Use of two new Na/Li geothermometric relationships for geothermal fluids in volcanic environments

• Published in: Chemical Geology
• Main Authors: Sanjuan, Bernard, Millot, Romain, Asmundsson, Ragnar, Michel, Brach, Giroud, Niels
• Other Authors: Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Iceland GeoSurvey (ISOR ), Nagra, NAGRA, Financemen européen, HITI FP6, European Project: 35108,HITI
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2014
• Subjects: Chemical geothermometer; Li isotopes; Geothermal fluid; Basalt; [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry; [SDE.MCG]Environmental Sciences/Global Changes; Krafla; Námafjall; Nesjavellir; Pacific; Reykjanes; Seltjarnarnes; Iceland
• Online Access: https://hal-brgm.archives-ouvertes.fr/hal-01074101; https://doi.org/10.1016/j.chemgeo.2014.09.011

International audience This work has made it possible to obtain two new Na/Li geothermometric relationships in addition to the three already known (Fouillac and Michard, 1981; Kharaka et al., 1982) and confirms that the Na/Li geothermometer, unlike the Na/K, Na/K/Ca, K/Mg and silica geothermometers, or the isotope δ18O (H2O-SO4) geothermometer, also depends on the fluid salinity and the nature of the reservoir rocks reacting with the geothermal water. One of the relationships concerns the fluids derived from seawater-basalt interaction processes existing in emerged rifts such as those of Iceland (Reykjanes, Svartsengi, and Seltjarnarnes geothermal fields) and Djibouti (Asal-Ghoubbet and Obock geothermal areas), or in numerous oceanic ridges and rises (Mid-Atlantic and Middle-Valley ridges, East Pacific rise, etc.). The best adapted Na/Li relationship for geothermal fluids discharged from emerged rifts between 0 and 365 °C is: T(K)= 920/[log(Na/Li)−1.105] (r2 = 0.994; n = 27) where Na and Li are the aqueous concentrations of these elements given in mol/L. The other Na/Li relationship was determined using dilute waters collected from wells located in different hightemperature (200-325 °C) volcanic geothermal areas of Iceland (Krafla, Námafjall, Nesjavellir and Hveragerdi). This relationship can be expressed as follows: T(K)= 2002/[log(Na/Li) + 1.322] (r2= 0.967, n= 17). These two relationships give estimations of temperature with an uncertainty close to ±20 °C. The second Na/Li relationship was also successfully applied to HT dilute geothermal waters from the East African Rift (Ethiopia, Kenya). Some case studies in the literature and thermodynamic considerations suggest that the Na/Li ratios for this type of fluids could be controlled by full equilibrium reactions involving a mineral assemblage constituting at least albite, K-feldspar, quartz and clay minerals such as kaolinite, illite (or muscovite) and Li-micas. Unlike the Na/Li ratios, no thermometric relationship using Li isotopes could be determined for ...