A new zeolite topology deriving from levyne dehydration.
Knowledge of the structural modifications induced by temperature in zeolites and of their stability fields is of prime importance to assess zeolite persistence and effectiveness in their technological applications. Some porous materials, when completely dehydrated, undergo irreversible changes in th...
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ftunivmodena:oai:iris.unimore.it:11380/1061049 2024-01-21T10:07:30+01:00 A new zeolite topology deriving from levyne dehydration. Arletti, R. Quartieri, S. Alvaro, M. Càmara, F. VEZZALINI, Maria Giovanna Arletti, R. Quartieri, S. Vezzalini, Maria Giovanna Alvaro, M. Càmara, F. 2012 STAMPA http://hdl.handle.net/11380/1061049 eng eng - country:ITA place:Torino ispartofbook:Atti del V International Workshop OXIDES 2012 joined with AIZ V International Workshop OXIDES 2012 joined with AIZ volume:1 firstpage:158 lastpage:158 http://hdl.handle.net/11380/1061049 zeolite levyne dehydration phase transition structure info:eu-repo/semantics/conferenceObject 2012 ftunivmodena 2023-12-26T23:15:40Z Knowledge of the structural modifications induced by temperature in zeolites and of their stability fields is of prime importance to assess zeolite persistence and effectiveness in their technological applications. Some porous materials, when completely dehydrated, undergo irreversible changes in the framework topology. In general, these changes are due to the strain induced by migration of cations - initially located in the channels and surrounded by water molecules - to achieve a better coordination with framework anions after the water release. Notwithstanding the spread interest for porous materials with levyne topology (LEV), their thermal behavior and stability have not been studied in detail up to now. In this work, the thermal induced structural modifications of a natural levyne from Fagridalur (Iceland) (Ca7.8 Na2.2K1.1Al19.8Si31.2O10851H2O, a= 13.3619(4) Å, c= 22.8820(1) Å, V = 3538.0(3) Å3, s.g. R-3m) were studied by both temperature-resolved synchrotron X-ray powder diffraction experiments (SR-XRPD), and by conventional-source high-temperature single crystal X-ray diffraction (SC-XRD). LEV framework consists of stacking 6-rings perpendicular to [0001] (6mR) in the sequence AABCCABBC (Merlino et al. 1975). Levyne cage is confined by two pairs of 6mR (D6R building units), and contains the non-framework cations and water molecules. A three-dimensional channel system, confined by 8-membered rings, lies perpendicular to [0001]. The SR-XRPD patterns were collected in continuum from room-T to 800°C, while SC-XRD experiments were performed at room-T, 30, 100 and 250°C. Below 100°C a lattice parameter increases, while c decreases, accounting for a very low volume reduction and few water molecule loss. Between 100 and 200 °C, the release of more than 23 water molecules induces the cations migration toward the framework oxygen atoms, so to achieve a better coordination. Above 230°C, a further water loss induces the breaking of the oxygen bridges in the D6R, the edge-sharing tetrahedral phenomenon and the ... Conference Object Iceland Archivio della ricerca dell'Università di Modena e Reggio Emilia (Unimore: IRIS) |
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Archivio della ricerca dell'Università di Modena e Reggio Emilia (Unimore: IRIS) |
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English |
topic |
zeolite levyne dehydration phase transition structure |
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zeolite levyne dehydration phase transition structure Arletti, R. Quartieri, S. Alvaro, M. Càmara, F. VEZZALINI, Maria Giovanna A new zeolite topology deriving from levyne dehydration. |
topic_facet |
zeolite levyne dehydration phase transition structure |
description |
Knowledge of the structural modifications induced by temperature in zeolites and of their stability fields is of prime importance to assess zeolite persistence and effectiveness in their technological applications. Some porous materials, when completely dehydrated, undergo irreversible changes in the framework topology. In general, these changes are due to the strain induced by migration of cations - initially located in the channels and surrounded by water molecules - to achieve a better coordination with framework anions after the water release. Notwithstanding the spread interest for porous materials with levyne topology (LEV), their thermal behavior and stability have not been studied in detail up to now. In this work, the thermal induced structural modifications of a natural levyne from Fagridalur (Iceland) (Ca7.8 Na2.2K1.1Al19.8Si31.2O10851H2O, a= 13.3619(4) Å, c= 22.8820(1) Å, V = 3538.0(3) Å3, s.g. R-3m) were studied by both temperature-resolved synchrotron X-ray powder diffraction experiments (SR-XRPD), and by conventional-source high-temperature single crystal X-ray diffraction (SC-XRD). LEV framework consists of stacking 6-rings perpendicular to [0001] (6mR) in the sequence AABCCABBC (Merlino et al. 1975). Levyne cage is confined by two pairs of 6mR (D6R building units), and contains the non-framework cations and water molecules. A three-dimensional channel system, confined by 8-membered rings, lies perpendicular to [0001]. The SR-XRPD patterns were collected in continuum from room-T to 800°C, while SC-XRD experiments were performed at room-T, 30, 100 and 250°C. Below 100°C a lattice parameter increases, while c decreases, accounting for a very low volume reduction and few water molecule loss. Between 100 and 200 °C, the release of more than 23 water molecules induces the cations migration toward the framework oxygen atoms, so to achieve a better coordination. Above 230°C, a further water loss induces the breaking of the oxygen bridges in the D6R, the edge-sharing tetrahedral phenomenon and the ... |
author2 |
Arletti, R. Quartieri, S. Vezzalini, Maria Giovanna Alvaro, M. Càmara, F. |
format |
Conference Object |
author |
Arletti, R. Quartieri, S. Alvaro, M. Càmara, F. VEZZALINI, Maria Giovanna |
author_facet |
Arletti, R. Quartieri, S. Alvaro, M. Càmara, F. VEZZALINI, Maria Giovanna |
author_sort |
Arletti, R. |
title |
A new zeolite topology deriving from levyne dehydration. |
title_short |
A new zeolite topology deriving from levyne dehydration. |
title_full |
A new zeolite topology deriving from levyne dehydration. |
title_fullStr |
A new zeolite topology deriving from levyne dehydration. |
title_full_unstemmed |
A new zeolite topology deriving from levyne dehydration. |
title_sort |
new zeolite topology deriving from levyne dehydration. |
publisher |
- |
publishDate |
2012 |
url |
http://hdl.handle.net/11380/1061049 |
genre |
Iceland |
genre_facet |
Iceland |
op_relation |
ispartofbook:Atti del V International Workshop OXIDES 2012 joined with AIZ V International Workshop OXIDES 2012 joined with AIZ volume:1 firstpage:158 lastpage:158 http://hdl.handle.net/11380/1061049 |
_version_ |
1788698094398865408 |