Bioctive glycoglycerolipid analogues: an expeditious enzymatic approach to mono- and diesters of 2-O-beta-D-galactoglycerol

2-O-β-D-Galactosylglycerol 1 was submitted to acylation using Pseudomonas cepacia or Candida antarctica lipases as catalysts and 2,2,2- trifluoroethyl esters of butanoic, hexanoic, octanoic or decanoic acid as acyl carriers. Taking advantage of the high diastereoselectivity and regioselectivity of t...

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Published in:Tetrahedron: Asymmetry
Main Authors: D. Colombo, F. Ronchetti, A. Scala, L. Toma
Format: Article in Journal/Newspaper
Language:English
Published: 1998
Subjects:
Settore BIO/10 - Biochimica
Antarc*
Antarctica
Online Access:http://hdl.handle.net/2434/182045
https://doi.org/10.1016/S0957-4166(98)00207-9
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spelling ftunivmilanoair:oai:air.unimi.it:2434/182045 2024-04-21T07:46:48+00:00 Bioctive glycoglycerolipid analogues: an expeditious enzymatic approach to mono- and diesters of 2-O-beta-D-galactoglycerol D. Colombo F. Ronchetti A. Scala L. Toma D. Colombo F. Ronchetti A. Scala L. Toma 1998 http://hdl.handle.net/2434/182045 https://doi.org/10.1016/S0957-4166(98)00207-9 eng eng info:eu-repo/semantics/altIdentifier/wos/WOS:000074743700014 volume:9 issue:12 firstpage:2113 lastpage:2119 journal:TETRAHEDRON-ASYMMETRY http://hdl.handle.net/2434/182045 doi:10.1016/S0957-4166(98)00207-9 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-0032547028 Settore BIO/10 - Biochimica info:eu-repo/semantics/article 1998 ftunivmilanoair https://doi.org/10.1016/S0957-4166(98)00207-9 2024-03-27T01:55:43Z 2-O-β-D-Galactosylglycerol 1 was submitted to acylation using Pseudomonas cepacia or Candida antarctica lipases as catalysts and 2,2,2- trifluoroethyl esters of butanoic, hexanoic, octanoic or decanoic acid as acyl carriers. Taking advantage of the high diastereoselectivity and regioselectivity of the two enzymes, the 1-O-, 3-O-, 6'-O-acyl and the 1,6'- di-O-acylderivatives of 1 were obtained pure or in an appreciably enriched form. Article in Journal/Newspaper Antarc* Antarctica The University of Milan: Archivio Istituzionale della Ricerca (AIR) Tetrahedron: Asymmetry 9 12 2113 2119
institution Open Polar
collection The University of Milan: Archivio Istituzionale della Ricerca (AIR)
op_collection_id ftunivmilanoair
language English
topic Settore BIO/10 - Biochimica
spellingShingle Settore BIO/10 - Biochimica
D. Colombo
F. Ronchetti
A. Scala
L. Toma
Bioctive glycoglycerolipid analogues: an expeditious enzymatic approach to mono- and diesters of 2-O-beta-D-galactoglycerol
topic_facet Settore BIO/10 - Biochimica
description 2-O-β-D-Galactosylglycerol 1 was submitted to acylation using Pseudomonas cepacia or Candida antarctica lipases as catalysts and 2,2,2- trifluoroethyl esters of butanoic, hexanoic, octanoic or decanoic acid as acyl carriers. Taking advantage of the high diastereoselectivity and regioselectivity of the two enzymes, the 1-O-, 3-O-, 6'-O-acyl and the 1,6'- di-O-acylderivatives of 1 were obtained pure or in an appreciably enriched form.
author2 D. Colombo
F. Ronchetti
A. Scala
L. Toma
format Article in Journal/Newspaper
author D. Colombo
F. Ronchetti
A. Scala
L. Toma
author_facet D. Colombo
F. Ronchetti
A. Scala
L. Toma
author_sort D. Colombo
title Bioctive glycoglycerolipid analogues: an expeditious enzymatic approach to mono- and diesters of 2-O-beta-D-galactoglycerol
title_short Bioctive glycoglycerolipid analogues: an expeditious enzymatic approach to mono- and diesters of 2-O-beta-D-galactoglycerol
title_full Bioctive glycoglycerolipid analogues: an expeditious enzymatic approach to mono- and diesters of 2-O-beta-D-galactoglycerol
title_fullStr Bioctive glycoglycerolipid analogues: an expeditious enzymatic approach to mono- and diesters of 2-O-beta-D-galactoglycerol
title_full_unstemmed Bioctive glycoglycerolipid analogues: an expeditious enzymatic approach to mono- and diesters of 2-O-beta-D-galactoglycerol
title_sort bioctive glycoglycerolipid analogues: an expeditious enzymatic approach to mono- and diesters of 2-o-beta-d-galactoglycerol
publishDate 1998
url http://hdl.handle.net/2434/182045
https://doi.org/10.1016/S0957-4166(98)00207-9
genre Antarc*
Antarctica
genre_facet Antarc*
Antarctica
op_relation info:eu-repo/semantics/altIdentifier/wos/WOS:000074743700014
volume:9
issue:12
firstpage:2113
lastpage:2119
journal:TETRAHEDRON-ASYMMETRY
http://hdl.handle.net/2434/182045
doi:10.1016/S0957-4166(98)00207-9
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-0032547028
op_doi https://doi.org/10.1016/S0957-4166(98)00207-9
container_title Tetrahedron: Asymmetry
container_volume 9
container_issue 12
container_start_page 2113
op_container_end_page 2119
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