng eng Elsevier Science Bv doi:10.1016/j.palaeo.2008.09.001 issn:0031-0182 orcid:0000-0002-2413-6178 orcid:0000-0002-2944-9632 40672120 KZCX3-SW-152 SKLLQG0408 LP0453664 Geography Physical Geosciences Multidisciplinary Paleontology Physical Geography Geology C1 960304 Climate Variability (excl. Social Impacts) 040303 Geochronology Journal Article 2008 ftunivqespace https://doi.org/10.1016/j.palaeo.2008.09.001 2020-08-31T22:46:07Z In a pilot study, the rare earth elements and yttrium (REE when discussed without Y or REY with Y) were measured by inductively-coupled plasma mass spectrometry (ICP-MS) on a stalagmite (SJ3) from northeast Sichuan, Central China. This stalagmite was dated by the thermal ionization mass spectrometry (TIMS) Th-230 method to between 38 and 10 thousand years before present (ka BP). The REY geochemical indices, including the concentrations, Lanthanum, Cerium and Yttrium anomalies and the fractionation between light and heavy REE (LREE and HREE), display significant stadial-interstadial changes corresponding to variations in past climates and environments. The North American Shale Composite (NASC)-normalized REY patterns for sub-samples of SJ3 display obvious negative Ce anomalies and positive Y anomalies. For most sub-samples, the LREE are relatively depleted relative to the HREE. La anomalies during relatively cold and dry climatic phases (including the last glacial maximum (LGM) and the period synchronous with Heinrich event one identified in the North Atlantic region) are usually positive, while the Ce and Yanomalies and the LREE-HREE fractionation are more pronounced. During relatively warm and humid phases the REY pattern displays an opposite signature. The REY sources for SJ3 include the overlying soil layer, which consists mainly of aeolian sediments. and the host rock of the Late Permian limestone. Source change may be the primary mechanism controlling the variations of the REY pattern for SJ3. The REY pattern for the youngest sub-sample from the top dirty section of SJ3, which is porous and rich in detrital materials, seems to be dominated by the overlying soil layer. The REY in sub-samples deposited during relatively cold and dry phases may come mainly from the host limestone and thus show patterns more similar to a marine signal. For the rest of the sub-samples, REY from both sources may be present. In addition to the sources, the REY pattern for SJ3 may also be influenced by REY mobilization from sources and transportation in groundwater. and prior carbonate deposition, all of which should be closely related with changes in climate and environment. Thus the REY pattern for speleothems might be a potential proxy for past climate and environment. (C) 2008 Elsevier B.V. All rights reserved. Article in Journal/Newspaper North Atlantic The University of Queensland: UQ eSpace Palaeogeography, Palaeoclimatology, Palaeoecology 270 1-2 128 138 |
institution |
Open Polar |
collection |
The University of Queensland: UQ eSpace |
op_collection_id |
ftunivqespace |
language |
English |
topic |
Geography Physical Geosciences Multidisciplinary Paleontology Physical Geography Geology C1 960304 Climate Variability (excl. Social Impacts) 040303 Geochronology |
spellingShingle |
Geography Physical Geosciences Multidisciplinary Paleontology Physical Geography Geology C1 960304 Climate Variability (excl. Social Impacts) 040303 Geochronology Zhou, Z. H. Wang, Q. Zhao, J. X. Zheng, L. N. Guan, H. Z. Feng, Y. X. Greig, A. Rare earth elements and yttrium in a stalagmite from Central China and potential paleoclimatic implications |
topic_facet |
Geography Physical Geosciences Multidisciplinary Paleontology Physical Geography Geology C1 960304 Climate Variability (excl. Social Impacts) 040303 Geochronology |
description |
In a pilot study, the rare earth elements and yttrium (REE when discussed without Y or REY with Y) were measured by inductively-coupled plasma mass spectrometry (ICP-MS) on a stalagmite (SJ3) from northeast Sichuan, Central China. This stalagmite was dated by the thermal ionization mass spectrometry (TIMS) Th-230 method to between 38 and 10 thousand years before present (ka BP). The REY geochemical indices, including the concentrations, Lanthanum, Cerium and Yttrium anomalies and the fractionation between light and heavy REE (LREE and HREE), display significant stadial-interstadial changes corresponding to variations in past climates and environments. The North American Shale Composite (NASC)-normalized REY patterns for sub-samples of SJ3 display obvious negative Ce anomalies and positive Y anomalies. For most sub-samples, the LREE are relatively depleted relative to the HREE. La anomalies during relatively cold and dry climatic phases (including the last glacial maximum (LGM) and the period synchronous with Heinrich event one identified in the North Atlantic region) are usually positive, while the Ce and Yanomalies and the LREE-HREE fractionation are more pronounced. During relatively warm and humid phases the REY pattern displays an opposite signature. The REY sources for SJ3 include the overlying soil layer, which consists mainly of aeolian sediments. and the host rock of the Late Permian limestone. Source change may be the primary mechanism controlling the variations of the REY pattern for SJ3. The REY pattern for the youngest sub-sample from the top dirty section of SJ3, which is porous and rich in detrital materials, seems to be dominated by the overlying soil layer. The REY in sub-samples deposited during relatively cold and dry phases may come mainly from the host limestone and thus show patterns more similar to a marine signal. For the rest of the sub-samples, REY from both sources may be present. In addition to the sources, the REY pattern for SJ3 may also be influenced by REY mobilization from sources and transportation in groundwater. and prior carbonate deposition, all of which should be closely related with changes in climate and environment. Thus the REY pattern for speleothems might be a potential proxy for past climate and environment. (C) 2008 Elsevier B.V. All rights reserved. |
format |
Article in Journal/Newspaper |
author |
Zhou, Z. H. Wang, Q. Zhao, J. X. Zheng, L. N. Guan, H. Z. Feng, Y. X. Greig, A. |
author_facet |
Zhou, Z. H. Wang, Q. Zhao, J. X. Zheng, L. N. Guan, H. Z. Feng, Y. X. Greig, A. |
author_sort |
Zhou, Z. H. |
title |
Rare earth elements and yttrium in a stalagmite from Central China and potential paleoclimatic implications |
title_short |
Rare earth elements and yttrium in a stalagmite from Central China and potential paleoclimatic implications |
title_full |
Rare earth elements and yttrium in a stalagmite from Central China and potential paleoclimatic implications |
title_fullStr |
Rare earth elements and yttrium in a stalagmite from Central China and potential paleoclimatic implications |
title_full_unstemmed |
Rare earth elements and yttrium in a stalagmite from Central China and potential paleoclimatic implications |
title_sort |
rare earth elements and yttrium in a stalagmite from central china and potential paleoclimatic implications |
publisher |
Elsevier Science Bv |
publishDate |
2008 |
url |
https://espace.library.uq.edu.au/view/UQ:167111 |
genre |
North Atlantic |
genre_facet |
North Atlantic |
op_relation |
doi:10.1016/j.palaeo.2008.09.001 issn:0031-0182 orcid:0000-0002-2413-6178 orcid:0000-0002-2944-9632 40672120 KZCX3-SW-152 SKLLQG0408 LP0453664 |
op_doi |
https://doi.org/10.1016/j.palaeo.2008.09.001 |
container_title |
Palaeogeography, Palaeoclimatology, Palaeoecology |
container_volume |
270 |
container_issue |
1-2 |
container_start_page |
128 |
op_container_end_page |
138 |
_version_ |
1766136808066777088 |