Evaluation of the Effect of Chemical or Enzymatic Synthesis Methods on Biodegradability of Polyesters
International audience This work compares the biodegradability of polyesters produced by an esterification reaction between glycerol and oleic di-acid (D 18:1) issued from green chemical pathways, via either classical thermo-chemical methods, or an enzymatic method using the immobilized lipase of Ca...
Published in: | Journal of Polymers and the Environment |
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Main Authors: | , , , , , , , , |
Other Authors: | , , , , , , , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
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HAL CCSD
2016
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Subjects: | |
Online Access: | https://hal.sorbonne-universite.fr/hal-01285524 https://hal.sorbonne-universite.fr/hal-01285524/document https://hal.sorbonne-universite.fr/hal-01285524/file/Goujard_2015_Evaluation_of_the.pdf https://doi.org/10.1007/s10924-015-0742-7 |
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ftunivparisseine:oai:HAL:hal-01285524v1 |
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openpolar |
institution |
Open Polar |
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Université Paris Seine: ComUE (HAL) |
op_collection_id |
ftunivparisseine |
language |
English |
topic |
Chemical polyesters Enzymatic polyesters Biodegradability [CHIM]Chemical Sciences |
spellingShingle |
Chemical polyesters Enzymatic polyesters Biodegradability [CHIM]Chemical Sciences Goujard, Laurent Roumanet, Pierre-Jean Barea, Bruno Raoul, Yann Ziarelli, Fabio Le Petit, Jean Jarroux, Nathalie Ferré, Elisée Guégan, Philippe Evaluation of the Effect of Chemical or Enzymatic Synthesis Methods on Biodegradability of Polyesters |
topic_facet |
Chemical polyesters Enzymatic polyesters Biodegradability [CHIM]Chemical Sciences |
description |
International audience This work compares the biodegradability of polyesters produced by an esterification reaction between glycerol and oleic di-acid (D 18:1) issued from green chemical pathways, via either classical thermo-chemical methods, or an enzymatic method using the immobilized lipase of Candida antartica B (Novozym 435). An elastomeric polymer synthesized by enzymatic catalysis is more biodegradable than an elastomeric thermo-chemical polyester synthesized by a standard chemical procedure. This difference lies in percentage of the dendritic motifs, in values of the degree of substitution, and certainly in cross-links inducing an hyper-branched structure less accessible to the lipolytic enzymes in a waste treatment plant. However, when the elastomeric polymer synthesized by enzymatic catalysis is processed at high temperature as required for certain industrial applications, it presents an identical rate of biodegradation than the chemical polyester. The advantages of the thermo-chemical methods are greater speed and lower cost. Enzymatic synthesis appears be suited to producing polyesters, devoid of metallic catalysts, which must be used without processing at high temperature to keep a high biodegradability. |
author2 |
Institut méditerranéen de biodiversité et d'écologie marine et continentale (IMBE) Avignon Université (AU)-Aix Marseille Université (AMU)-Institut de recherche pour le développement IRD : UMR237-Centre National de la Recherche Scientifique (CNRS) Laboratoire Analyse et Modélisation pour la Biologie et l'Environnement (LAMBE) Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Cergy Pontoise (UCP) Université Paris-Seine-Université Paris-Seine-Université d'Évry-Val-d'Essonne (UEVE)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) Ingénierie des Agro-polymères et Technologies Émergentes (UMR IATE) Centre de Coopération Internationale en Recherche Agronomique pour le Développement (Cirad)-Institut National de la Recherche Agronomique (INRA)-Université Montpellier 2 - Sciences et Techniques (UM2)-Centre international d'études supérieures en sciences agronomiques (Montpellier SupAgro)-Université de Montpellier (UM)-Institut national d’études supérieures agronomiques de Montpellier (Montpellier SupAgro) Organisation Nationale Interprofessionnelle des Graines et Fruits Oléagineux (ONIDOL) ONIDOL Fédération des Sciences Chimiques de Marseille (FSCM) Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) Institut Parisien de Chimie Moléculaire (IPCM) Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) |
format |
Article in Journal/Newspaper |
author |
Goujard, Laurent Roumanet, Pierre-Jean Barea, Bruno Raoul, Yann Ziarelli, Fabio Le Petit, Jean Jarroux, Nathalie Ferré, Elisée Guégan, Philippe |
author_facet |
Goujard, Laurent Roumanet, Pierre-Jean Barea, Bruno Raoul, Yann Ziarelli, Fabio Le Petit, Jean Jarroux, Nathalie Ferré, Elisée Guégan, Philippe |
author_sort |
Goujard, Laurent |
title |
Evaluation of the Effect of Chemical or Enzymatic Synthesis Methods on Biodegradability of Polyesters |
title_short |
Evaluation of the Effect of Chemical or Enzymatic Synthesis Methods on Biodegradability of Polyesters |
title_full |
Evaluation of the Effect of Chemical or Enzymatic Synthesis Methods on Biodegradability of Polyesters |
title_fullStr |
Evaluation of the Effect of Chemical or Enzymatic Synthesis Methods on Biodegradability of Polyesters |
title_full_unstemmed |
Evaluation of the Effect of Chemical or Enzymatic Synthesis Methods on Biodegradability of Polyesters |
title_sort |
evaluation of the effect of chemical or enzymatic synthesis methods on biodegradability of polyesters |
publisher |
HAL CCSD |
publishDate |
2016 |
url |
https://hal.sorbonne-universite.fr/hal-01285524 https://hal.sorbonne-universite.fr/hal-01285524/document https://hal.sorbonne-universite.fr/hal-01285524/file/Goujard_2015_Evaluation_of_the.pdf https://doi.org/10.1007/s10924-015-0742-7 |
genre |
antartic* |
genre_facet |
antartic* |
op_source |
ISSN: 1566-2543 EISSN: 1572-8900 Journal of Polymers and the Environment https://hal.sorbonne-universite.fr/hal-01285524 Journal of Polymers and the Environment, 2016, 24 (1), pp.64-71. ⟨10.1007/s10924-015-0742-7⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10924-015-0742-7 hal-01285524 https://hal.sorbonne-universite.fr/hal-01285524 https://hal.sorbonne-universite.fr/hal-01285524/document https://hal.sorbonne-universite.fr/hal-01285524/file/Goujard_2015_Evaluation_of_the.pdf doi:10.1007/s10924-015-0742-7 PRODINRA: 355883 WOS: 000371296400007 |
op_rights |
info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.1007/s10924-015-0742-7 |
container_title |
Journal of Polymers and the Environment |
container_volume |
24 |
container_issue |
1 |
container_start_page |
64 |
op_container_end_page |
71 |
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1798837215780929536 |
spelling |
ftunivparisseine:oai:HAL:hal-01285524v1 2024-05-12T07:56:52+00:00 Evaluation of the Effect of Chemical or Enzymatic Synthesis Methods on Biodegradability of Polyesters Goujard, Laurent Roumanet, Pierre-Jean Barea, Bruno Raoul, Yann Ziarelli, Fabio Le Petit, Jean Jarroux, Nathalie Ferré, Elisée Guégan, Philippe Institut méditerranéen de biodiversité et d'écologie marine et continentale (IMBE) Avignon Université (AU)-Aix Marseille Université (AMU)-Institut de recherche pour le développement IRD : UMR237-Centre National de la Recherche Scientifique (CNRS) Laboratoire Analyse et Modélisation pour la Biologie et l'Environnement (LAMBE) Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Cergy Pontoise (UCP) Université Paris-Seine-Université Paris-Seine-Université d'Évry-Val-d'Essonne (UEVE)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) Ingénierie des Agro-polymères et Technologies Émergentes (UMR IATE) Centre de Coopération Internationale en Recherche Agronomique pour le Développement (Cirad)-Institut National de la Recherche Agronomique (INRA)-Université Montpellier 2 - Sciences et Techniques (UM2)-Centre international d'études supérieures en sciences agronomiques (Montpellier SupAgro)-Université de Montpellier (UM)-Institut national d’études supérieures agronomiques de Montpellier (Montpellier SupAgro) Organisation Nationale Interprofessionnelle des Graines et Fruits Oléagineux (ONIDOL) ONIDOL Fédération des Sciences Chimiques de Marseille (FSCM) Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) Institut Parisien de Chimie Moléculaire (IPCM) Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) 2016-03 https://hal.sorbonne-universite.fr/hal-01285524 https://hal.sorbonne-universite.fr/hal-01285524/document https://hal.sorbonne-universite.fr/hal-01285524/file/Goujard_2015_Evaluation_of_the.pdf https://doi.org/10.1007/s10924-015-0742-7 en eng HAL CCSD Springer Verlag info:eu-repo/semantics/altIdentifier/doi/10.1007/s10924-015-0742-7 hal-01285524 https://hal.sorbonne-universite.fr/hal-01285524 https://hal.sorbonne-universite.fr/hal-01285524/document https://hal.sorbonne-universite.fr/hal-01285524/file/Goujard_2015_Evaluation_of_the.pdf doi:10.1007/s10924-015-0742-7 PRODINRA: 355883 WOS: 000371296400007 info:eu-repo/semantics/OpenAccess ISSN: 1566-2543 EISSN: 1572-8900 Journal of Polymers and the Environment https://hal.sorbonne-universite.fr/hal-01285524 Journal of Polymers and the Environment, 2016, 24 (1), pp.64-71. ⟨10.1007/s10924-015-0742-7⟩ Chemical polyesters Enzymatic polyesters Biodegradability [CHIM]Chemical Sciences info:eu-repo/semantics/article Journal articles 2016 ftunivparisseine https://doi.org/10.1007/s10924-015-0742-7 2024-04-12T00:10:02Z International audience This work compares the biodegradability of polyesters produced by an esterification reaction between glycerol and oleic di-acid (D 18:1) issued from green chemical pathways, via either classical thermo-chemical methods, or an enzymatic method using the immobilized lipase of Candida antartica B (Novozym 435). An elastomeric polymer synthesized by enzymatic catalysis is more biodegradable than an elastomeric thermo-chemical polyester synthesized by a standard chemical procedure. This difference lies in percentage of the dendritic motifs, in values of the degree of substitution, and certainly in cross-links inducing an hyper-branched structure less accessible to the lipolytic enzymes in a waste treatment plant. However, when the elastomeric polymer synthesized by enzymatic catalysis is processed at high temperature as required for certain industrial applications, it presents an identical rate of biodegradation than the chemical polyester. The advantages of the thermo-chemical methods are greater speed and lower cost. Enzymatic synthesis appears be suited to producing polyesters, devoid of metallic catalysts, which must be used without processing at high temperature to keep a high biodegradability. Article in Journal/Newspaper antartic* Université Paris Seine: ComUE (HAL) Journal of Polymers and the Environment 24 1 64 71 |