Catalytic Reductive N-Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments
This is the peer reviewed version of the following article: Angew. Chem. Int. Ed. 2019, 58, 12820 12838, which has been published in final form at https://doi.org/10.1002/anie.201810121. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archi...
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John Wiley & Sons
2019
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Online Access: | http://hdl.handle.net/10251/153458 https://doi.org/10.1002/anie.201810121 |
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Carbon dioxide Carboxylic Carbonic acid derivatives Heterocycles N-alkylation Reductive transformations QUIMICA ORGANICA |
spellingShingle |
Carbon dioxide Carboxylic Carbonic acid derivatives Heterocycles N-alkylation Reductive transformations QUIMICA ORGANICA Cabrero Antonino, Jose Ramón Adam-Ortiz, Rosa Beller, Matthias Catalytic Reductive N-Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments |
topic_facet |
Carbon dioxide Carboxylic Carbonic acid derivatives Heterocycles N-alkylation Reductive transformations QUIMICA ORGANICA |
description |
This is the peer reviewed version of the following article: Angew. Chem. Int. Ed. 2019, 58, 12820 12838, which has been published in final form at https://doi.org/10.1002/anie.201810121. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. [EN] N-Alkylamines are key intermediates in the synthesis of fine chemicals, dyes, and natural products, and hence are highly valuable building blocks in organic chemistry. Consequently, the development of greener and more efficient procedures for their production continues to attract the interest of both academic and industrial chemists. Reductive procedures such as reductive amination or N-alkylation through hydrogen autotransfer by employing carbonyl compounds or alcohols as alkylating agents have prevailed for the synthesis of amines. In the last few years, carboxylic/carbonic acid derivatives and CO2 have been introduced as alternative and convenient alkylating sources. The safety, easy accessibility, and high stability of these reagents makes the development of new reductive transformations with them as N-alkylating agents a useful alternative to existing procedures. In this Review, we summarize reported examples of one-pot reductive N-alkylation methods that use carboxylic/carbonic acid derivatives or CO2 as alkylating agents. This work was supported by the state of MecklenburgVorpommern and the BMBF. J.R.C.-A. thanks the Ministerio de Ciencia, Innovacion y Universidades for a Juan de la Cierva contract. R.A. thanks UPV for a postdoctoral contract. Cabrero Antonino, JR.; Adam-Ortiz, R.; Beller, M. (2019). Catalytic Reductive N-Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments. Angewandte Chemie International Edition. 58(37):12820-12838. https://doi.org/10.1002/anie.201810121 S 12820 12838 58 37 Adams, J. M., & Cory, S. (1975). Modified nucleosides and bizarre 5′-termini in mouse myeloma mRNA. Nature, 255(5503), 28-33. doi:10.1038/255028a0 ... |
author2 |
Universitat Politècnica de València. Departamento de Química - Departament de Química Bundesministerium für Bildung und Forschung, Alemania |
format |
Article in Journal/Newspaper |
author |
Cabrero Antonino, Jose Ramón Adam-Ortiz, Rosa Beller, Matthias |
author_facet |
Cabrero Antonino, Jose Ramón Adam-Ortiz, Rosa Beller, Matthias |
author_sort |
Cabrero Antonino, Jose Ramón |
title |
Catalytic Reductive N-Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments |
title_short |
Catalytic Reductive N-Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments |
title_full |
Catalytic Reductive N-Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments |
title_fullStr |
Catalytic Reductive N-Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments |
title_full_unstemmed |
Catalytic Reductive N-Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments |
title_sort |
catalytic reductive n-alkylations using co2 and carboxylic acid derivatives: recent progress and developments |
publisher |
John Wiley & Sons |
publishDate |
2019 |
url |
http://hdl.handle.net/10251/153458 https://doi.org/10.1002/anie.201810121 |
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ENVELOPE(-60.873,-60.873,-64.156,-64.156) ENVELOPE(-59.717,-59.717,-62.450,-62.450) |
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Cierva Ortiz |
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Cierva Ortiz |
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Carbonic acid |
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Carbonic acid |
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ftunivpvalencia:oai:riunet.upv.es:10251/153458 2023-05-15T15:52:30+02:00 Catalytic Reductive N-Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments Cabrero Antonino, Jose Ramón Adam-Ortiz, Rosa Beller, Matthias Universitat Politècnica de València. Departamento de Química - Departament de Química Bundesministerium für Bildung und Forschung, Alemania 2019-09-09 http://hdl.handle.net/10251/153458 https://doi.org/10.1002/anie.201810121 eng eng John Wiley & Sons Angewandte Chemie International Edition https://doi.org/10.1002/anie.201810121 10.1038/255028a0 10.1055/b-003-108611 10.1038/nature11112 10.1002/anie.201205674 10.1002/ange.201205674 10.1021/acs.chemrev.6b00486 10.1016/S0040-4020(01)00722-0 10.3998/ark.5550190.0010.108 10.1002/anie.201507219 10.1002/ange.201507219 10.1039/p29920000519 10.1080/00397919708003343 10.1021/bk-1996-0626.ch006 10.1016/S0926-860X(96)00402-4 10.1021/ef9600974 10.1016/S0926-860X(01)00796-7 10.1021/ar010076f 10.1021/jo034548a 10.1021/jo048532b 10.1021/jo060674d 10.1351/pac200779111855 10.1039/b713985c 10.1016/j.apcata.2010.01.042 10.1016/j.bmcl.2009.10.124 10.1002/chem.201303802 10.1002/cctc.201400015 10.1002/cber.190503801154 10.1021/ja01338a041 10.1021/jo00211a028 10.1016/S0040-4039(00)76894-8 10.1002/1615-4169(200212)344:10 1037::AID-ADSC1037>3.0.CO;2-3 10.1021/ja905143m 10.1002/anie.201001715 10.1002/ange.201001715 10.1002/anie.201400059 10.1002/ange.201400059 10.1039/C4OB00620H 10.1126/science.aan6245 10.1246/bcsj.58.1551 10.1039/C5SC00941C 10.1021/acscatal.6b01687 10.1039/C6RA22383D 10.1002/(SICI)1521-3773(19990816)38:16 2372::AID-ANIE2372>3.0.CO;2-H 10.1002/(SICI)1521-3757(19990816)111:16 2515::AID-ANGE2515>3.0.CO;2-A 10.1126/science.1076371 10.1021/ja030143w 10.1002/chem.200601155 10.1002/cctc.201000411 http://rightsstatements.org/vocab/InC/1.0/ info:eu-repo/semantics/openAccess Carbon dioxide Carboxylic Carbonic acid derivatives Heterocycles N-alkylation Reductive transformations QUIMICA ORGANICA info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion 2019 ftunivpvalencia https://doi.org/10.1002/anie.201810121 2022-06-12T20:54:29Z This is the peer reviewed version of the following article: Angew. Chem. Int. Ed. 2019, 58, 12820 12838, which has been published in final form at https://doi.org/10.1002/anie.201810121. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. [EN] N-Alkylamines are key intermediates in the synthesis of fine chemicals, dyes, and natural products, and hence are highly valuable building blocks in organic chemistry. Consequently, the development of greener and more efficient procedures for their production continues to attract the interest of both academic and industrial chemists. Reductive procedures such as reductive amination or N-alkylation through hydrogen autotransfer by employing carbonyl compounds or alcohols as alkylating agents have prevailed for the synthesis of amines. In the last few years, carboxylic/carbonic acid derivatives and CO2 have been introduced as alternative and convenient alkylating sources. The safety, easy accessibility, and high stability of these reagents makes the development of new reductive transformations with them as N-alkylating agents a useful alternative to existing procedures. In this Review, we summarize reported examples of one-pot reductive N-alkylation methods that use carboxylic/carbonic acid derivatives or CO2 as alkylating agents. This work was supported by the state of MecklenburgVorpommern and the BMBF. J.R.C.-A. thanks the Ministerio de Ciencia, Innovacion y Universidades for a Juan de la Cierva contract. R.A. thanks UPV for a postdoctoral contract. Cabrero Antonino, JR.; Adam-Ortiz, R.; Beller, M. (2019). Catalytic Reductive N-Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments. Angewandte Chemie International Edition. 58(37):12820-12838. https://doi.org/10.1002/anie.201810121 S 12820 12838 58 37 Adams, J. M., & Cory, S. (1975). Modified nucleosides and bizarre 5′-termini in mouse myeloma mRNA. Nature, 255(5503), 28-33. doi:10.1038/255028a0 ... Article in Journal/Newspaper Carbonic acid Politechnical University of Valencia: RiuNet Cierva ENVELOPE(-60.873,-60.873,-64.156,-64.156) Ortiz ENVELOPE(-59.717,-59.717,-62.450,-62.450) Angewandte Chemie International Edition 58 37 12820 12838 |