In-Situ Crystallization and Continuous Modification of Chromian Spinel in the "Sulfide-Poor Platinum-Group Metal Ores" of the Norilsk-1 Intrusion (Northern Siberia, Russia)
Layers rich in chromian spinel (Cr-spinel) occur in numerous differentiated and layered intrusions. These layers are often characterized by elevated and even economic concentrations of platinum-group-elements (PGEs), but only scarce sulfide mineralization. One particular type of such lithology occur...
Published in: | Minerals |
---|---|
Main Authors: | , , , , , , , , , |
Other Authors: | |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
MDPI
2021
|
Subjects: | |
Online Access: | http://hdl.handle.net/10138/326914 |
id |
ftunivhelsihelda:oai:helda.helsinki.fi:10138/326914 |
---|---|
record_format |
openpolar |
spelling |
ftunivhelsihelda:oai:helda.helsinki.fi:10138/326914 2024-01-07T09:44:40+01:00 In-Situ Crystallization and Continuous Modification of Chromian Spinel in the "Sulfide-Poor Platinum-Group Metal Ores" of the Norilsk-1 Intrusion (Northern Siberia, Russia) Chayka, Ivan F. Zhitova, Liudmila M. Antsiferova, Tatiana N. Abersteiner, Adam Shevko, Artem Ya Izokh, Andrey E. Tolstykh, Nadezhda D. Gora, Marina P. Chubarov, Valery M. Kamenetsky, Vadim S. Department of Geosciences and Geography 2021-02-23T09:20:02Z 30 application/pdf http://hdl.handle.net/10138/326914 eng eng MDPI 10.3390/min10060498 The study was conducted under the State Assignment to the V.S. Sobolev Institute of Geology and Mineralogy SB RAS and was supported by the Russian Science Foundation grant 19-17-13013. Sampling and analytics were partly supported by the Russian Foundation for Basic Research grant 16-05-00945a. Chayka , I F , Zhitova , L M , Antsiferova , T N , Abersteiner , A , Shevko , A Y , Izokh , A E , Tolstykh , N D , Gora , M P , Chubarov , V M & Kamenetsky , V S 2020 , ' In-Situ Crystallization and Continuous Modification of Chromian Spinel in the "Sulfide-Poor Platinum-Group Metal Ores" of the Norilsk-1 Intrusion (Northern Siberia, Russia) ' , Minerals , vol. 10 , no. 6 , 498 . https://doi.org/10.3390/min10060498 90770dda-31a4-4778-80f6-8044e60af37a http://hdl.handle.net/10138/326914 000551084800001 cc_by openAccess info:eu-repo/semantics/openAccess Cr-spinel chromite layered intrusion Norilsk-1 BUSHVELD COMPLEX OPHIOLITIC COMPLEXES STILLWATER COMPLEX MELT INCLUSIONS OMAN OPHIOLITE KOLA-PENINSULA MAFIC ROCKS KILAUEA IKI ORIGIN 1171 Geosciences Article publishedVersion 2021 ftunivhelsihelda 2023-12-14T00:02:32Z Layers rich in chromian spinel (Cr-spinel) occur in numerous differentiated and layered intrusions. These layers are often characterized by elevated and even economic concentrations of platinum-group-elements (PGEs), but only scarce sulfide mineralization. One particular type of such lithology occurs in the roof parts of the Norilsk-type differentiated intrusions (Russia) and is referred to as the "sulfide-poor PGE ores". We investigated rocks containing variable enrichments in Cr-spinel, sulfides, and platinum-group minerals (PGMs) from two sections of the upper zone of the Norilsk-1 intrusion, with a focus on Cr-spinel. The rocks are dominated by two lithological types: (1) leucogabbro/troctolitic and (2) olivine-gabbro. Fine-grained (5-100 mu m) disperse disseminations with varying modal abundances of Cr-spinel are characteristic for the rocks studied. Those abundances range from scarce mineralization through to very dense (up to 30 vol. % Cr-spinel) cloud-like accumulations. However, compact-grained accumulations and cumulate-like textures, which are typical for chromitites of layered intrusions, are not characteristic for the studied rocks. Instead, the disseminations exhibit chain- and trail-like alignments of Cr-spinel grains, which cross the boundaries between enclosing silicates, and sub-circular arrangements. The study revealed millimeter-scaled patchy distribution of Cr-spinel compositions within a given dissemination with Cr-spinel chemistry being strongly correlated with a kind of the enclosing silicate. (1) In unaltered rocks, plagioclase hosts more magnesian Cr-spinel (Mg# 30-60), while Cr-spinel in mafic minerals is less magnesian (Mg# 18-35). (2) In altered rocks, more magnesian Cr-spinel is hosted by less altered silicates, while strongly altered silicates mainly host less magnesian Cr-spinel. Systematics of trivalent cations exhibits divergent trends, even on a scale of a thin section, and depends on a kind of hosting lithology. Leucogabbro/troctolite lithologies contain Cr-spinel with ... Article in Journal/Newspaper kola peninsula norilsk Siberia HELDA – University of Helsinki Open Repository Kola Peninsula Norilsk ENVELOPE(88.203,88.203,69.354,69.354) Minerals 10 6 498 |
institution |
Open Polar |
collection |
HELDA – University of Helsinki Open Repository |
op_collection_id |
ftunivhelsihelda |
language |
English |
topic |
Cr-spinel chromite layered intrusion Norilsk-1 BUSHVELD COMPLEX OPHIOLITIC COMPLEXES STILLWATER COMPLEX MELT INCLUSIONS OMAN OPHIOLITE KOLA-PENINSULA MAFIC ROCKS KILAUEA IKI ORIGIN 1171 Geosciences |
spellingShingle |
Cr-spinel chromite layered intrusion Norilsk-1 BUSHVELD COMPLEX OPHIOLITIC COMPLEXES STILLWATER COMPLEX MELT INCLUSIONS OMAN OPHIOLITE KOLA-PENINSULA MAFIC ROCKS KILAUEA IKI ORIGIN 1171 Geosciences Chayka, Ivan F. Zhitova, Liudmila M. Antsiferova, Tatiana N. Abersteiner, Adam Shevko, Artem Ya Izokh, Andrey E. Tolstykh, Nadezhda D. Gora, Marina P. Chubarov, Valery M. Kamenetsky, Vadim S. In-Situ Crystallization and Continuous Modification of Chromian Spinel in the "Sulfide-Poor Platinum-Group Metal Ores" of the Norilsk-1 Intrusion (Northern Siberia, Russia) |
topic_facet |
Cr-spinel chromite layered intrusion Norilsk-1 BUSHVELD COMPLEX OPHIOLITIC COMPLEXES STILLWATER COMPLEX MELT INCLUSIONS OMAN OPHIOLITE KOLA-PENINSULA MAFIC ROCKS KILAUEA IKI ORIGIN 1171 Geosciences |
description |
Layers rich in chromian spinel (Cr-spinel) occur in numerous differentiated and layered intrusions. These layers are often characterized by elevated and even economic concentrations of platinum-group-elements (PGEs), but only scarce sulfide mineralization. One particular type of such lithology occurs in the roof parts of the Norilsk-type differentiated intrusions (Russia) and is referred to as the "sulfide-poor PGE ores". We investigated rocks containing variable enrichments in Cr-spinel, sulfides, and platinum-group minerals (PGMs) from two sections of the upper zone of the Norilsk-1 intrusion, with a focus on Cr-spinel. The rocks are dominated by two lithological types: (1) leucogabbro/troctolitic and (2) olivine-gabbro. Fine-grained (5-100 mu m) disperse disseminations with varying modal abundances of Cr-spinel are characteristic for the rocks studied. Those abundances range from scarce mineralization through to very dense (up to 30 vol. % Cr-spinel) cloud-like accumulations. However, compact-grained accumulations and cumulate-like textures, which are typical for chromitites of layered intrusions, are not characteristic for the studied rocks. Instead, the disseminations exhibit chain- and trail-like alignments of Cr-spinel grains, which cross the boundaries between enclosing silicates, and sub-circular arrangements. The study revealed millimeter-scaled patchy distribution of Cr-spinel compositions within a given dissemination with Cr-spinel chemistry being strongly correlated with a kind of the enclosing silicate. (1) In unaltered rocks, plagioclase hosts more magnesian Cr-spinel (Mg# 30-60), while Cr-spinel in mafic minerals is less magnesian (Mg# 18-35). (2) In altered rocks, more magnesian Cr-spinel is hosted by less altered silicates, while strongly altered silicates mainly host less magnesian Cr-spinel. Systematics of trivalent cations exhibits divergent trends, even on a scale of a thin section, and depends on a kind of hosting lithology. Leucogabbro/troctolite lithologies contain Cr-spinel with ... |
author2 |
Department of Geosciences and Geography |
format |
Article in Journal/Newspaper |
author |
Chayka, Ivan F. Zhitova, Liudmila M. Antsiferova, Tatiana N. Abersteiner, Adam Shevko, Artem Ya Izokh, Andrey E. Tolstykh, Nadezhda D. Gora, Marina P. Chubarov, Valery M. Kamenetsky, Vadim S. |
author_facet |
Chayka, Ivan F. Zhitova, Liudmila M. Antsiferova, Tatiana N. Abersteiner, Adam Shevko, Artem Ya Izokh, Andrey E. Tolstykh, Nadezhda D. Gora, Marina P. Chubarov, Valery M. Kamenetsky, Vadim S. |
author_sort |
Chayka, Ivan F. |
title |
In-Situ Crystallization and Continuous Modification of Chromian Spinel in the "Sulfide-Poor Platinum-Group Metal Ores" of the Norilsk-1 Intrusion (Northern Siberia, Russia) |
title_short |
In-Situ Crystallization and Continuous Modification of Chromian Spinel in the "Sulfide-Poor Platinum-Group Metal Ores" of the Norilsk-1 Intrusion (Northern Siberia, Russia) |
title_full |
In-Situ Crystallization and Continuous Modification of Chromian Spinel in the "Sulfide-Poor Platinum-Group Metal Ores" of the Norilsk-1 Intrusion (Northern Siberia, Russia) |
title_fullStr |
In-Situ Crystallization and Continuous Modification of Chromian Spinel in the "Sulfide-Poor Platinum-Group Metal Ores" of the Norilsk-1 Intrusion (Northern Siberia, Russia) |
title_full_unstemmed |
In-Situ Crystallization and Continuous Modification of Chromian Spinel in the "Sulfide-Poor Platinum-Group Metal Ores" of the Norilsk-1 Intrusion (Northern Siberia, Russia) |
title_sort |
in-situ crystallization and continuous modification of chromian spinel in the "sulfide-poor platinum-group metal ores" of the norilsk-1 intrusion (northern siberia, russia) |
publisher |
MDPI |
publishDate |
2021 |
url |
http://hdl.handle.net/10138/326914 |
long_lat |
ENVELOPE(88.203,88.203,69.354,69.354) |
geographic |
Kola Peninsula Norilsk |
geographic_facet |
Kola Peninsula Norilsk |
genre |
kola peninsula norilsk Siberia |
genre_facet |
kola peninsula norilsk Siberia |
op_relation |
10.3390/min10060498 The study was conducted under the State Assignment to the V.S. Sobolev Institute of Geology and Mineralogy SB RAS and was supported by the Russian Science Foundation grant 19-17-13013. Sampling and analytics were partly supported by the Russian Foundation for Basic Research grant 16-05-00945a. Chayka , I F , Zhitova , L M , Antsiferova , T N , Abersteiner , A , Shevko , A Y , Izokh , A E , Tolstykh , N D , Gora , M P , Chubarov , V M & Kamenetsky , V S 2020 , ' In-Situ Crystallization and Continuous Modification of Chromian Spinel in the "Sulfide-Poor Platinum-Group Metal Ores" of the Norilsk-1 Intrusion (Northern Siberia, Russia) ' , Minerals , vol. 10 , no. 6 , 498 . https://doi.org/10.3390/min10060498 90770dda-31a4-4778-80f6-8044e60af37a http://hdl.handle.net/10138/326914 000551084800001 |
op_rights |
cc_by openAccess info:eu-repo/semantics/openAccess |
container_title |
Minerals |
container_volume |
10 |
container_issue |
6 |
container_start_page |
498 |
_version_ |
1787426077322248192 |