Origin of insoluble organic matter in type 1 and 2 chondrites: New clues, new questions
Insoluble organic matter (IOM) extracted from primitive chondrites is a polyaromatic solid with a structure and composition resembling that of terrestrial kerogens. A survey of its composition and structure has been carried out on a series of 27 CR, CM, CI and ungrouped C2 carbonaceous chondrites (T...
Published in: | Geochimica et Cosmochimica Acta |
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Main Authors: | , , , , , , , , , , |
Other Authors: | , , , , , , , , , , , , , , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
HAL CCSD
2014
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Subjects: | |
Online Access: | https://hal.in2p3.fr/in2p3-01057484 https://doi.org/10.1016/J.GCA.2014.03.025 |
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ftunivnantes:oai:HAL:in2p3-01057484v1 |
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Open Polar |
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Université de Nantes: HAL-UNIV-NANTES |
op_collection_id |
ftunivnantes |
language |
English |
topic |
[PHYS.ASTR.EP]Physics [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP] [SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP] |
spellingShingle |
[PHYS.ASTR.EP]Physics [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP] [SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP] Quirico, E. Orthous-Daunay, F. R. Beck, P. Bonal, L. Brunetto, R. Dartois, E. Pino, T. Montagnac, G. Rouzaud, J. N. Engrand, C. Duprat, J. Origin of insoluble organic matter in type 1 and 2 chondrites: New clues, new questions |
topic_facet |
[PHYS.ASTR.EP]Physics [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP] [SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP] |
description |
Insoluble organic matter (IOM) extracted from primitive chondrites is a polyaromatic solid with a structure and composition resembling that of terrestrial kerogens. A survey of its composition and structure has been carried out on a series of 27 CR, CM, CI and ungrouped C2 carbonaceous chondrites (Tagish Lake, Bells, Essebi, Acfer 094) using infrared and multi-wavelength Raman micro-spectroscopy (244, 514 and 785 nm laser excitations). The results show that chondritic IOM from PCA 91008 (CM2), WIS 91600 (CM2), QUE 93005 (CM2), Tagish Lake (C2 ungrouped) and possibly Cold Bokkeveld (CM2) has been subjected to the past action of short duration thermal metamorphism, presumably triggered by impacts. The IOM in most of the CM chondrites that experienced moderate to heavy aqueous alteration may have been slightly modified by collision-induced heating. However, even IOM from chondrites that escaped significant thermal metamorphism displays Raman characteristics consistent with a formation by thermal processing, either in the protosolar disk or in the parent body. An alternative energetic process to thermal heating is ion irradiation. After thoroughly analyzing both these scenarii, no conclusion can be drawn as to which is the most plausible mechanism nor whether the heating process took place prior or after accretion. The results show for the first time that the width of the G band in spectra collected with a 514 nm excitation correlates with the O/C atomic ratio, suggesting a major role of oxygen in the cross-linking of polyaromatic units. (c) 2014 Elsevier Ltd |
author2 |
Institut de Planétologie et d'Astrophysique de Grenoble (IPAG ) Observatoire des Sciences de l'Univers de Grenoble (OSUG) Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Centre National d'Études Spatiales Toulouse (CNES)-Centre National de la Recherche Scientifique (CNRS) Institut d'astrophysique spatiale (IAS) Université Paris-Sud - Paris 11 (UP11)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Centre National d’Études Spatiales Paris (CNES) Institut des Sciences Moléculaires d'Orsay (ISMO) Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS) Laboratoire de géologie de l'ENS (LGENS) Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Département des Géosciences - ENS Paris École normale supérieure - Paris (ENS-PSL) Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-École normale supérieure - Paris (ENS-PSL) Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL) Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement Lyon (LGL-TPE) École normale supérieure - Lyon (ENS Lyon)-Université Claude Bernard Lyon 1 (UCBL) Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) CSNSM AN Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM) Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM) Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS) Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM) |
format |
Article in Journal/Newspaper |
author |
Quirico, E. Orthous-Daunay, F. R. Beck, P. Bonal, L. Brunetto, R. Dartois, E. Pino, T. Montagnac, G. Rouzaud, J. N. Engrand, C. Duprat, J. |
author_facet |
Quirico, E. Orthous-Daunay, F. R. Beck, P. Bonal, L. Brunetto, R. Dartois, E. Pino, T. Montagnac, G. Rouzaud, J. N. Engrand, C. Duprat, J. |
author_sort |
Quirico, E. |
title |
Origin of insoluble organic matter in type 1 and 2 chondrites: New clues, new questions |
title_short |
Origin of insoluble organic matter in type 1 and 2 chondrites: New clues, new questions |
title_full |
Origin of insoluble organic matter in type 1 and 2 chondrites: New clues, new questions |
title_fullStr |
Origin of insoluble organic matter in type 1 and 2 chondrites: New clues, new questions |
title_full_unstemmed |
Origin of insoluble organic matter in type 1 and 2 chondrites: New clues, new questions |
title_sort |
origin of insoluble organic matter in type 1 and 2 chondrites: new clues, new questions |
publisher |
HAL CCSD |
publishDate |
2014 |
url |
https://hal.in2p3.fr/in2p3-01057484 https://doi.org/10.1016/J.GCA.2014.03.025 |
long_lat |
ENVELOPE(-134.272,-134.272,60.313,60.313) ENVELOPE(-134.233,-134.233,59.717,59.717) |
geographic |
Tagish Tagish Lake |
geographic_facet |
Tagish Tagish Lake |
genre |
Tagish |
genre_facet |
Tagish |
op_source |
ISSN: 0016-7037 EISSN: 0016-7037 Geochimica et Cosmochimica Acta https://hal.in2p3.fr/in2p3-01057484 Geochimica et Cosmochimica Acta, 2014, 136, pp.80-99. ⟨10.1016/J.GCA.2014.03.025⟩ |
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op_doi |
https://doi.org/10.1016/J.GCA.2014.03.025 |
container_title |
Geochimica et Cosmochimica Acta |
container_volume |
136 |
container_start_page |
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op_container_end_page |
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1766213556224655360 |
spelling |
ftunivnantes:oai:HAL:in2p3-01057484v1 2023-05-15T18:30:04+02:00 Origin of insoluble organic matter in type 1 and 2 chondrites: New clues, new questions Quirico, E. Orthous-Daunay, F. R. Beck, P. Bonal, L. Brunetto, R. Dartois, E. Pino, T. Montagnac, G. Rouzaud, J. N. Engrand, C. Duprat, J. Institut de Planétologie et d'Astrophysique de Grenoble (IPAG ) Observatoire des Sciences de l'Univers de Grenoble (OSUG) Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Centre National d'Études Spatiales Toulouse (CNES)-Centre National de la Recherche Scientifique (CNRS) Institut d'astrophysique spatiale (IAS) Université Paris-Sud - Paris 11 (UP11)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Centre National d’Études Spatiales Paris (CNES) Institut des Sciences Moléculaires d'Orsay (ISMO) Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS) Laboratoire de géologie de l'ENS (LGENS) Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Département des Géosciences - ENS Paris École normale supérieure - Paris (ENS-PSL) Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-École normale supérieure - Paris (ENS-PSL) Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL) Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement Lyon (LGL-TPE) École normale supérieure - Lyon (ENS Lyon)-Université Claude Bernard Lyon 1 (UCBL) Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) CSNSM AN Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM) Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM) Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS) Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM) 2014-07 https://hal.in2p3.fr/in2p3-01057484 https://doi.org/10.1016/J.GCA.2014.03.025 en eng HAL CCSD Elsevier info:eu-repo/semantics/altIdentifier/doi/10.1016/J.GCA.2014.03.025 in2p3-01057484 https://hal.in2p3.fr/in2p3-01057484 BIBCODE: 2014GeCoA.136.80Q doi:10.1016/J.GCA.2014.03.025 ISSN: 0016-7037 EISSN: 0016-7037 Geochimica et Cosmochimica Acta https://hal.in2p3.fr/in2p3-01057484 Geochimica et Cosmochimica Acta, 2014, 136, pp.80-99. ⟨10.1016/J.GCA.2014.03.025⟩ [PHYS.ASTR.EP]Physics [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP] [SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP] info:eu-repo/semantics/article Journal articles 2014 ftunivnantes https://doi.org/10.1016/J.GCA.2014.03.025 2023-03-08T07:41:01Z Insoluble organic matter (IOM) extracted from primitive chondrites is a polyaromatic solid with a structure and composition resembling that of terrestrial kerogens. A survey of its composition and structure has been carried out on a series of 27 CR, CM, CI and ungrouped C2 carbonaceous chondrites (Tagish Lake, Bells, Essebi, Acfer 094) using infrared and multi-wavelength Raman micro-spectroscopy (244, 514 and 785 nm laser excitations). The results show that chondritic IOM from PCA 91008 (CM2), WIS 91600 (CM2), QUE 93005 (CM2), Tagish Lake (C2 ungrouped) and possibly Cold Bokkeveld (CM2) has been subjected to the past action of short duration thermal metamorphism, presumably triggered by impacts. The IOM in most of the CM chondrites that experienced moderate to heavy aqueous alteration may have been slightly modified by collision-induced heating. However, even IOM from chondrites that escaped significant thermal metamorphism displays Raman characteristics consistent with a formation by thermal processing, either in the protosolar disk or in the parent body. An alternative energetic process to thermal heating is ion irradiation. After thoroughly analyzing both these scenarii, no conclusion can be drawn as to which is the most plausible mechanism nor whether the heating process took place prior or after accretion. The results show for the first time that the width of the G band in spectra collected with a 514 nm excitation correlates with the O/C atomic ratio, suggesting a major role of oxygen in the cross-linking of polyaromatic units. (c) 2014 Elsevier Ltd Article in Journal/Newspaper Tagish Université de Nantes: HAL-UNIV-NANTES Tagish ENVELOPE(-134.272,-134.272,60.313,60.313) Tagish Lake ENVELOPE(-134.233,-134.233,59.717,59.717) Geochimica et Cosmochimica Acta 136 80 99 |