Strontium isotopic analysis of environmental microsamples by inductively coupled plasma – tandem mass spectrometry
In this work, a new method has been developed for accurate and precise Sr isotopic analysis of microsamples via inductively coupled plasma - tandem mass spectrometry (ICP-MS/MS). For introduction of low-volume samples, a setup consisting of a syringe-driven pump that allows to work at low and stable...
Published in: | Journal of Analytical Atomic Spectrometry |
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2022
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ftunivgent:oai:archive.ugent.be:8757202 2023-09-26T15:10:15+02:00 Strontium isotopic analysis of environmental microsamples by inductively coupled plasma – tandem mass spectrometry Bertinetti, Stefano Bolea Fernandez, Eduardo Malandrino, Mery Moroni, Beatrice Cappelletti, David Grotti, Marco Vanhaecke, Frank 2022 application/pdf https://biblio.ugent.be/publication/8757202 http://hdl.handle.net/1854/LU-8757202 https://doi.org/10.1039/d1ja00329a https://biblio.ugent.be/publication/8757202/file/8757206 eng eng https://biblio.ugent.be/publication/8757202 http://hdl.handle.net/1854/LU-8757202 http://dx.doi.org/10.1039/d1ja00329a https://biblio.ugent.be/publication/8757202/file/8757206 No license (in copyright) info:eu-repo/semantics/restrictedAccess JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY ISSN: 0267-9477 ISSN: 1364-5544 Chemistry Spectroscopy Analytical Chemistry ICP-MS EAST ANTARCTICA ISOBARIC INTERFERENCES REACTION CHEMISTRY DUST CIRCULATION PROVENANCE PRECISION ELEMENTS RATIOS journalArticle info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion 2022 ftunivgent https://doi.org/10.1039/d1ja00329a 2023-08-30T22:07:02Z In this work, a new method has been developed for accurate and precise Sr isotopic analysis of microsamples via inductively coupled plasma - tandem mass spectrometry (ICP-MS/MS). For introduction of low-volume samples, a setup consisting of a syringe-driven pump that allows to work at low and stable sample introduction flow rates was combined with a high-efficiency sample introduction system, originally designed for the introduction of single cells and other discrete entities into the ICP. The method requires 240 mu L of sample only, introduced at a sample uptake rate of 20 mu L min(-1) and allows for the straightforward measurement of the Sr-87/Sr-86 isotope ratio without prior Rb/Sr separation. The isobaric overlap of the signals of Rb-87 and Sr-87 is overcome by the selective reaction between Sr+ and CH3F gas in the collision/reaction cell (CRC) of an ICP-MS/MS instrument. In this way, Sr+ ions are measured as their corresponding SrF+ reaction product ions in a mass-shift approach. A multivariate approach was applied to obtain optimum instrument settings (sample uptake rate, nebulizer gas flow rate, make-up gas flow rate, and plasma sampling depth) for maximum sensitivity and optimum precision of the Sr-87/Sr-86 and Sr-88/Sr-86 isotope ratios. The method thus developed was found to be accurate (mean bias = -0.001 +/- 0.070%, with respect to a quality control reference value) and showed an external precision of 0.17% (RSD, n = 24) at an analytical concentration of 2 ng g(-1). The method was applied to the analysis of small-volume digests of samples of Antarctic atmospheric particulates (PM10) and of soils from Australia and South America as potential source areas for atmospheric particulates reaching East Antarctica. The raw soil samples were handled using a dedicated resuspension/collection system to select the finest fraction (PM2.5), thus simulating the long-range transport of mineral dust in the atmosphere. The results obtained for these samples were found to be in good agreement with literature data, ... Article in Journal/Newspaper Antarc* Antarctic Antarctica East Antarctica Ghent University Academic Bibliography Antarctic East Antarctica Journal of Analytical Atomic Spectrometry 37 1 103 113 |
institution |
Open Polar |
collection |
Ghent University Academic Bibliography |
op_collection_id |
ftunivgent |
language |
English |
topic |
Chemistry Spectroscopy Analytical Chemistry ICP-MS EAST ANTARCTICA ISOBARIC INTERFERENCES REACTION CHEMISTRY DUST CIRCULATION PROVENANCE PRECISION ELEMENTS RATIOS |
spellingShingle |
Chemistry Spectroscopy Analytical Chemistry ICP-MS EAST ANTARCTICA ISOBARIC INTERFERENCES REACTION CHEMISTRY DUST CIRCULATION PROVENANCE PRECISION ELEMENTS RATIOS Bertinetti, Stefano Bolea Fernandez, Eduardo Malandrino, Mery Moroni, Beatrice Cappelletti, David Grotti, Marco Vanhaecke, Frank Strontium isotopic analysis of environmental microsamples by inductively coupled plasma – tandem mass spectrometry |
topic_facet |
Chemistry Spectroscopy Analytical Chemistry ICP-MS EAST ANTARCTICA ISOBARIC INTERFERENCES REACTION CHEMISTRY DUST CIRCULATION PROVENANCE PRECISION ELEMENTS RATIOS |
description |
In this work, a new method has been developed for accurate and precise Sr isotopic analysis of microsamples via inductively coupled plasma - tandem mass spectrometry (ICP-MS/MS). For introduction of low-volume samples, a setup consisting of a syringe-driven pump that allows to work at low and stable sample introduction flow rates was combined with a high-efficiency sample introduction system, originally designed for the introduction of single cells and other discrete entities into the ICP. The method requires 240 mu L of sample only, introduced at a sample uptake rate of 20 mu L min(-1) and allows for the straightforward measurement of the Sr-87/Sr-86 isotope ratio without prior Rb/Sr separation. The isobaric overlap of the signals of Rb-87 and Sr-87 is overcome by the selective reaction between Sr+ and CH3F gas in the collision/reaction cell (CRC) of an ICP-MS/MS instrument. In this way, Sr+ ions are measured as their corresponding SrF+ reaction product ions in a mass-shift approach. A multivariate approach was applied to obtain optimum instrument settings (sample uptake rate, nebulizer gas flow rate, make-up gas flow rate, and plasma sampling depth) for maximum sensitivity and optimum precision of the Sr-87/Sr-86 and Sr-88/Sr-86 isotope ratios. The method thus developed was found to be accurate (mean bias = -0.001 +/- 0.070%, with respect to a quality control reference value) and showed an external precision of 0.17% (RSD, n = 24) at an analytical concentration of 2 ng g(-1). The method was applied to the analysis of small-volume digests of samples of Antarctic atmospheric particulates (PM10) and of soils from Australia and South America as potential source areas for atmospheric particulates reaching East Antarctica. The raw soil samples were handled using a dedicated resuspension/collection system to select the finest fraction (PM2.5), thus simulating the long-range transport of mineral dust in the atmosphere. The results obtained for these samples were found to be in good agreement with literature data, ... |
format |
Article in Journal/Newspaper |
author |
Bertinetti, Stefano Bolea Fernandez, Eduardo Malandrino, Mery Moroni, Beatrice Cappelletti, David Grotti, Marco Vanhaecke, Frank |
author_facet |
Bertinetti, Stefano Bolea Fernandez, Eduardo Malandrino, Mery Moroni, Beatrice Cappelletti, David Grotti, Marco Vanhaecke, Frank |
author_sort |
Bertinetti, Stefano |
title |
Strontium isotopic analysis of environmental microsamples by inductively coupled plasma – tandem mass spectrometry |
title_short |
Strontium isotopic analysis of environmental microsamples by inductively coupled plasma – tandem mass spectrometry |
title_full |
Strontium isotopic analysis of environmental microsamples by inductively coupled plasma – tandem mass spectrometry |
title_fullStr |
Strontium isotopic analysis of environmental microsamples by inductively coupled plasma – tandem mass spectrometry |
title_full_unstemmed |
Strontium isotopic analysis of environmental microsamples by inductively coupled plasma – tandem mass spectrometry |
title_sort |
strontium isotopic analysis of environmental microsamples by inductively coupled plasma – tandem mass spectrometry |
publishDate |
2022 |
url |
https://biblio.ugent.be/publication/8757202 http://hdl.handle.net/1854/LU-8757202 https://doi.org/10.1039/d1ja00329a https://biblio.ugent.be/publication/8757202/file/8757206 |
geographic |
Antarctic East Antarctica |
geographic_facet |
Antarctic East Antarctica |
genre |
Antarc* Antarctic Antarctica East Antarctica |
genre_facet |
Antarc* Antarctic Antarctica East Antarctica |
op_source |
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY ISSN: 0267-9477 ISSN: 1364-5544 |
op_relation |
https://biblio.ugent.be/publication/8757202 http://hdl.handle.net/1854/LU-8757202 http://dx.doi.org/10.1039/d1ja00329a https://biblio.ugent.be/publication/8757202/file/8757206 |
op_rights |
No license (in copyright) info:eu-repo/semantics/restrictedAccess |
op_doi |
https://doi.org/10.1039/d1ja00329a |
container_title |
Journal of Analytical Atomic Spectrometry |
container_volume |
37 |
container_issue |
1 |
container_start_page |
103 |
op_container_end_page |
113 |
_version_ |
1778142161901977600 |