Natural and Anthropogenic Influences on Atmospheric Aerosol Variability

• Main Author: Asmi, Ari
• Other Authors: Maßling, Andreas, University of Helsinki, Faculty of Science, Department of Physics, Division of Atmospheric Sciences, Helsingin yliopisto, matemaattis-luonnontieteellinen tiedekunta, fysiikan laitos, Helsingfors universitet, matematisk-naturvetenskapliga fakulteten, institutionen för fysik, Kulmala, Markku, Kerminen, Veli-Matti
• Format: Doctoral or Postdoctoral Thesis
• Language: English
• Published: Helsingin yliopisto 2012
• Subjects: fysiikka; Pacific; Antarc*; Antarctica
• Online Access: http://hdl.handle.net/10138/37607

Aerosol particles are everywhere in the atmosphere. They are a key factor in many important processes in the atmosphere, including cloud formation, scattering of incoming solar radiation and air chemistry. The aerosol particles have relatively short lifetimes in lower atmosphere, typically from days to weeks, and thus they have a high spatial and temporal variability. This thesis concentrates on the extent and reasons of sub-micron aerosol particle variability in the lower atmosphere, using both global atmospheric models and analysis of observational data. Aerosol number size distributions in the lower atmosphere are affected strongly by the new particle formation. Perhaps more importantly, a strong influence new particle formation is also evident in the cloud condensation nuclei (CCN) concentrations, suggesting a major role of the sulphuric acid driven new particle formation in the climate system. In this thesis, the sub-micron aerosol number size distributions in the European regional background air were characterized for the first time from consistent, homogenized and comparable datasets. Some recent studies have suggested that differences in aerosol emissions between weekdays could also affect the weather via aerosol-cloud interactions. In this thesis, the weekday-to-weekday variation of CCN sized aerosol number concentrations in Europe were found to be much smaller than expected from earlier studies, based on particle mass measurements. This result suggests that a lack of week-day variability in meteorology is not necessarily a sign of weak aerosol-cloud interactions. An analysis of statistically significant trends in past decades of measured aerosol number concentrations from Europe, North America, Pacific islands and Antarctica generally show decreases in concentrations. The analysis of these changes show that a potential explanation for the decreasing trends is the general reduction of anthropogenic emissions, especially SO2, although a combination of several drivers for these changes in the number ...