Lithium isotope fractionation in magmatic systems : constraints from in situ δ7Li determinations on magmatic minerals by femtosecond-laser ablation-MC-ICP-MS
Investigations on the fractionation of stable metal isotopes to characterize mass flux at high temperatures have been proven to be a powerful tool during the past years. In this study, high precision in situ analyses on Li isotope ratios were performed on reference glasses and natural olivines at lo...
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Hannover : Institutionelles Repositorium der Leibniz Universität Hannover
2020
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ftunivhannover:oai:www.repo.uni-hannover.de:123456789/9976 2023-07-16T03:59:19+02:00 Lithium isotope fractionation in magmatic systems : constraints from in situ δ7Li determinations on magmatic minerals by femtosecond-laser ablation-MC-ICP-MS Steinmann, Lena 2020 https://www.repo.uni-hannover.de/handle/123456789/9976 https://doi.org/10.15488/9918 eng eng Hannover : Institutionelles Repositorium der Leibniz Universität Hannover http://dx.doi.org/10.15488/9918 https://www.repo.uni-hannover.de/handle/123456789/9976 Es gilt deutsches Urheberrecht. Das Dokument darf zum eigenen Gebrauch kostenfrei genutzt, aber nicht im Internet bereitgestellt oder an Außenstehende weitergegeben werden. frei zugänglich Lithium isotope fractionation olivine matrix-dependent isotope fractionation in the plasma diffusion modeling multi-stage magma evolution magmatic degassing Massif Central (France) Lithium-Isotopenfraktionierung Olivin fs-LA-MC-ICP-MS matrixabhängige Isotopenfraktionierung im Plasma Diffusionsmodellierung mehrstufige Magmenevolution magmatische Entgasung Massif Central (Frankreich) ddc:550 status-type:publishedVersion doc-type:DoctoralThesis doc-type:Text 2020 ftunivhannover https://doi.org/10.15488/9918 2023-06-28T10:38:30Z Investigations on the fractionation of stable metal isotopes to characterize mass flux at high temperatures have been proven to be a powerful tool during the past years. In this study, high precision in situ analyses on Li isotope ratios were performed on reference glasses and natural olivines at low concentration levels by femtosecond-laser ablation multi collector inductively coupled plasma mass spectrometry (fs-LA-MC-ICP-MS) in order to investigate the fractionation of Li isotopes during magma evolution. The analytical technique was tested by analyzing a series of reference glasses in situ and cross calibrating them with published values acquired by other methods (solution nebulization MC-ICP-MS, SIMS and TIMS). The results of this methodical investigation showed that operating the plasma at relatively cool conditions (900 W) largely suppresses matrix-dependent isotope effects in the plasma. In order to achieve the best precision for concentrations ranging from 2 to 10 µg/g a detector combination of an ion counter for the determination of 6Li and a faraday cup equipped with a 1013 Ω amplifier for 7Li was applied. Precise and accurate measurements of δ7Li with ~2 ‰ (2 σ) analytical uncertainty were performed on reference glass T1-G (δ7LiT1 G = 1.6-2.4 ‰). The fractionation of Li isotopes on the outcrop and mineral scale were investigated in this study. Bulk Li isotope analyses of an outcrop over a length of ~50 m in the French Massif Central showed that on the outcrop scale the isotopic composition varied between +2.1 and +3.3 ±2.0 ‰. The measured δ7Li-values coincide with the range of unaltered volcanic whole-rock suites worldwide (+2.0 to +5.0 ‰) and the value determined for the bulk silicate Earth (+3.5 to +4.0 ‰). A systems analysis was performed in order to determine melt reservoirs for two locations of distinct geotectonic settings (ocean intra-plate (Tenerife, Canary Islands, Spain) and volcanic island arc (Kluchevskoy volcano, Kamchatka peninsula, Russia)). Reservoirs of varying primitive grade in a ... Doctoral or Postdoctoral Thesis Kamchatka Kamchatka Peninsula Institutional Repository of Leibniz Universität Hannover Faraday ENVELOPE(-64.256,-64.256,-65.246,-65.246) Kamchatka Peninsula ENVELOPE(160.000,160.000,56.000,56.000) |
institution |
Open Polar |
collection |
Institutional Repository of Leibniz Universität Hannover |
op_collection_id |
ftunivhannover |
language |
English |
topic |
Lithium isotope fractionation olivine matrix-dependent isotope fractionation in the plasma diffusion modeling multi-stage magma evolution magmatic degassing Massif Central (France) Lithium-Isotopenfraktionierung Olivin fs-LA-MC-ICP-MS matrixabhängige Isotopenfraktionierung im Plasma Diffusionsmodellierung mehrstufige Magmenevolution magmatische Entgasung Massif Central (Frankreich) ddc:550 |
spellingShingle |
Lithium isotope fractionation olivine matrix-dependent isotope fractionation in the plasma diffusion modeling multi-stage magma evolution magmatic degassing Massif Central (France) Lithium-Isotopenfraktionierung Olivin fs-LA-MC-ICP-MS matrixabhängige Isotopenfraktionierung im Plasma Diffusionsmodellierung mehrstufige Magmenevolution magmatische Entgasung Massif Central (Frankreich) ddc:550 Steinmann, Lena Lithium isotope fractionation in magmatic systems : constraints from in situ δ7Li determinations on magmatic minerals by femtosecond-laser ablation-MC-ICP-MS |
topic_facet |
Lithium isotope fractionation olivine matrix-dependent isotope fractionation in the plasma diffusion modeling multi-stage magma evolution magmatic degassing Massif Central (France) Lithium-Isotopenfraktionierung Olivin fs-LA-MC-ICP-MS matrixabhängige Isotopenfraktionierung im Plasma Diffusionsmodellierung mehrstufige Magmenevolution magmatische Entgasung Massif Central (Frankreich) ddc:550 |
description |
Investigations on the fractionation of stable metal isotopes to characterize mass flux at high temperatures have been proven to be a powerful tool during the past years. In this study, high precision in situ analyses on Li isotope ratios were performed on reference glasses and natural olivines at low concentration levels by femtosecond-laser ablation multi collector inductively coupled plasma mass spectrometry (fs-LA-MC-ICP-MS) in order to investigate the fractionation of Li isotopes during magma evolution. The analytical technique was tested by analyzing a series of reference glasses in situ and cross calibrating them with published values acquired by other methods (solution nebulization MC-ICP-MS, SIMS and TIMS). The results of this methodical investigation showed that operating the plasma at relatively cool conditions (900 W) largely suppresses matrix-dependent isotope effects in the plasma. In order to achieve the best precision for concentrations ranging from 2 to 10 µg/g a detector combination of an ion counter for the determination of 6Li and a faraday cup equipped with a 1013 Ω amplifier for 7Li was applied. Precise and accurate measurements of δ7Li with ~2 ‰ (2 σ) analytical uncertainty were performed on reference glass T1-G (δ7LiT1 G = 1.6-2.4 ‰). The fractionation of Li isotopes on the outcrop and mineral scale were investigated in this study. Bulk Li isotope analyses of an outcrop over a length of ~50 m in the French Massif Central showed that on the outcrop scale the isotopic composition varied between +2.1 and +3.3 ±2.0 ‰. The measured δ7Li-values coincide with the range of unaltered volcanic whole-rock suites worldwide (+2.0 to +5.0 ‰) and the value determined for the bulk silicate Earth (+3.5 to +4.0 ‰). A systems analysis was performed in order to determine melt reservoirs for two locations of distinct geotectonic settings (ocean intra-plate (Tenerife, Canary Islands, Spain) and volcanic island arc (Kluchevskoy volcano, Kamchatka peninsula, Russia)). Reservoirs of varying primitive grade in a ... |
format |
Doctoral or Postdoctoral Thesis |
author |
Steinmann, Lena |
author_facet |
Steinmann, Lena |
author_sort |
Steinmann, Lena |
title |
Lithium isotope fractionation in magmatic systems : constraints from in situ δ7Li determinations on magmatic minerals by femtosecond-laser ablation-MC-ICP-MS |
title_short |
Lithium isotope fractionation in magmatic systems : constraints from in situ δ7Li determinations on magmatic minerals by femtosecond-laser ablation-MC-ICP-MS |
title_full |
Lithium isotope fractionation in magmatic systems : constraints from in situ δ7Li determinations on magmatic minerals by femtosecond-laser ablation-MC-ICP-MS |
title_fullStr |
Lithium isotope fractionation in magmatic systems : constraints from in situ δ7Li determinations on magmatic minerals by femtosecond-laser ablation-MC-ICP-MS |
title_full_unstemmed |
Lithium isotope fractionation in magmatic systems : constraints from in situ δ7Li determinations on magmatic minerals by femtosecond-laser ablation-MC-ICP-MS |
title_sort |
lithium isotope fractionation in magmatic systems : constraints from in situ δ7li determinations on magmatic minerals by femtosecond-laser ablation-mc-icp-ms |
publisher |
Hannover : Institutionelles Repositorium der Leibniz Universität Hannover |
publishDate |
2020 |
url |
https://www.repo.uni-hannover.de/handle/123456789/9976 https://doi.org/10.15488/9918 |
long_lat |
ENVELOPE(-64.256,-64.256,-65.246,-65.246) ENVELOPE(160.000,160.000,56.000,56.000) |
geographic |
Faraday Kamchatka Peninsula |
geographic_facet |
Faraday Kamchatka Peninsula |
genre |
Kamchatka Kamchatka Peninsula |
genre_facet |
Kamchatka Kamchatka Peninsula |
op_relation |
http://dx.doi.org/10.15488/9918 https://www.repo.uni-hannover.de/handle/123456789/9976 |
op_rights |
Es gilt deutsches Urheberrecht. Das Dokument darf zum eigenen Gebrauch kostenfrei genutzt, aber nicht im Internet bereitgestellt oder an Außenstehende weitergegeben werden. frei zugänglich |
op_doi |
https://doi.org/10.15488/9918 |
_version_ |
1771546953800220672 |