A global study of hygroscopicity-driven light-scattering enhancement in the context of other in situ aerosol optical properties
The scattering and backscattering enhancement factors (f (RH) and f(b)(RH)) describe how aerosol particle light scattering and backscattering, respectively, change with relative humidity (RH). They are important parameters in estimating direct aerosol radiative forcing (DARF). In this study we use t...
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COPERNICUS GESELLSCHAFT MBH
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ftunivhelsihelda:oai:helda.helsinki.fi:10138/335980 2024-01-07T09:38:05+01:00 A global study of hygroscopicity-driven light-scattering enhancement in the context of other in situ aerosol optical properties Titos, Gloria Burgos, Maria A. Zieger, Paul Alados-Arboledas, Lucas Baltensperger, Urs Jefferson, Anne Sherman, James Weingartner, Ernest Henzing, Bas Luoma, Krista O'Dowd, Colin Wiedensohler, Alfred Andrews, Elisabeth Institute for Atmospheric and Earth System Research (INAR) 2021-11-03T09:26:02Z 20 application/pdf http://hdl.handle.net/10138/335980 eng eng COPERNICUS GESELLSCHAFT MBH 10.5194/acp-21-13031-2021 This research has been supported by the Department of Energy, Labor and Economic Growth (grant no. DESC0016541). Titos , G , Burgos , M A , Zieger , P , Alados-Arboledas , L , Baltensperger , U , Jefferson , A , Sherman , J , Weingartner , E , Henzing , B , Luoma , K , O'Dowd , C , Wiedensohler , A & Andrews , E 2021 , ' A global study of hygroscopicity-driven light-scattering enhancement in the context of other in situ aerosol optical properties ' , Atmospheric Chemistry and Physics , vol. 21 , no. 17 , pp. 13031-13050 . https://doi.org/10.5194/acp-21-13031-2021 ORCID: /0000-0001-8841-3050/work/102573301 85114346310 a464778c-bbb6-4da1-9164-3d5518801f35 http://hdl.handle.net/10138/335980 000692941900004 cc_by openAccess info:eu-repo/semantics/openAccess 114 Physical sciences Article publishedVersion 2021 ftunivhelsihelda 2023-12-14T00:03:34Z The scattering and backscattering enhancement factors (f (RH) and f(b)(RH)) describe how aerosol particle light scattering and backscattering, respectively, change with relative humidity (RH). They are important parameters in estimating direct aerosol radiative forcing (DARF). In this study we use the dataset presented in Burgos et al. (2019) that compiles f(RH) and f(b)(RH) measurements at three wavelengths (i.e., 450, 550 and 700 nm) performed with tandem nephelometer systems at multiple sites around the world. We present an overview of f (RH) and f(b)(RH) based on both long-term and campaign observations from 23 sites representing a range of aerosol types. The scattering enhancement shows a strong variability from site to site, with no clear pattern with respect to the total scattering coefficient. In general, higher f(RH) is observed at Arctic and marine sites, while lower values are found at urban and desert sites, although a consistent pattern as a function of site type is not observed. The backscattering enhancement f(b)(RH) is consistently lower than f(RH) at all sites, with the difference between f(RH) and f(b)(RH) increasing for aerosol with higher f(RH). This is consistent with Mie theory, which predicts higher enhancement of the light scattering in the forward than in the backward direction as the particle takes up water. Our results show that the scattering enhancement is higher for PM1 than PM10 at most sites, which is also supported by theory due to the change in scattering efficiency with the size parameter that relates particle size and the wavelength of incident light. At marine-influenced sites this difference is enhanced when coarse particles (likely sea salt) predominate. For most sites, f (RH) is observed to increase with increasing wavelength, except at sites with a known dust influence where the spectral dependence of f (RH) is found to be low or even exhibit the opposite pattern. The impact of RH on aerosol properties used to calculate radiative forcing (e.g., single-scattering albedo, ... Article in Journal/Newspaper albedo Arctic HELDA – University of Helsinki Open Repository Arctic Atmospheric Chemistry and Physics 21 17 13031 13050 |
institution |
Open Polar |
collection |
HELDA – University of Helsinki Open Repository |
op_collection_id |
ftunivhelsihelda |
language |
English |
topic |
114 Physical sciences |
spellingShingle |
114 Physical sciences Titos, Gloria Burgos, Maria A. Zieger, Paul Alados-Arboledas, Lucas Baltensperger, Urs Jefferson, Anne Sherman, James Weingartner, Ernest Henzing, Bas Luoma, Krista O'Dowd, Colin Wiedensohler, Alfred Andrews, Elisabeth A global study of hygroscopicity-driven light-scattering enhancement in the context of other in situ aerosol optical properties |
topic_facet |
114 Physical sciences |
description |
The scattering and backscattering enhancement factors (f (RH) and f(b)(RH)) describe how aerosol particle light scattering and backscattering, respectively, change with relative humidity (RH). They are important parameters in estimating direct aerosol radiative forcing (DARF). In this study we use the dataset presented in Burgos et al. (2019) that compiles f(RH) and f(b)(RH) measurements at three wavelengths (i.e., 450, 550 and 700 nm) performed with tandem nephelometer systems at multiple sites around the world. We present an overview of f (RH) and f(b)(RH) based on both long-term and campaign observations from 23 sites representing a range of aerosol types. The scattering enhancement shows a strong variability from site to site, with no clear pattern with respect to the total scattering coefficient. In general, higher f(RH) is observed at Arctic and marine sites, while lower values are found at urban and desert sites, although a consistent pattern as a function of site type is not observed. The backscattering enhancement f(b)(RH) is consistently lower than f(RH) at all sites, with the difference between f(RH) and f(b)(RH) increasing for aerosol with higher f(RH). This is consistent with Mie theory, which predicts higher enhancement of the light scattering in the forward than in the backward direction as the particle takes up water. Our results show that the scattering enhancement is higher for PM1 than PM10 at most sites, which is also supported by theory due to the change in scattering efficiency with the size parameter that relates particle size and the wavelength of incident light. At marine-influenced sites this difference is enhanced when coarse particles (likely sea salt) predominate. For most sites, f (RH) is observed to increase with increasing wavelength, except at sites with a known dust influence where the spectral dependence of f (RH) is found to be low or even exhibit the opposite pattern. The impact of RH on aerosol properties used to calculate radiative forcing (e.g., single-scattering albedo, ... |
author2 |
Institute for Atmospheric and Earth System Research (INAR) |
format |
Article in Journal/Newspaper |
author |
Titos, Gloria Burgos, Maria A. Zieger, Paul Alados-Arboledas, Lucas Baltensperger, Urs Jefferson, Anne Sherman, James Weingartner, Ernest Henzing, Bas Luoma, Krista O'Dowd, Colin Wiedensohler, Alfred Andrews, Elisabeth |
author_facet |
Titos, Gloria Burgos, Maria A. Zieger, Paul Alados-Arboledas, Lucas Baltensperger, Urs Jefferson, Anne Sherman, James Weingartner, Ernest Henzing, Bas Luoma, Krista O'Dowd, Colin Wiedensohler, Alfred Andrews, Elisabeth |
author_sort |
Titos, Gloria |
title |
A global study of hygroscopicity-driven light-scattering enhancement in the context of other in situ aerosol optical properties |
title_short |
A global study of hygroscopicity-driven light-scattering enhancement in the context of other in situ aerosol optical properties |
title_full |
A global study of hygroscopicity-driven light-scattering enhancement in the context of other in situ aerosol optical properties |
title_fullStr |
A global study of hygroscopicity-driven light-scattering enhancement in the context of other in situ aerosol optical properties |
title_full_unstemmed |
A global study of hygroscopicity-driven light-scattering enhancement in the context of other in situ aerosol optical properties |
title_sort |
global study of hygroscopicity-driven light-scattering enhancement in the context of other in situ aerosol optical properties |
publisher |
COPERNICUS GESELLSCHAFT MBH |
publishDate |
2021 |
url |
http://hdl.handle.net/10138/335980 |
geographic |
Arctic |
geographic_facet |
Arctic |
genre |
albedo Arctic |
genre_facet |
albedo Arctic |
op_relation |
10.5194/acp-21-13031-2021 This research has been supported by the Department of Energy, Labor and Economic Growth (grant no. DESC0016541). Titos , G , Burgos , M A , Zieger , P , Alados-Arboledas , L , Baltensperger , U , Jefferson , A , Sherman , J , Weingartner , E , Henzing , B , Luoma , K , O'Dowd , C , Wiedensohler , A & Andrews , E 2021 , ' A global study of hygroscopicity-driven light-scattering enhancement in the context of other in situ aerosol optical properties ' , Atmospheric Chemistry and Physics , vol. 21 , no. 17 , pp. 13031-13050 . https://doi.org/10.5194/acp-21-13031-2021 ORCID: /0000-0001-8841-3050/work/102573301 85114346310 a464778c-bbb6-4da1-9164-3d5518801f35 http://hdl.handle.net/10138/335980 000692941900004 |
op_rights |
cc_by openAccess info:eu-repo/semantics/openAccess |
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Atmospheric Chemistry and Physics |
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21 |
container_issue |
17 |
container_start_page |
13031 |
op_container_end_page |
13050 |
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1787429558962618368 |