Nanoplastic in the North Atlantic Subtropical Gyre
International audience Plastics can be found in all ecosystems across the globe. This type of environmental pollution is important, even if its impact is not fully understood. The presence of small plastic particles at the micro- and nanoscales is of growing concern, but nanoplastic has not yet been...
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ftunivnantes:oai:HAL:insu-01647511v1 2023-05-15T17:29:57+02:00 Nanoplastic in the North Atlantic Subtropical Gyre ter Halle, Alexandra Jeanneau, Laurent Martignac, Marion Jardé, Emilie Pedrono, Boris Brach, Laurent Gigault, Julien Interactions moléculaires et réactivité chimique et photochimique (IMRCP) Institut de Chimie de Toulouse (ICT-FR 2599) Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3) Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP) Université Fédérale Toulouse Midi-Pyrénées-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3) Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS) Géosciences Rennes (GR) Université de Rennes 1 (UR1) Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Rennes (OSUR) Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Rennes 2 (UR2) Université de Rennes (UNIV-RENNES)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université de Rennes 2 (UR2) Université de Rennes (UNIV-RENNES)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Centre National de la Recherche Scientifique (CNRS) Cordouan Technologies Centre National d?Etudes Spatiales Centre National de la Recherche Scientifique Total Corporate Foundation 2017-12-05 https://hal-insu.archives-ouvertes.fr/insu-01647511 https://doi.org/10.1021/acs.est.7b03667 en eng HAL CCSD American Chemical Society info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.est.7b03667 info:eu-repo/semantics/altIdentifier/pmid/29161030 insu-01647511 https://hal-insu.archives-ouvertes.fr/insu-01647511 doi:10.1021/acs.est.7b03667 PUBMED: 29161030 ISSN: 0013-936X EISSN: 1520-5851 Environmental Science and Technology https://hal-insu.archives-ouvertes.fr/insu-01647511 Environmental Science and Technology, 2017, 51 (23), pp.13689-13697. ⟨10.1021/acs.est.7b03667⟩ GEOF [SDE]Environmental Sciences [CHIM]Chemical Sciences info:eu-repo/semantics/article Journal articles 2017 ftunivnantes https://doi.org/10.1021/acs.est.7b03667 2023-02-22T09:31:39Z International audience Plastics can be found in all ecosystems across the globe. This type of environmental pollution is important, even if its impact is not fully understood. The presence of small plastic particles at the micro- and nanoscales is of growing concern, but nanoplastic has not yet been observed in natural samples. In this study, we examined four size fractions (meso-, large micro-, small micro-, and nanoplastics) of debris collected in the North Atlantic subtropical gyre. To obtain the nanoplastic portion, we isolated the colloidal fraction of seawater. After ultrafiltration, the occurrence of nanoscale particles was demonstrated using dynamic light scattering experiments. The chemical fingerprint of the colloids was obtained by pyrolysis coupled with gas chromatography–mass spectrometry. We demonstrated that the signal was anthropogenic and attributed to a combination of plastics. The polymer composition varied among the size classes. At the micro- and nanoscales, polyvinyl chloride, polyethylene terephthalate, polystyrene and polyethylene were observed. We also observed changes in the pyrolytic signals of polyethylene with decreasing debris size, which could be related to the structural modification of this plastic as a consequence of weathering. Article in Journal/Newspaper North Atlantic Université de Nantes: HAL-UNIV-NANTES Environmental Science & Technology 51 23 13689 13697 |
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Université de Nantes: HAL-UNIV-NANTES |
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ftunivnantes |
language |
English |
topic |
GEOF [SDE]Environmental Sciences [CHIM]Chemical Sciences |
spellingShingle |
GEOF [SDE]Environmental Sciences [CHIM]Chemical Sciences ter Halle, Alexandra Jeanneau, Laurent Martignac, Marion Jardé, Emilie Pedrono, Boris Brach, Laurent Gigault, Julien Nanoplastic in the North Atlantic Subtropical Gyre |
topic_facet |
GEOF [SDE]Environmental Sciences [CHIM]Chemical Sciences |
description |
International audience Plastics can be found in all ecosystems across the globe. This type of environmental pollution is important, even if its impact is not fully understood. The presence of small plastic particles at the micro- and nanoscales is of growing concern, but nanoplastic has not yet been observed in natural samples. In this study, we examined four size fractions (meso-, large micro-, small micro-, and nanoplastics) of debris collected in the North Atlantic subtropical gyre. To obtain the nanoplastic portion, we isolated the colloidal fraction of seawater. After ultrafiltration, the occurrence of nanoscale particles was demonstrated using dynamic light scattering experiments. The chemical fingerprint of the colloids was obtained by pyrolysis coupled with gas chromatography–mass spectrometry. We demonstrated that the signal was anthropogenic and attributed to a combination of plastics. The polymer composition varied among the size classes. At the micro- and nanoscales, polyvinyl chloride, polyethylene terephthalate, polystyrene and polyethylene were observed. We also observed changes in the pyrolytic signals of polyethylene with decreasing debris size, which could be related to the structural modification of this plastic as a consequence of weathering. |
author2 |
Interactions moléculaires et réactivité chimique et photochimique (IMRCP) Institut de Chimie de Toulouse (ICT-FR 2599) Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3) Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP) Université Fédérale Toulouse Midi-Pyrénées-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3) Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS) Géosciences Rennes (GR) Université de Rennes 1 (UR1) Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Rennes (OSUR) Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Rennes 2 (UR2) Université de Rennes (UNIV-RENNES)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université de Rennes 2 (UR2) Université de Rennes (UNIV-RENNES)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Centre National de la Recherche Scientifique (CNRS) Cordouan Technologies Centre National d?Etudes Spatiales Centre National de la Recherche Scientifique Total Corporate Foundation |
format |
Article in Journal/Newspaper |
author |
ter Halle, Alexandra Jeanneau, Laurent Martignac, Marion Jardé, Emilie Pedrono, Boris Brach, Laurent Gigault, Julien |
author_facet |
ter Halle, Alexandra Jeanneau, Laurent Martignac, Marion Jardé, Emilie Pedrono, Boris Brach, Laurent Gigault, Julien |
author_sort |
ter Halle, Alexandra |
title |
Nanoplastic in the North Atlantic Subtropical Gyre |
title_short |
Nanoplastic in the North Atlantic Subtropical Gyre |
title_full |
Nanoplastic in the North Atlantic Subtropical Gyre |
title_fullStr |
Nanoplastic in the North Atlantic Subtropical Gyre |
title_full_unstemmed |
Nanoplastic in the North Atlantic Subtropical Gyre |
title_sort |
nanoplastic in the north atlantic subtropical gyre |
publisher |
HAL CCSD |
publishDate |
2017 |
url |
https://hal-insu.archives-ouvertes.fr/insu-01647511 https://doi.org/10.1021/acs.est.7b03667 |
genre |
North Atlantic |
genre_facet |
North Atlantic |
op_source |
ISSN: 0013-936X EISSN: 1520-5851 Environmental Science and Technology https://hal-insu.archives-ouvertes.fr/insu-01647511 Environmental Science and Technology, 2017, 51 (23), pp.13689-13697. ⟨10.1021/acs.est.7b03667⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.est.7b03667 info:eu-repo/semantics/altIdentifier/pmid/29161030 insu-01647511 https://hal-insu.archives-ouvertes.fr/insu-01647511 doi:10.1021/acs.est.7b03667 PUBMED: 29161030 |
op_doi |
https://doi.org/10.1021/acs.est.7b03667 |
container_title |
Environmental Science & Technology |
container_volume |
51 |
container_issue |
23 |
container_start_page |
13689 |
op_container_end_page |
13697 |
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1766125201807900672 |