Lead isotopic analysis of Antarctic snow using multi-collector ICP-mass spectrometry
Reliable determination of Pb isotope ratios in Antarctic snow is challenging because of the low analyte concentration and the low volume of sample typically available. In this work, a combination of a total sample consumption introduction system (the torch-integrated sample introduction system, TISI...
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ftunivgent:oai:archive.ugent.be:6985571 2023-06-11T04:05:07+02:00 Lead isotopic analysis of Antarctic snow using multi-collector ICP-mass spectrometry Bazzano, Andrea Latruwe, Kris Grotti, Marco Vanhaecke, Frank 2015 application/pdf https://biblio.ugent.be/publication/6985571 http://hdl.handle.net/1854/LU-6985571 https://doi.org/10.1039/c4ja00484a https://biblio.ugent.be/publication/6985571/file/6985592 eng eng https://biblio.ugent.be/publication/6985571 http://hdl.handle.net/1854/LU-6985571 http://dx.doi.org/10.1039/c4ja00484a https://biblio.ugent.be/publication/6985571/file/6985592 No license (in copyright) info:eu-repo/semantics/restrictedAccess JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY ISSN: 0267-9477 Chemistry EXPONENTIAL MODEL SHEATHING GAS GRAM CONCENTRATIONS ENVIRONMENTAL-SAMPLES DOUBLE SPIKE PB ISOTOPES COATS LAND MU-L MIN(-1) SAMPLE-INTRODUCTION SYSTEM RATIO MEASUREMENTS journalArticle info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion 2015 ftunivgent https://doi.org/10.1039/c4ja00484a 2023-05-10T22:24:34Z Reliable determination of Pb isotope ratios in Antarctic snow is challenging because of the low analyte concentration and the low volume of sample typically available. In this work, a combination of a total sample consumption introduction system (the torch-integrated sample introduction system, TISIS) with multi-collector ICP-mass spectrometry (MC-ICP-MS) was used for this purpose. With this instrumental setup, accurate and precise determination of Pb isotope ratios was possible at concentrations as low as 0.5 ng mL(-1), while using 0.2 mL of solution only (total amount of Pb: 100 pg). At 10 ng mL(-1), the repeatability for the Pb-207/Pb-206 ratio was 0.16 parts per thousand RSD. The concentration range was further extended downwards by using 100-fold analyte element preconcentration via freeze-drying of 20 g of snow. The Pb concentration in procedural blanks was 0.5 +/- 0.3 pg g(-1), enabling the determination of Pb isotope ratios in snow samples containing down to 5 pg g(-1) of Pb. After development and validation, the procedure was applied to snow samples collected at Dome C (East Antarctic Plateau) on a monthly basis during the 2006 and 2010 campaigns. The method developed was able to reveal a seasonal variation in the Pb isotope ratios occurring during 2006 and strong inter-annual variation between the two campaigns. Article in Journal/Newspaper Antarc* Antarctic Ghent University Academic Bibliography Antarctic Coats Land ENVELOPE(-27.500,-27.500,-77.000,-77.000) Journal of Analytical Atomic Spectrometry 30 6 1322 1328 |
institution |
Open Polar |
collection |
Ghent University Academic Bibliography |
op_collection_id |
ftunivgent |
language |
English |
topic |
Chemistry EXPONENTIAL MODEL SHEATHING GAS GRAM CONCENTRATIONS ENVIRONMENTAL-SAMPLES DOUBLE SPIKE PB ISOTOPES COATS LAND MU-L MIN(-1) SAMPLE-INTRODUCTION SYSTEM RATIO MEASUREMENTS |
spellingShingle |
Chemistry EXPONENTIAL MODEL SHEATHING GAS GRAM CONCENTRATIONS ENVIRONMENTAL-SAMPLES DOUBLE SPIKE PB ISOTOPES COATS LAND MU-L MIN(-1) SAMPLE-INTRODUCTION SYSTEM RATIO MEASUREMENTS Bazzano, Andrea Latruwe, Kris Grotti, Marco Vanhaecke, Frank Lead isotopic analysis of Antarctic snow using multi-collector ICP-mass spectrometry |
topic_facet |
Chemistry EXPONENTIAL MODEL SHEATHING GAS GRAM CONCENTRATIONS ENVIRONMENTAL-SAMPLES DOUBLE SPIKE PB ISOTOPES COATS LAND MU-L MIN(-1) SAMPLE-INTRODUCTION SYSTEM RATIO MEASUREMENTS |
description |
Reliable determination of Pb isotope ratios in Antarctic snow is challenging because of the low analyte concentration and the low volume of sample typically available. In this work, a combination of a total sample consumption introduction system (the torch-integrated sample introduction system, TISIS) with multi-collector ICP-mass spectrometry (MC-ICP-MS) was used for this purpose. With this instrumental setup, accurate and precise determination of Pb isotope ratios was possible at concentrations as low as 0.5 ng mL(-1), while using 0.2 mL of solution only (total amount of Pb: 100 pg). At 10 ng mL(-1), the repeatability for the Pb-207/Pb-206 ratio was 0.16 parts per thousand RSD. The concentration range was further extended downwards by using 100-fold analyte element preconcentration via freeze-drying of 20 g of snow. The Pb concentration in procedural blanks was 0.5 +/- 0.3 pg g(-1), enabling the determination of Pb isotope ratios in snow samples containing down to 5 pg g(-1) of Pb. After development and validation, the procedure was applied to snow samples collected at Dome C (East Antarctic Plateau) on a monthly basis during the 2006 and 2010 campaigns. The method developed was able to reveal a seasonal variation in the Pb isotope ratios occurring during 2006 and strong inter-annual variation between the two campaigns. |
format |
Article in Journal/Newspaper |
author |
Bazzano, Andrea Latruwe, Kris Grotti, Marco Vanhaecke, Frank |
author_facet |
Bazzano, Andrea Latruwe, Kris Grotti, Marco Vanhaecke, Frank |
author_sort |
Bazzano, Andrea |
title |
Lead isotopic analysis of Antarctic snow using multi-collector ICP-mass spectrometry |
title_short |
Lead isotopic analysis of Antarctic snow using multi-collector ICP-mass spectrometry |
title_full |
Lead isotopic analysis of Antarctic snow using multi-collector ICP-mass spectrometry |
title_fullStr |
Lead isotopic analysis of Antarctic snow using multi-collector ICP-mass spectrometry |
title_full_unstemmed |
Lead isotopic analysis of Antarctic snow using multi-collector ICP-mass spectrometry |
title_sort |
lead isotopic analysis of antarctic snow using multi-collector icp-mass spectrometry |
publishDate |
2015 |
url |
https://biblio.ugent.be/publication/6985571 http://hdl.handle.net/1854/LU-6985571 https://doi.org/10.1039/c4ja00484a https://biblio.ugent.be/publication/6985571/file/6985592 |
long_lat |
ENVELOPE(-27.500,-27.500,-77.000,-77.000) |
geographic |
Antarctic Coats Land |
geographic_facet |
Antarctic Coats Land |
genre |
Antarc* Antarctic |
genre_facet |
Antarc* Antarctic |
op_source |
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY ISSN: 0267-9477 |
op_relation |
https://biblio.ugent.be/publication/6985571 http://hdl.handle.net/1854/LU-6985571 http://dx.doi.org/10.1039/c4ja00484a https://biblio.ugent.be/publication/6985571/file/6985592 |
op_rights |
No license (in copyright) info:eu-repo/semantics/restrictedAccess |
op_doi |
https://doi.org/10.1039/c4ja00484a |
container_title |
Journal of Analytical Atomic Spectrometry |
container_volume |
30 |
container_issue |
6 |
container_start_page |
1322 |
op_container_end_page |
1328 |
_version_ |
1768371916689637376 |