Fluorpyromorphite, Pb5(PO4)3F, a new apatite-group mineral from Sukhovyaz Mountain, Southern Urals, and Tolbachik volcano, Kamchatka
Fluorpyromorphite, ideally Pb5(PO4)3F, a new apatite-group member, an F-dominant analog of pyromorphite and hydrox-ylpyromorphite. It is a supergene mineral found at two localities: Sukhovyaz Mountain, Ufaley District, Southern Urals (holotype) and Mountain 1004, Tolbachik volcano, Kamchatka (co-typ...
Published in: | Journal of Geosciences |
---|---|
Main Authors: | , , , , , , , , , |
Other Authors: | , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
CESKA GEOLOGICKA SPOLECNOST
2023
|
Subjects: | |
Online Access: | https://hdl.handle.net/11577/3491891 https://doi.org/10.3190/jgeosci.368 |
id |
ftunivpadovairis:oai:www.research.unipd.it:11577/3491891 |
---|---|
record_format |
openpolar |
spelling |
ftunivpadovairis:oai:www.research.unipd.it:11577/3491891 2024-02-11T10:05:24+01:00 Fluorpyromorphite, Pb5(PO4)3F, a new apatite-group mineral from Sukhovyaz Mountain, Southern Urals, and Tolbachik volcano, Kamchatka Kasatkin, AV Pekov, IV Skoda, R Chukanov, NV Nestola, F Agakhanov, AA Kuznetsov, AM Koshlyakova, NN Plasil, J Britvin, SN Kasatkin, Av Pekov, Iv Skoda, R Chukanov, Nv Nestola, F Agakhanov, Aa Kuznetsov, Am Koshlyakova, Nn Plasil, J Britvin, Sn 2023 STAMPA https://hdl.handle.net/11577/3491891 https://doi.org/10.3190/jgeosci.368 eng eng CESKA GEOLOGICKA SPOLECNOST info:eu-repo/semantics/altIdentifier/wos/WOS:000936829500005 volume:68 issue:1 firstpage:81 lastpage:93 numberofpages:13 journal:JOURNAL OF GEOSCIENCES https://hdl.handle.net/11577/3491891 doi:10.3190/jgeosci.368 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85148948372 fluorpyromorphite new mineral apatite group Sukhovyaz Mountain Southern Ural Tolbachik volcano info:eu-repo/semantics/article 2023 ftunivpadovairis https://doi.org/10.3190/jgeosci.368 2024-01-17T17:34:18Z Fluorpyromorphite, ideally Pb5(PO4)3F, a new apatite-group member, an F-dominant analog of pyromorphite and hydrox-ylpyromorphite. It is a supergene mineral found at two localities: Sukhovyaz Mountain, Ufaley District, Southern Urals (holotype) and Mountain 1004, Tolbachik volcano, Kamchatka (co-type), both in Russia. At Sukhovyaz, fluorpyromorphite forms anhedral grains up to 0.2 mm across (usually much smaller), filling cavities in quartz and sometimes partially replacing fluorapatite. Associated supergene minerals include pyromorphite, hydroxylpyromorphite, fluorphosphohedy-phane, mimetite, and nickeltsumcorite. At Tolbachik, fluorpyromorphite occurs in the oxidation zone of paleo-fumarolic deposits in close association with pyromorphite, fluorphosphohedyphane, wulfenite, cerussite, munakataite, vanadinite, chrysocolla, and opal. It forms crude long-prismatic to acicular crystals up to 0.1 mm long and up to 5 mu m thick com-bined in bunches and spherulites up to 0.2 mm. Fluorpyromorphite is colorless (Sukhovyaz) or yellow (Tolbachik), translucent to transparent and has a vitreous luster. It is brittle, with an uneven fracture and poor cleavage on (001). The calculated density values are 7.382 (holotype) and 6.831 (cotype) g/cm3. Fluorpyromorphite is optically uniaxial (-). In reflected light, it is light-grey, weakly anisotropic. The reflectance values (Rmin/Rmax, %) are: 15.8/16.6 (470 nm), 16.2/17.2 (546 nm), 15.9/16.9 (589 nm), 15.4/16.2 (650 nm). The chemical composition is (electron microprobe, wt. %; holotype/co-type): CaO 0.10/3.16, SrO 0.17/0.00, PbO 83.51/77.39, P2O516.13/16.35, CrO3 0.00/0.49, SeO3 0.00/0.98, F 1.00/1.35, Cl 0.29/0.40, H2Ocalc 0.13/0.00, -O=(F,Cl) -0.49/-0.66, total 100.84/99.46. The empirical formulae based on 13 anions (O +F + Cl+OH)pfu are Pb4.95Ca0.02Sr0.02P3.00O12F0.70(OH)0.19Cl0.11 (holotype) and Pb4.26Ca0.69P2.83Se6+0.09Cr6+0.06 O11.99F0.87Cl0.14 (co-type). Fluorpyromorphite is hexagonal, space group P63/m, unit-cell parameters (from powder X-ray diffraction data; holotype / ... Article in Journal/Newspaper Kamchatka Padua Research Archive (IRIS - Università degli Studi di Padova) Tolbachik ENVELOPE(159.960,159.960,55.537,55.537) Journal of Geosciences 81 93 |
institution |
Open Polar |
collection |
Padua Research Archive (IRIS - Università degli Studi di Padova) |
op_collection_id |
ftunivpadovairis |
language |
English |
topic |
fluorpyromorphite new mineral apatite group Sukhovyaz Mountain Southern Ural Tolbachik volcano |
spellingShingle |
fluorpyromorphite new mineral apatite group Sukhovyaz Mountain Southern Ural Tolbachik volcano Kasatkin, AV Pekov, IV Skoda, R Chukanov, NV Nestola, F Agakhanov, AA Kuznetsov, AM Koshlyakova, NN Plasil, J Britvin, SN Fluorpyromorphite, Pb5(PO4)3F, a new apatite-group mineral from Sukhovyaz Mountain, Southern Urals, and Tolbachik volcano, Kamchatka |
topic_facet |
fluorpyromorphite new mineral apatite group Sukhovyaz Mountain Southern Ural Tolbachik volcano |
description |
Fluorpyromorphite, ideally Pb5(PO4)3F, a new apatite-group member, an F-dominant analog of pyromorphite and hydrox-ylpyromorphite. It is a supergene mineral found at two localities: Sukhovyaz Mountain, Ufaley District, Southern Urals (holotype) and Mountain 1004, Tolbachik volcano, Kamchatka (co-type), both in Russia. At Sukhovyaz, fluorpyromorphite forms anhedral grains up to 0.2 mm across (usually much smaller), filling cavities in quartz and sometimes partially replacing fluorapatite. Associated supergene minerals include pyromorphite, hydroxylpyromorphite, fluorphosphohedy-phane, mimetite, and nickeltsumcorite. At Tolbachik, fluorpyromorphite occurs in the oxidation zone of paleo-fumarolic deposits in close association with pyromorphite, fluorphosphohedyphane, wulfenite, cerussite, munakataite, vanadinite, chrysocolla, and opal. It forms crude long-prismatic to acicular crystals up to 0.1 mm long and up to 5 mu m thick com-bined in bunches and spherulites up to 0.2 mm. Fluorpyromorphite is colorless (Sukhovyaz) or yellow (Tolbachik), translucent to transparent and has a vitreous luster. It is brittle, with an uneven fracture and poor cleavage on (001). The calculated density values are 7.382 (holotype) and 6.831 (cotype) g/cm3. Fluorpyromorphite is optically uniaxial (-). In reflected light, it is light-grey, weakly anisotropic. The reflectance values (Rmin/Rmax, %) are: 15.8/16.6 (470 nm), 16.2/17.2 (546 nm), 15.9/16.9 (589 nm), 15.4/16.2 (650 nm). The chemical composition is (electron microprobe, wt. %; holotype/co-type): CaO 0.10/3.16, SrO 0.17/0.00, PbO 83.51/77.39, P2O516.13/16.35, CrO3 0.00/0.49, SeO3 0.00/0.98, F 1.00/1.35, Cl 0.29/0.40, H2Ocalc 0.13/0.00, -O=(F,Cl) -0.49/-0.66, total 100.84/99.46. The empirical formulae based on 13 anions (O +F + Cl+OH)pfu are Pb4.95Ca0.02Sr0.02P3.00O12F0.70(OH)0.19Cl0.11 (holotype) and Pb4.26Ca0.69P2.83Se6+0.09Cr6+0.06 O11.99F0.87Cl0.14 (co-type). Fluorpyromorphite is hexagonal, space group P63/m, unit-cell parameters (from powder X-ray diffraction data; holotype / ... |
author2 |
Kasatkin, Av Pekov, Iv Skoda, R Chukanov, Nv Nestola, F Agakhanov, Aa Kuznetsov, Am Koshlyakova, Nn Plasil, J Britvin, Sn |
format |
Article in Journal/Newspaper |
author |
Kasatkin, AV Pekov, IV Skoda, R Chukanov, NV Nestola, F Agakhanov, AA Kuznetsov, AM Koshlyakova, NN Plasil, J Britvin, SN |
author_facet |
Kasatkin, AV Pekov, IV Skoda, R Chukanov, NV Nestola, F Agakhanov, AA Kuznetsov, AM Koshlyakova, NN Plasil, J Britvin, SN |
author_sort |
Kasatkin, AV |
title |
Fluorpyromorphite, Pb5(PO4)3F, a new apatite-group mineral from Sukhovyaz Mountain, Southern Urals, and Tolbachik volcano, Kamchatka |
title_short |
Fluorpyromorphite, Pb5(PO4)3F, a new apatite-group mineral from Sukhovyaz Mountain, Southern Urals, and Tolbachik volcano, Kamchatka |
title_full |
Fluorpyromorphite, Pb5(PO4)3F, a new apatite-group mineral from Sukhovyaz Mountain, Southern Urals, and Tolbachik volcano, Kamchatka |
title_fullStr |
Fluorpyromorphite, Pb5(PO4)3F, a new apatite-group mineral from Sukhovyaz Mountain, Southern Urals, and Tolbachik volcano, Kamchatka |
title_full_unstemmed |
Fluorpyromorphite, Pb5(PO4)3F, a new apatite-group mineral from Sukhovyaz Mountain, Southern Urals, and Tolbachik volcano, Kamchatka |
title_sort |
fluorpyromorphite, pb5(po4)3f, a new apatite-group mineral from sukhovyaz mountain, southern urals, and tolbachik volcano, kamchatka |
publisher |
CESKA GEOLOGICKA SPOLECNOST |
publishDate |
2023 |
url |
https://hdl.handle.net/11577/3491891 https://doi.org/10.3190/jgeosci.368 |
long_lat |
ENVELOPE(159.960,159.960,55.537,55.537) |
geographic |
Tolbachik |
geographic_facet |
Tolbachik |
genre |
Kamchatka |
genre_facet |
Kamchatka |
op_relation |
info:eu-repo/semantics/altIdentifier/wos/WOS:000936829500005 volume:68 issue:1 firstpage:81 lastpage:93 numberofpages:13 journal:JOURNAL OF GEOSCIENCES https://hdl.handle.net/11577/3491891 doi:10.3190/jgeosci.368 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85148948372 |
op_doi |
https://doi.org/10.3190/jgeosci.368 |
container_title |
Journal of Geosciences |
container_start_page |
81 |
op_container_end_page |
93 |
_version_ |
1790602430655758336 |