Crystal chemistry of Al-rich biotites coexisting with muscovites in peraluminous granites
A comparison was made between single-crystal structure refinements, electron microprobe analy ses and octahedral site populations of seven biotite crystals and data obtained previously for coexisting muscovite in peraluminous granites using the same methods. Both micas, From several plutons of North...
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Online Access: | http://hdl.handle.net/11380/305778 https://doi.org/10.2138/am-2000-0405 |
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ftunivmodena:oai:iris.unimore.it:11380/305778 2024-04-14T08:03:49+00:00 Crystal chemistry of Al-rich biotites coexisting with muscovites in peraluminous granites BRIGATTI, Maria Franca POPPI, Luciano P. Frigieri C. Ghezzo Brigatti, Maria Franca P., Frigieri C., Ghezzo Poppi, Luciano 2000 STAMPA http://hdl.handle.net/11380/305778 https://doi.org/10.2138/am-2000-0405 eng eng info:eu-repo/semantics/altIdentifier/wos/WOS:000085702400005 volume:85 issue:3-4 firstpage:436 lastpage:448 journal:AMERICAN MINERALOGIST http://hdl.handle.net/11380/305778 doi:10.2138/am-2000-0405 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-0034097263 biotiti crystal chemistry info:eu-repo/semantics/article 2000 ftunivmodena https://doi.org/10.2138/am-2000-0405 2024-03-21T17:50:03Z A comparison was made between single-crystal structure refinements, electron microprobe analy ses and octahedral site populations of seven biotite crystals and data obtained previously for coexisting muscovite in peraluminous granites using the same methods. Both micas, From several plutons of Northern Victoria Land (Antarctica) and Sardinia (Italy), show significant octahedral substitutions: biotite has a composition characterized by relatively high Al-[6] content (0.32 less than or equal to Al-[6] less than or equal to 0.59 apfu), whereas muscovite is characterized by phengite-like substitutions [0.12 less than or equal to ([6])(Mg + Fe + Ti + Mn) less than or equal to 0.35]. Mean bond-lengths and electron count data for six biotites-1M (space group C2/m. agreement factor 2.7% less than or equal to R-obs less than or equal to 3.6%) and a biotite-2M(1) (space group C2/c, R-obs = 2.8%) show that Al substitutes for divalent cations in the octahedral M2 site and that the Fe and Mg distribution is disordered. The mean tetrahedral bond lengths determined for biotite-2M(1) reflect Al-Si disorder. In coexisting muscovite-2M(1) crystals, small positive electron density residuals close to M1 site position as well as the increase in M2 mean atomic number is in agreement with the presence of a significant phengitic component. Reduction in biotite unit-cell dimensions with the increase of Al follows a pattern similar to that of associated muscovites. and the octahedral site volumes of both micas are influenced by the Al saturation index (ASI) of the rock. These results, and the calculated partition coefficients between biotite and muscovite for elements in M sites, are consistent with continuous reaction and re-equilibration of biotite and muscovite during crystallization of peraluminous granitic melts. Article in Journal/Newspaper Antarc* Antarctica Victoria Land Archivio della ricerca dell'Università di Modena e Reggio Emilia (Unimore: IRIS) Victoria Land American Mineralogist 85 3-4 436 448 |
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Open Polar |
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Archivio della ricerca dell'Università di Modena e Reggio Emilia (Unimore: IRIS) |
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ftunivmodena |
language |
English |
topic |
biotiti crystal chemistry |
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biotiti crystal chemistry BRIGATTI, Maria Franca POPPI, Luciano P. Frigieri C. Ghezzo Crystal chemistry of Al-rich biotites coexisting with muscovites in peraluminous granites |
topic_facet |
biotiti crystal chemistry |
description |
A comparison was made between single-crystal structure refinements, electron microprobe analy ses and octahedral site populations of seven biotite crystals and data obtained previously for coexisting muscovite in peraluminous granites using the same methods. Both micas, From several plutons of Northern Victoria Land (Antarctica) and Sardinia (Italy), show significant octahedral substitutions: biotite has a composition characterized by relatively high Al-[6] content (0.32 less than or equal to Al-[6] less than or equal to 0.59 apfu), whereas muscovite is characterized by phengite-like substitutions [0.12 less than or equal to ([6])(Mg + Fe + Ti + Mn) less than or equal to 0.35]. Mean bond-lengths and electron count data for six biotites-1M (space group C2/m. agreement factor 2.7% less than or equal to R-obs less than or equal to 3.6%) and a biotite-2M(1) (space group C2/c, R-obs = 2.8%) show that Al substitutes for divalent cations in the octahedral M2 site and that the Fe and Mg distribution is disordered. The mean tetrahedral bond lengths determined for biotite-2M(1) reflect Al-Si disorder. In coexisting muscovite-2M(1) crystals, small positive electron density residuals close to M1 site position as well as the increase in M2 mean atomic number is in agreement with the presence of a significant phengitic component. Reduction in biotite unit-cell dimensions with the increase of Al follows a pattern similar to that of associated muscovites. and the octahedral site volumes of both micas are influenced by the Al saturation index (ASI) of the rock. These results, and the calculated partition coefficients between biotite and muscovite for elements in M sites, are consistent with continuous reaction and re-equilibration of biotite and muscovite during crystallization of peraluminous granitic melts. |
author2 |
Brigatti, Maria Franca P., Frigieri C., Ghezzo Poppi, Luciano |
format |
Article in Journal/Newspaper |
author |
BRIGATTI, Maria Franca POPPI, Luciano P. Frigieri C. Ghezzo |
author_facet |
BRIGATTI, Maria Franca POPPI, Luciano P. Frigieri C. Ghezzo |
author_sort |
BRIGATTI, Maria Franca |
title |
Crystal chemistry of Al-rich biotites coexisting with muscovites in peraluminous granites |
title_short |
Crystal chemistry of Al-rich biotites coexisting with muscovites in peraluminous granites |
title_full |
Crystal chemistry of Al-rich biotites coexisting with muscovites in peraluminous granites |
title_fullStr |
Crystal chemistry of Al-rich biotites coexisting with muscovites in peraluminous granites |
title_full_unstemmed |
Crystal chemistry of Al-rich biotites coexisting with muscovites in peraluminous granites |
title_sort |
crystal chemistry of al-rich biotites coexisting with muscovites in peraluminous granites |
publishDate |
2000 |
url |
http://hdl.handle.net/11380/305778 https://doi.org/10.2138/am-2000-0405 |
geographic |
Victoria Land |
geographic_facet |
Victoria Land |
genre |
Antarc* Antarctica Victoria Land |
genre_facet |
Antarc* Antarctica Victoria Land |
op_relation |
info:eu-repo/semantics/altIdentifier/wos/WOS:000085702400005 volume:85 issue:3-4 firstpage:436 lastpage:448 journal:AMERICAN MINERALOGIST http://hdl.handle.net/11380/305778 doi:10.2138/am-2000-0405 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-0034097263 |
op_doi |
https://doi.org/10.2138/am-2000-0405 |
container_title |
American Mineralogist |
container_volume |
85 |
container_issue |
3-4 |
container_start_page |
436 |
op_container_end_page |
448 |
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1796300116414431232 |