Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters
The application of an inductively coupled plasma mass spectrometry detection system to the speciation of organolead compounds in environmental waters is described. Derivatization was carried out by propylation with a Grignard reagent after extraction of the organolead compounds into hexane as their...
Published in: | Journal of Analytical Atomic Spectrometry |
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1997
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Online Access: | https://biblio.ugent.be/publication/185035 http://hdl.handle.net/1854/LU-185035 https://doi.org/10.1039/a701386h https://biblio.ugent.be/publication/185035/file/3056359 |
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ftunivgent:oai:archive.ugent.be:185035 2023-10-01T03:56:21+02:00 Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters Heisterkamp, Monika De Smaele, Tom Candelone, Jean-Pierre Moens, Luc Dams, Richard Adams, Freddy C 1997 application/pdf https://biblio.ugent.be/publication/185035 http://hdl.handle.net/1854/LU-185035 https://doi.org/10.1039/a701386h https://biblio.ugent.be/publication/185035/file/3056359 eng eng https://biblio.ugent.be/publication/185035 http://hdl.handle.net/1854/LU-185035 http://dx.doi.org/10.1039/a701386h https://biblio.ugent.be/publication/185035/file/3056359 No license (in copyright) info:eu-repo/semantics/restrictedAccess JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY ISSN: 0267-9477 Chemistry AAS GREENLAND SNOW SAMPLES INTERFACE PRECONCENTRATION LEAD SPECIATION ABSORPTION SPECTROMETRY IONIC ALKYLLEAD COMPOUNDS PERFORMANCE LIQUID-CHROMATOGRAPHY ATOMIC-EMISSION-SPECTROMETRY environmental water gas chromatography inductively coupled plasma mass spectrometry propylation speciation organolead compound journalArticle info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion 1997 ftunivgent https://doi.org/10.1039/a701386h 2023-09-06T22:28:18Z The application of an inductively coupled plasma mass spectrometry detection system to the speciation of organolead compounds in environmental waters is described. Derivatization was carried out by propylation with a Grignard reagent after extraction of the organolead compounds into hexane as their diethyldithiocarbamate complexes. This was followed by separation and detection with capillary gas chromatography and inductively coupled plasma mass spectrometry. Detection limits ranging from 10 fg (0.05 ng l(-1)) (as Pb) for trimethyllead to 16 fg (0.08 ng l(-1)) (as Ph) for diethyllead were achieved. The accuracy of the method was confirmed by additional analysis of the water samples with capillary gas chromatography coupled to microwave-induced plasma atomic emission spectrometry and by the analysis of a reference material from the Standards, Measurements & Testing Programme of the European Union. Article in Journal/Newspaper Greenland Ghent University Academic Bibliography Greenland Journal of Analytical Atomic Spectrometry 12 9 1077 1081 |
institution |
Open Polar |
collection |
Ghent University Academic Bibliography |
op_collection_id |
ftunivgent |
language |
English |
topic |
Chemistry AAS GREENLAND SNOW SAMPLES INTERFACE PRECONCENTRATION LEAD SPECIATION ABSORPTION SPECTROMETRY IONIC ALKYLLEAD COMPOUNDS PERFORMANCE LIQUID-CHROMATOGRAPHY ATOMIC-EMISSION-SPECTROMETRY environmental water gas chromatography inductively coupled plasma mass spectrometry propylation speciation organolead compound |
spellingShingle |
Chemistry AAS GREENLAND SNOW SAMPLES INTERFACE PRECONCENTRATION LEAD SPECIATION ABSORPTION SPECTROMETRY IONIC ALKYLLEAD COMPOUNDS PERFORMANCE LIQUID-CHROMATOGRAPHY ATOMIC-EMISSION-SPECTROMETRY environmental water gas chromatography inductively coupled plasma mass spectrometry propylation speciation organolead compound Heisterkamp, Monika De Smaele, Tom Candelone, Jean-Pierre Moens, Luc Dams, Richard Adams, Freddy C Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters |
topic_facet |
Chemistry AAS GREENLAND SNOW SAMPLES INTERFACE PRECONCENTRATION LEAD SPECIATION ABSORPTION SPECTROMETRY IONIC ALKYLLEAD COMPOUNDS PERFORMANCE LIQUID-CHROMATOGRAPHY ATOMIC-EMISSION-SPECTROMETRY environmental water gas chromatography inductively coupled plasma mass spectrometry propylation speciation organolead compound |
description |
The application of an inductively coupled plasma mass spectrometry detection system to the speciation of organolead compounds in environmental waters is described. Derivatization was carried out by propylation with a Grignard reagent after extraction of the organolead compounds into hexane as their diethyldithiocarbamate complexes. This was followed by separation and detection with capillary gas chromatography and inductively coupled plasma mass spectrometry. Detection limits ranging from 10 fg (0.05 ng l(-1)) (as Pb) for trimethyllead to 16 fg (0.08 ng l(-1)) (as Ph) for diethyllead were achieved. The accuracy of the method was confirmed by additional analysis of the water samples with capillary gas chromatography coupled to microwave-induced plasma atomic emission spectrometry and by the analysis of a reference material from the Standards, Measurements & Testing Programme of the European Union. |
format |
Article in Journal/Newspaper |
author |
Heisterkamp, Monika De Smaele, Tom Candelone, Jean-Pierre Moens, Luc Dams, Richard Adams, Freddy C |
author_facet |
Heisterkamp, Monika De Smaele, Tom Candelone, Jean-Pierre Moens, Luc Dams, Richard Adams, Freddy C |
author_sort |
Heisterkamp, Monika |
title |
Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters |
title_short |
Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters |
title_full |
Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters |
title_fullStr |
Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters |
title_full_unstemmed |
Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters |
title_sort |
inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters |
publishDate |
1997 |
url |
https://biblio.ugent.be/publication/185035 http://hdl.handle.net/1854/LU-185035 https://doi.org/10.1039/a701386h https://biblio.ugent.be/publication/185035/file/3056359 |
geographic |
Greenland |
geographic_facet |
Greenland |
genre |
Greenland |
genre_facet |
Greenland |
op_source |
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY ISSN: 0267-9477 |
op_relation |
https://biblio.ugent.be/publication/185035 http://hdl.handle.net/1854/LU-185035 http://dx.doi.org/10.1039/a701386h https://biblio.ugent.be/publication/185035/file/3056359 |
op_rights |
No license (in copyright) info:eu-repo/semantics/restrictedAccess |
op_doi |
https://doi.org/10.1039/a701386h |
container_title |
Journal of Analytical Atomic Spectrometry |
container_volume |
12 |
container_issue |
9 |
container_start_page |
1077 |
op_container_end_page |
1081 |
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1778525818757054464 |