On the evolution of atmosphere-ocean oxygenation and plate tectonic processes as recorded in Paleoproterozoic sedimentary basins

• Published in: Chemical Geology
• Main Author: Partin, Camille Ann
• Other Authors: Bekker, Andrey (Geological Sciences), Camacho, Alfredo (Geological Sciences) Wang, Feiyue (Chemistry) Galven Halverson (Earth and Planetary Sciences, McGill University)
• Format: Doctoral or Postdoctoral Thesis
• Language: English
• Published: Elsevier 2013
• Subjects: Paleoproterozoic; Great Oxidation Event; rise of atmospheric oxygen; U-Pb geochronology; chemostratigraphy; Rae craton; geochemical uranium cycle; global magmatic shutdown; basin analysis; Arctic; Canada; Rae
• Online Access: http://hdl.handle.net/1993/22727

Important geochemical and tectonic events in the Paleoproterozoic Era lay the foundation for the status and operation of the modern Earth, including the initial rise of atmospheric oxygen paving the path for animal evolution, and the emergence of modern plate tectonic processes leading to the amalgamation of the Canadian Shield (Laurentia). Rudimentary geological and geochronological documentation of Paleoproterozoic sedimentary basins is the foundation from which we can ask larger questions about geochemical changes or plate tectonic events on the evolving Earth, since those questions are largely answered by analyzing the sedimentary record. This thesis outlines the stratigraphy, detrital zircon U-Pb geochronology, elemental and isotopic geochemistry, and basin evolution of the Paleoproterozoic Penrhyn and Piling basins on the Rae craton in Arctic Canada, which record important tectonic and geochemical events on both a regional and global scale. The concentration of the redox-sensitive trace element, U, in seawater has not been constant throughout geologic time and is linked to changes in oceanic and atmospheric oxygen content. Secular variations in the record of U contents of shales and iron formations indicate that the redox state of the atmosphere-ocean system after the Great Oxidation Event (GOE) was more dynamic than previously thought. Trends towards lower oxygen content recorded after ~2.05 Ga in the middle Proterozoic suggest that oxygen level decreased. This is contrary to traditional models assuming unidirectional atmospheric oxygen rise throughout the Proterozoic. The data demonstrate the earliest signal of oxidative U cycling, manifested in 2.47 - 2.43 Ga iron formations, and show that oxygenation was a protracted process initiated shortly after the end of the Archean. It has been proposed that a global and long-lived magmatic and tectonic shutdown event from ~2.45 to 2.22 Ga played a causal role in the GOE, since it overlaps the time interval in which atmospheric oxygen initially rose on Earth. ...