Nafertisite, Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2, from Mt. Kukisvumchorr, khibiny alkaline massif, kola peninsula, Russia : refinement of the crystal structure and revision of the chemical formula
The crystal structure of nafertisite, Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2, from Mt. Kukisvumchorr, Khibiny alkaline massif, Kola peninsula, Russia, a 5.358(1), b 16.204(3), c 21.976(4) Å , β 94.91(1)Å3, V 1901.0(7) Å3, space group A2/m, Z = 2, Dcalc. 3.116 g/cm3, has been refined to an R1 value of 5...
Published in: | European Journal of Mineralogy |
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Online Access: | http://hdl.handle.net/2434/477220 https://doi.org/10.1127/0935-1221/2014/0026-2401 |
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ftunivmilanoair:oai:air.unimi.it:2434/477220 2023-12-31T10:08:57+01:00 Nafertisite, Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2, from Mt. Kukisvumchorr, khibiny alkaline massif, kola peninsula, Russia : refinement of the crystal structure and revision of the chemical formula F. Cámara E. Sokolova Y. A. Abdu F. C. Hawthorne F . C á m a r ; E S o k l v ; Y A b d u ; F H w t h n e 2014-09 http://hdl.handle.net/2434/477220 https://doi.org/10.1127/0935-1221/2014/0026-2401 eng eng Schweizerbart'sche info:eu-repo/semantics/altIdentifier/wos/WOS:000343780600008 volume:26 issue:5 firstpage:689 lastpage:700 numberofpages:12 journal:EUROPEAN JOURNAL OF MINERALOGY http://hdl.handle.net/2434/477220 doi:10.1127/0935-1221/2014/0026-2401 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-84910073642 info:eu-repo/semantics/closedAccess Electron-microprobe analysi FTIR spectroscopy Mössbauer spectroscopy Nafertisite Nafertisite T6O17 ribbon Raman spectroscopy Structure refinement Settore GEO/06 - Mineralogia info:eu-repo/semantics/article 2014 ftunivmilanoair https://doi.org/10.1127/0935-1221/2014/0026-2401 2023-12-05T23:26:51Z The crystal structure of nafertisite, Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2, from Mt. Kukisvumchorr, Khibiny alkaline massif, Kola peninsula, Russia, a 5.358(1), b 16.204(3), c 21.976(4) Å , β 94.91(1)Å3, V 1901.0(7) Å3, space group A2/m, Z = 2, Dcalc. 3.116 g/cm3, has been refined to an R1 value of 5.60%for 2747 observed [Fo.4σF] unique reflections collected with a single-crystal diffractometer. The crystal used in the collection of the X-ray intensity data was analyzed by electron microprobe; the Fe3+/ (Fe2++Fe3+) ratio was measured by Mössbauer spectroscopy, and FTIR and Raman spectra were collected. The empirical formula was calculated on the basis of (O + F + OH + H2O) = 44.39 pfu: (Na1.39K0.61)σ2Na1(Rb0.06Cs0.02□0.92)σ1(Fe2+9.11Mg0.46Mn0.22 Al0.10Na0.09Ca0.02)σ10 (Ti1.90Nb0.05Mg0.03Zr0.02)σ2[(Si11.81Al0.19)sigma;12O34]O2(OH)6 (F0.86O0.14)σ1(H2O)1.39; Z=2; the content of H2O was calculated from the structure-refinement results. The HOH layer is the main structural unit in nafertisite. It consists of a central octahedral (O) sheet and two adjacent heteropolyhedral (H) sheets. The O sheet is composed of Fe2+-dominant M(1-3) octahedra, the M(1-3) sites are fully occupied and the ideal composition of the O sheet is Fe2+10apfu. The H sheet is composed of the nafertisite T6O17 ribbons and Ti-dominant D octahedra. The chemical composition of the nafertisite ribbon is (Si11.81Al0.19)O34 apfu, ideally (Si6O17)2 pfu. In the crystal structure of nafertisite, HOH layers alternate with intermediate (I) blocks along c. In the I block, the A, B, C and W sites are occupied by (Na1.39K0.61), Na, (□;0.92Rb0.06Cs0.02) and [(H2O)1.39□0.61] pfu, respectively. The chemical composition of the I block of the general formula A2BCW is [(Na1.39 K0.61)Na1(□0.92Rb0.06Cs0.02)(H2O)1.39] pfu, ideally Na3(H2O)2 pfu. Nafertisite is closely related to the astrophyllite-group minerals. Article in Journal/Newspaper kola peninsula The University of Milan: Archivio Istituzionale della Ricerca (AIR) European Journal of Mineralogy 26 5 689 700 |
institution |
Open Polar |
collection |
The University of Milan: Archivio Istituzionale della Ricerca (AIR) |
op_collection_id |
ftunivmilanoair |
language |
English |
topic |
Electron-microprobe analysi FTIR spectroscopy Mössbauer spectroscopy Nafertisite Nafertisite T6O17 ribbon Raman spectroscopy Structure refinement Settore GEO/06 - Mineralogia |
spellingShingle |
Electron-microprobe analysi FTIR spectroscopy Mössbauer spectroscopy Nafertisite Nafertisite T6O17 ribbon Raman spectroscopy Structure refinement Settore GEO/06 - Mineralogia F. Cámara E. Sokolova Y. A. Abdu F. C. Hawthorne Nafertisite, Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2, from Mt. Kukisvumchorr, khibiny alkaline massif, kola peninsula, Russia : refinement of the crystal structure and revision of the chemical formula |
topic_facet |
Electron-microprobe analysi FTIR spectroscopy Mössbauer spectroscopy Nafertisite Nafertisite T6O17 ribbon Raman spectroscopy Structure refinement Settore GEO/06 - Mineralogia |
description |
The crystal structure of nafertisite, Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2, from Mt. Kukisvumchorr, Khibiny alkaline massif, Kola peninsula, Russia, a 5.358(1), b 16.204(3), c 21.976(4) Å , β 94.91(1)Å3, V 1901.0(7) Å3, space group A2/m, Z = 2, Dcalc. 3.116 g/cm3, has been refined to an R1 value of 5.60%for 2747 observed [Fo.4σF] unique reflections collected with a single-crystal diffractometer. The crystal used in the collection of the X-ray intensity data was analyzed by electron microprobe; the Fe3+/ (Fe2++Fe3+) ratio was measured by Mössbauer spectroscopy, and FTIR and Raman spectra were collected. The empirical formula was calculated on the basis of (O + F + OH + H2O) = 44.39 pfu: (Na1.39K0.61)σ2Na1(Rb0.06Cs0.02□0.92)σ1(Fe2+9.11Mg0.46Mn0.22 Al0.10Na0.09Ca0.02)σ10 (Ti1.90Nb0.05Mg0.03Zr0.02)σ2[(Si11.81Al0.19)sigma;12O34]O2(OH)6 (F0.86O0.14)σ1(H2O)1.39; Z=2; the content of H2O was calculated from the structure-refinement results. The HOH layer is the main structural unit in nafertisite. It consists of a central octahedral (O) sheet and two adjacent heteropolyhedral (H) sheets. The O sheet is composed of Fe2+-dominant M(1-3) octahedra, the M(1-3) sites are fully occupied and the ideal composition of the O sheet is Fe2+10apfu. The H sheet is composed of the nafertisite T6O17 ribbons and Ti-dominant D octahedra. The chemical composition of the nafertisite ribbon is (Si11.81Al0.19)O34 apfu, ideally (Si6O17)2 pfu. In the crystal structure of nafertisite, HOH layers alternate with intermediate (I) blocks along c. In the I block, the A, B, C and W sites are occupied by (Na1.39K0.61), Na, (□;0.92Rb0.06Cs0.02) and [(H2O)1.39□0.61] pfu, respectively. The chemical composition of the I block of the general formula A2BCW is [(Na1.39 K0.61)Na1(□0.92Rb0.06Cs0.02)(H2O)1.39] pfu, ideally Na3(H2O)2 pfu. Nafertisite is closely related to the astrophyllite-group minerals. |
author2 |
F . C á m a r ; E S o k l v ; Y A b d u ; F H w t h n e |
format |
Article in Journal/Newspaper |
author |
F. Cámara E. Sokolova Y. A. Abdu F. C. Hawthorne |
author_facet |
F. Cámara E. Sokolova Y. A. Abdu F. C. Hawthorne |
author_sort |
F. Cámara |
title |
Nafertisite, Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2, from Mt. Kukisvumchorr, khibiny alkaline massif, kola peninsula, Russia : refinement of the crystal structure and revision of the chemical formula |
title_short |
Nafertisite, Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2, from Mt. Kukisvumchorr, khibiny alkaline massif, kola peninsula, Russia : refinement of the crystal structure and revision of the chemical formula |
title_full |
Nafertisite, Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2, from Mt. Kukisvumchorr, khibiny alkaline massif, kola peninsula, Russia : refinement of the crystal structure and revision of the chemical formula |
title_fullStr |
Nafertisite, Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2, from Mt. Kukisvumchorr, khibiny alkaline massif, kola peninsula, Russia : refinement of the crystal structure and revision of the chemical formula |
title_full_unstemmed |
Nafertisite, Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2, from Mt. Kukisvumchorr, khibiny alkaline massif, kola peninsula, Russia : refinement of the crystal structure and revision of the chemical formula |
title_sort |
nafertisite, na3fe2+10ti2(si6o17)2o2(oh)6f(h2o)2, from mt. kukisvumchorr, khibiny alkaline massif, kola peninsula, russia : refinement of the crystal structure and revision of the chemical formula |
publisher |
Schweizerbart'sche |
publishDate |
2014 |
url |
http://hdl.handle.net/2434/477220 https://doi.org/10.1127/0935-1221/2014/0026-2401 |
genre |
kola peninsula |
genre_facet |
kola peninsula |
op_relation |
info:eu-repo/semantics/altIdentifier/wos/WOS:000343780600008 volume:26 issue:5 firstpage:689 lastpage:700 numberofpages:12 journal:EUROPEAN JOURNAL OF MINERALOGY http://hdl.handle.net/2434/477220 doi:10.1127/0935-1221/2014/0026-2401 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-84910073642 |
op_rights |
info:eu-repo/semantics/closedAccess |
op_doi |
https://doi.org/10.1127/0935-1221/2014/0026-2401 |
container_title |
European Journal of Mineralogy |
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26 |
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5 |
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689 |
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700 |
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1786841912535154688 |