The impact of vegetation on REE fractionation in stream waters of a small forested catchment ( the Strengbach case )

• Published in: Geochimica et Cosmochimica Acta
• Main Authors: Stille, Peter, Steinmann, Marc, Pierret, Marie-Claire, Gauthier-Lafaye, François, Chabaux, François, Viville, Daniel, Pourcelot, L., Matera, Virginie, Aouad, Georges, Aubert, Dominique
• Other Authors: Centre de géochimie de la surface (CGS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Louis Pasteur - Strasbourg I-Centre National de la Recherche Scientifique (CNRS), Laboratoire Chrono-environnement (UMR 6249) (LCE), Centre National de la Recherche Scientifique (CNRS)-Université de Franche-Comté (UFC), Université Bourgogne Franche-Comté COMUE (UBFC)-Université Bourgogne Franche-Comté COMUE (UBFC), Institut de Radioprotection et de Sûreté Nucléaire (IRSN), Institut de Géologie et d'Hydrogéologie, Université de Neuchâtel = University of Neuchatel (UNINE), Centre de Formation et de Recherche sur les Environnements Méditérranéens (CEFREM), Université de Perpignan Via Domitia (UPVD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), UMR 6249 Chrono-environnement
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2006
• Subjects: [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry; [SDE.MCG]Environmental Sciences/Global Changes; Arctic
• Online Access: https://hal.science/hal-00446947; https://doi.org/10.1016/j.gca.2006.04.028

International audience Previous studies on waters of a streamlet in the Vosges Mountains (Eastern France) have shown that strontium and rare earth elements (REE) mainly originate from preferential dissolution of apatite during weathering. However, stream water REE patterns normalized to apatite are still depleted in the light REE (LREE, La–Sm) pointing to the presence of an additional LREE depleting process. Vegetation samples are strongly enriched in LREE compared to stream water and their Sr and Nd isotopic compositions are comparable with those of apatite and stream water. Thus, the preferential LREE uptake by vegetation might lead to an additional LREE depletion of surface runoff in the forested catchment. Mass balance calculations indicate, that the yearly LREE uptake by vegetation is comparable with the LREE export by the streamlet and, therefore, might be an important factor controlling LREE depletion in river water. This is underlined by the observation that rivers from arctic and boreal regions with sparse vegetation appear to be less depleted in LREE than rivers from tropical environments or boreal environments with a dense vegetation cover.