A modeling study of methane hydrate decomposition in contact with the external surface of zeolites
International audience The behavior of methane hydrate (MH) enclosed between the (010) surfaces of the silicalite-1 zeolite was studied by means of molecular dynamics simulations at temperatures of 150 and 250 K. Calculations reveal that the interaction with the hydrophilic surface OH groups destabi...
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ftunivnantes:oai:HAL:hal-01593275v1 2023-05-15T17:11:48+02:00 A modeling study of methane hydrate decomposition in contact with the external surface of zeolites Smirnov, Konstantin Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 (LASIRE) Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS) 2017 https://hal.science/hal-01593275 https://doi.org/10.1039/C7CP01985H en eng HAL CCSD Royal Society of Chemistry info:eu-repo/semantics/altIdentifier/doi/10.1039/C7CP01985H hal-01593275 https://hal.science/hal-01593275 doi:10.1039/C7CP01985H ISSN: 1463-9076 EISSN: 1463-9084 Physical Chemistry Chemical Physics https://hal.science/hal-01593275 Physical Chemistry Chemical Physics, 2017, 19 (34), pp.23095 - 23105. ⟨10.1039/C7CP01985H⟩ [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry info:eu-repo/semantics/article Journal articles 2017 ftunivnantes https://doi.org/10.1039/C7CP01985H 2023-02-08T09:17:03Z International audience The behavior of methane hydrate (MH) enclosed between the (010) surfaces of the silicalite-1 zeolite was studied by means of molecular dynamics simulations at temperatures of 150 and 250 K. Calculations reveal that the interaction with the hydrophilic surface OH groups destabilizes the clathrate structure of hydrate. While MH mostly conserves the structure in the simulation at the low temperature, thermal motion at the high temperature breaks the fragilized cages of H-bonded water molecules, thus leading to the release of methane. The dissociation proceeds in a layer-by-layer manner starting from the outer parts of the MH slab until complete hydrate decomposition. The released CH4 molecules are absorbed by the microporous solid, whereas water is retained at the surfaces of hydrophobic silicalite and forms a meniscus in the interlayer space. Methane uptake reaches 70% of the silicalite sorption capacity. The energy necessary for the endothermic MH dissociation is supplied by the exothermic methane absorption by the zeolite. Article in Journal/Newspaper Methane hydrate Université de Nantes: HAL-UNIV-NANTES Physical Chemistry Chemical Physics 19 34 23095 23105 |
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Université de Nantes: HAL-UNIV-NANTES |
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English |
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[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry |
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[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry Smirnov, Konstantin A modeling study of methane hydrate decomposition in contact with the external surface of zeolites |
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[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry |
description |
International audience The behavior of methane hydrate (MH) enclosed between the (010) surfaces of the silicalite-1 zeolite was studied by means of molecular dynamics simulations at temperatures of 150 and 250 K. Calculations reveal that the interaction with the hydrophilic surface OH groups destabilizes the clathrate structure of hydrate. While MH mostly conserves the structure in the simulation at the low temperature, thermal motion at the high temperature breaks the fragilized cages of H-bonded water molecules, thus leading to the release of methane. The dissociation proceeds in a layer-by-layer manner starting from the outer parts of the MH slab until complete hydrate decomposition. The released CH4 molecules are absorbed by the microporous solid, whereas water is retained at the surfaces of hydrophobic silicalite and forms a meniscus in the interlayer space. Methane uptake reaches 70% of the silicalite sorption capacity. The energy necessary for the endothermic MH dissociation is supplied by the exothermic methane absorption by the zeolite. |
author2 |
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 (LASIRE) Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS) |
format |
Article in Journal/Newspaper |
author |
Smirnov, Konstantin |
author_facet |
Smirnov, Konstantin |
author_sort |
Smirnov, Konstantin |
title |
A modeling study of methane hydrate decomposition in contact with the external surface of zeolites |
title_short |
A modeling study of methane hydrate decomposition in contact with the external surface of zeolites |
title_full |
A modeling study of methane hydrate decomposition in contact with the external surface of zeolites |
title_fullStr |
A modeling study of methane hydrate decomposition in contact with the external surface of zeolites |
title_full_unstemmed |
A modeling study of methane hydrate decomposition in contact with the external surface of zeolites |
title_sort |
modeling study of methane hydrate decomposition in contact with the external surface of zeolites |
publisher |
HAL CCSD |
publishDate |
2017 |
url |
https://hal.science/hal-01593275 https://doi.org/10.1039/C7CP01985H |
genre |
Methane hydrate |
genre_facet |
Methane hydrate |
op_source |
ISSN: 1463-9076 EISSN: 1463-9084 Physical Chemistry Chemical Physics https://hal.science/hal-01593275 Physical Chemistry Chemical Physics, 2017, 19 (34), pp.23095 - 23105. ⟨10.1039/C7CP01985H⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1039/C7CP01985H hal-01593275 https://hal.science/hal-01593275 doi:10.1039/C7CP01985H |
op_doi |
https://doi.org/10.1039/C7CP01985H |
container_title |
Physical Chemistry Chemical Physics |
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19 |
container_issue |
34 |
container_start_page |
23095 |
op_container_end_page |
23105 |
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1766068567052124160 |