Five-dimensional imaging of freezing emulsions with solute effects
International audience The interaction of objects with a moving solidification front is a common feature of many industrial and natural processes such as metal processing, the growth of single-crystals, the cryopreservation of cells, or the formation of sea ice. Solidification fronts interact with o...
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Online Access: | https://hal.science/hal-01794931 https://hal.science/hal-01794931/document https://hal.science/hal-01794931/file/scifile.pdf https://doi.org/10.1126/science.aar4503 |
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ftunivnantes:oai:HAL:hal-01794931v1 2023-05-15T18:18:23+02:00 Five-dimensional imaging of freezing emulsions with solute effects Dedovets, Dmytro Monteux, Cécile Deville, Sylvain Laboratoire de Synthèse et Fonctionnalisation de Céramiques (LSFC) SAINT-GOBAIN-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) Sciences et Ingénierie de la Matière Molle (UMR 7615) (SIMM) Ecole Superieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI Paris) Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) 2018-04-19 https://hal.science/hal-01794931 https://hal.science/hal-01794931/document https://hal.science/hal-01794931/file/scifile.pdf https://doi.org/10.1126/science.aar4503 en eng HAL CCSD American Association for the Advancement of Science (AAAS) info:eu-repo/semantics/altIdentifier/doi/10.1126/science.aar4503 hal-01794931 https://hal.science/hal-01794931 https://hal.science/hal-01794931/document https://hal.science/hal-01794931/file/scifile.pdf doi:10.1126/science.aar4503 info:eu-repo/semantics/OpenAccess ISSN: 0036-8075 EISSN: 1095-9203 Science https://hal.science/hal-01794931 Science, 2018, 360 (6386), pp.303 - 306. ⟨10.1126/science.aar4503⟩ [CHIM.MATE]Chemical Sciences/Material chemistry [SPI.MAT]Engineering Sciences [physics]/Materials info:eu-repo/semantics/article Journal articles 2018 ftunivnantes https://doi.org/10.1126/science.aar4503 2023-01-25T00:43:36Z International audience The interaction of objects with a moving solidification front is a common feature of many industrial and natural processes such as metal processing, the growth of single-crystals, the cryopreservation of cells, or the formation of sea ice. Solidification fronts interact with objects with different outcomes, from the total rejection to their complete engulfment. We image the freezing of emulsions in 5D (space, time, and solute concentration) with confocal mi-croscopy. We show the solute induces long-range interactions that determine the solidification microstructure. The local increase of solute concentration enhances premelting, which controls the engulfment of droplets by the front and the evolution of grain boundaries. Freezing emulsions may be a good analogue of many solidification systems where objects interact with a solidification interface. Solidification fronts interact with hard or soft objects such as particles, bubbles, droplets, or cells, in three different ways: objects can be engulfed, rejected for some time and then encapsulated , or rejected for an extended period of time (1). Different outcomes are desired, depending 1 Article in Journal/Newspaper Sea ice Université de Nantes: HAL-UNIV-NANTES Science 360 6386 303 306 |
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Université de Nantes: HAL-UNIV-NANTES |
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ftunivnantes |
language |
English |
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[CHIM.MATE]Chemical Sciences/Material chemistry [SPI.MAT]Engineering Sciences [physics]/Materials |
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[CHIM.MATE]Chemical Sciences/Material chemistry [SPI.MAT]Engineering Sciences [physics]/Materials Dedovets, Dmytro Monteux, Cécile Deville, Sylvain Five-dimensional imaging of freezing emulsions with solute effects |
topic_facet |
[CHIM.MATE]Chemical Sciences/Material chemistry [SPI.MAT]Engineering Sciences [physics]/Materials |
description |
International audience The interaction of objects with a moving solidification front is a common feature of many industrial and natural processes such as metal processing, the growth of single-crystals, the cryopreservation of cells, or the formation of sea ice. Solidification fronts interact with objects with different outcomes, from the total rejection to their complete engulfment. We image the freezing of emulsions in 5D (space, time, and solute concentration) with confocal mi-croscopy. We show the solute induces long-range interactions that determine the solidification microstructure. The local increase of solute concentration enhances premelting, which controls the engulfment of droplets by the front and the evolution of grain boundaries. Freezing emulsions may be a good analogue of many solidification systems where objects interact with a solidification interface. Solidification fronts interact with hard or soft objects such as particles, bubbles, droplets, or cells, in three different ways: objects can be engulfed, rejected for some time and then encapsulated , or rejected for an extended period of time (1). Different outcomes are desired, depending 1 |
author2 |
Laboratoire de Synthèse et Fonctionnalisation de Céramiques (LSFC) SAINT-GOBAIN-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) Sciences et Ingénierie de la Matière Molle (UMR 7615) (SIMM) Ecole Superieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI Paris) Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) |
format |
Article in Journal/Newspaper |
author |
Dedovets, Dmytro Monteux, Cécile Deville, Sylvain |
author_facet |
Dedovets, Dmytro Monteux, Cécile Deville, Sylvain |
author_sort |
Dedovets, Dmytro |
title |
Five-dimensional imaging of freezing emulsions with solute effects |
title_short |
Five-dimensional imaging of freezing emulsions with solute effects |
title_full |
Five-dimensional imaging of freezing emulsions with solute effects |
title_fullStr |
Five-dimensional imaging of freezing emulsions with solute effects |
title_full_unstemmed |
Five-dimensional imaging of freezing emulsions with solute effects |
title_sort |
five-dimensional imaging of freezing emulsions with solute effects |
publisher |
HAL CCSD |
publishDate |
2018 |
url |
https://hal.science/hal-01794931 https://hal.science/hal-01794931/document https://hal.science/hal-01794931/file/scifile.pdf https://doi.org/10.1126/science.aar4503 |
genre |
Sea ice |
genre_facet |
Sea ice |
op_source |
ISSN: 0036-8075 EISSN: 1095-9203 Science https://hal.science/hal-01794931 Science, 2018, 360 (6386), pp.303 - 306. ⟨10.1126/science.aar4503⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1126/science.aar4503 hal-01794931 https://hal.science/hal-01794931 https://hal.science/hal-01794931/document https://hal.science/hal-01794931/file/scifile.pdf doi:10.1126/science.aar4503 |
op_rights |
info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.1126/science.aar4503 |
container_title |
Science |
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360 |
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6386 |
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303 |
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306 |
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1766194948137287680 |