Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization

[EN] In this study, the phosphonation of a polyaniline (PANI) backbone was achieved in an acid medium by electrochemical methods using aminophenylphosphonic (APPA) monomers. This was done through the electrochemical copolymerization of aniline with either 2- or 4-aminophenylphosphonic acid. Stable,...

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Published in:Polymers
Main Authors: Martínez-Sánchez, Beatriz, Quintero-Jaime, Andrés Felipe, Huerta, Francisco, Cazorla-Amorós, Diego, Morallón, Emilia
Other Authors: Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera, Generalitat Valenciana, Universidad de Alicante, European Regional Development Fund, Ministerio de Economía y Competitividad, Agencia Estatal de Investigación
Format: Article in Journal/Newspaper
Language:English
Published: MDPI AG 2020
Subjects:
Polyaniline
Phosphorus
Electrochemical polymerization
Modified polyaniline
QUIMICA FISICA
Martínez
Quintero
sami
Online Access:http://hdl.handle.net/10251/162601
https://doi.org/10.3390/polym12051029
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collection Politechnical University of Valencia: RiuNet
op_collection_id ftunivpvalencia
language English
topic Polyaniline
Phosphorus
Electrochemical polymerization
Modified polyaniline
QUIMICA FISICA
spellingShingle Polyaniline
Phosphorus
Electrochemical polymerization
Modified polyaniline
QUIMICA FISICA
Martínez-Sánchez, Beatriz
Quintero-Jaime, Andrés Felipe
Huerta, Francisco
Cazorla-Amorós, Diego
Morallón, Emilia
Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization
topic_facet Polyaniline
Phosphorus
Electrochemical polymerization
Modified polyaniline
QUIMICA FISICA
description [EN] In this study, the phosphonation of a polyaniline (PANI) backbone was achieved in an acid medium by electrochemical methods using aminophenylphosphonic (APPA) monomers. This was done through the electrochemical copolymerization of aniline with either 2- or 4-aminophenylphosphonic acid. Stable, electroactive polymers were obtained after the oxidation of the monomers up to 1.35 V (reversible hydrogen electrode, RHE). X-ray photoelectron spectroscopy (XPS) results revealed that the position of the phosphonic group in the aromatic ring of the monomer affected the amount of phosphorus incorporated into the copolymer. In addition, the redox transitions of the copolymers were examined by in situ Fourier-transform infrared (FTIR) spectroscopy, and it was concluded that their electroactive structures were analogous to those of PANI. From the APPA monomers it was possible to synthesize, in a controlled manner, polymeric materials with significant amounts of phosphorus in their structure through copolymerization with PANI. The authors would like to thank MINECO, FEDER (MAT2016-76595-R) for financial support. A.F.Q.-J. gratefully acknowledges the Generalitat Valenciana for the financial support through the Santiago Grisolia grant (GRISOLIA/2016/084). B.M.-S. acknowledges the Vice-rectorate for Research and Knowledge Transfer of University of Alicante for financial support (AII2018-16), as well as the Spanish Ministry of Science, Innovation and Universities for the FPU grant (FPU18/05127). Martínez-Sánchez, B.; Quintero-Jaime, AF.; Huerta, F.; Cazorla-Amorós, D.; Morallón, E. (2020). Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization. Polymers. 12(5):1-16. https://doi.org/10.3390/polym12051029 S 1 16 12 5 A Review on Conducting Polymers-Based Composites for Energy Storage Application. (2019). Journal of Chemical Reviews, 1(1), 19-34. doi:10.33945/sami/jcr.2019.1.1934 Ćirić-Marjanović, G. (2013). Recent advances in polyaniline research: Polymerization mechanisms, ...
author2 Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera
Generalitat Valenciana
Universidad de Alicante
European Regional Development Fund
Ministerio de Economía y Competitividad
Agencia Estatal de Investigación
format Article in Journal/Newspaper
author Martínez-Sánchez, Beatriz
Quintero-Jaime, Andrés Felipe
Huerta, Francisco
Cazorla-Amorós, Diego
Morallón, Emilia
author_facet Martínez-Sánchez, Beatriz
Quintero-Jaime, Andrés Felipe
Huerta, Francisco
Cazorla-Amorós, Diego
Morallón, Emilia
author_sort Martínez-Sánchez, Beatriz
title Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization
title_short Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization
title_full Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization
title_fullStr Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization
title_full_unstemmed Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization
title_sort synthesis of phosphorus-containing polyanilines by electrochemical copolymerization
publisher MDPI AG
publishDate 2020
url http://hdl.handle.net/10251/162601
https://doi.org/10.3390/polym12051029
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genre_facet sami
op_relation Polymers
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spelling ftunivpvalencia:oai:riunet.upv.es:10251/162601 2023-05-15T18:13:07+02:00 Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization Martínez-Sánchez, Beatriz Quintero-Jaime, Andrés Felipe Huerta, Francisco Cazorla-Amorós, Diego Morallón, Emilia Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera Generalitat Valenciana Universidad de Alicante European Regional Development Fund Ministerio de Economía y Competitividad Agencia Estatal de Investigación 2020-05 http://hdl.handle.net/10251/162601 https://doi.org/10.3390/polym12051029 eng eng MDPI AG Polymers info:eu-repo/grantAgreement/MINECO//MAT2016-76595-R/ES/NUEVAS ESTRATEGIAS DE FUNCIONALIZACION ELECTROQUIMICA DE MATERIALES CARBONOSOS NANOESTRUCTURADOS PARA LA REDUCCION DE OXIGENO Y BIOSENSORES/ info:eu-repo/grantAgreement/GVA//GRISOLIA%2F2016%2F084/ info:eu-repo/grantAgreement/UA//AII2018-16/ info:eu-repo/grantAgreement/AEI//FPU18%2F05127/ https://doi.org/10.3390/polym12051029 10.33945/SAMI/JCR.2019.1.1934 10.1016/j.synthmet.2013.06.004 10.1016/j.progpolymsci.2013.05.015 10.1021/jp908239m 10.1021/jp3090777 10.1016/B978-0-08-100789-1.00008-3 10.1021/nn400482d 10.1039/C8CC02105H 10.2478/s11696-013-0312-1 10.1016/j.polymer.2019.122129 10.1016/j.jpowsour.2003.08.008 10.1016/j.polymer.2018.04.008 10.1016/j.porgcoat.2019.105470 10.1016/B978-0-12-821381-0.00012-0 10.1016/j.eurpolymj.2004.10.047 10.1016/j.synthmet.2018.08.005 10.1016/j.electacta.2006.09.031 10.1007/s13726-011-0011-0 10.1021/ja00163a051 10.1016/j.synthmet.2010.11.034 10.1021/ma00205a011 10.1002/macp.1997.021980515 10.1016/j.jelechem.2003.11.005 10.1016/j.synthmet.2003.12.008 10.1016/j.polymer.2006.12.021 10.1016/j.electacta.2020.135935 10.1016/j.jallcom.2020.154638 10.1039/C9CC09279J 10.1039/C7RA04678B 10.1166/jnn.2013.8118 10.1016/j.eurpolymj.2019.07.048 10.1016/j.matlet.2019.127092 10.1016/j.tetlet.2014.04.115 10.1021/ja00138a004 10.1021/la050682+ 10.1021/cm802123a 10.1016/0022-0728(92)80466-H 10.1143/JJAP.50.081606 10.1016/j.polymer.2004.12.008 10.1149/1.2198010 10.1351/PAC-REP-10-02-01 10.1016/0022-0728(89)80104-4 10.1016/j.eurpolymj.2017.04.024 10.1016/j.carbon.2008.09.010 http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess CC-BY Polyaniline Phosphorus Electrochemical polymerization Modified polyaniline QUIMICA FISICA info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion 2020 ftunivpvalencia https://doi.org/10.3390/polym12051029 2022-06-12T20:55:45Z [EN] In this study, the phosphonation of a polyaniline (PANI) backbone was achieved in an acid medium by electrochemical methods using aminophenylphosphonic (APPA) monomers. This was done through the electrochemical copolymerization of aniline with either 2- or 4-aminophenylphosphonic acid. Stable, electroactive polymers were obtained after the oxidation of the monomers up to 1.35 V (reversible hydrogen electrode, RHE). X-ray photoelectron spectroscopy (XPS) results revealed that the position of the phosphonic group in the aromatic ring of the monomer affected the amount of phosphorus incorporated into the copolymer. In addition, the redox transitions of the copolymers were examined by in situ Fourier-transform infrared (FTIR) spectroscopy, and it was concluded that their electroactive structures were analogous to those of PANI. From the APPA monomers it was possible to synthesize, in a controlled manner, polymeric materials with significant amounts of phosphorus in their structure through copolymerization with PANI. The authors would like to thank MINECO, FEDER (MAT2016-76595-R) for financial support. A.F.Q.-J. gratefully acknowledges the Generalitat Valenciana for the financial support through the Santiago Grisolia grant (GRISOLIA/2016/084). B.M.-S. acknowledges the Vice-rectorate for Research and Knowledge Transfer of University of Alicante for financial support (AII2018-16), as well as the Spanish Ministry of Science, Innovation and Universities for the FPU grant (FPU18/05127). Martínez-Sánchez, B.; Quintero-Jaime, AF.; Huerta, F.; Cazorla-Amorós, D.; Morallón, E. (2020). Synthesis of Phosphorus-Containing Polyanilines by Electrochemical Copolymerization. Polymers. 12(5):1-16. https://doi.org/10.3390/polym12051029 S 1 16 12 5 A Review on Conducting Polymers-Based Composites for Energy Storage Application. (2019). Journal of Chemical Reviews, 1(1), 19-34. doi:10.33945/sami/jcr.2019.1.1934 Ćirić-Marjanović, G. (2013). Recent advances in polyaniline research: Polymerization mechanisms, ... Article in Journal/Newspaper sami Politechnical University of Valencia: RiuNet Martínez ENVELOPE(-62.183,-62.183,-64.650,-64.650) Quintero ENVELOPE(-62.000,-62.000,-64.683,-64.683) Polymers 12 5 1029

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