Trace-element abundances in the shallow lithospheric mantle of the North Atlantic Craton margin: Implications for melting and metasomatism beneath Northern Scotland

This is the final version of the article. Available from Mineralogical Society via the DOI in this record. Bulk rock geochemistry and major- and trace-element compositions of clinopyroxene have been determined for three suites of peridotitic mantle xenoliths from the North Atlantic Craton (NAC) in n...

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Published in:Mineralogical Magazine
Main Authors: Hughes, HSR, McDonald, I, Faithfull, JW, Upton, BGJ, Downes, H
Format: Article in Journal/Newspaper
Language:English
Published: Mineralogical Society 2015
Subjects:
Online Access:http://hdl.handle.net/10871/31735
https://doi.org/10.1180/minmag.2015.079.4.03
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author Hughes, HSR
McDonald, I
Faithfull, JW
Upton, BGJ
Downes, H
author_facet Hughes, HSR
McDonald, I
Faithfull, JW
Upton, BGJ
Downes, H
author_sort Hughes, HSR
collection University of Exeter: Open Research Exeter (ORE)
container_issue 4
container_start_page 877
container_title Mineralogical Magazine
container_volume 79
description This is the final version of the article. Available from Mineralogical Society via the DOI in this record. Bulk rock geochemistry and major- and trace-element compositions of clinopyroxene have been determined for three suites of peridotitic mantle xenoliths from the North Atlantic Craton (NAC) in northern Scotland, to establish the magmatic and metasomatic history of subcontinental lithospheric mantle (SCLM) below this region. Spinel lherzolites from the southernmost locality (Streap Com'laidh) have non-NAC mantle compositions, while the two northern xenolith suites (Loch Roag and Rinibar) are derived from the thinned NAC marginal keel. Clinopyroxene compositions have characteristic trace-element signatures which show both 'primary' and 'metasomatic' origins. We use Zr and Hf abundances to identify ancient cryptic refertilization in 'primary' clinopyroxenes. We suggest that Loch Roag and Rinibar peridotite xenoliths represent an ancient Archaean-Palaeoproterozoic SCLM with original depleted cratonic signatures which were overprinted by metasomatism around the time of intrusion of the Scourie Dyke Swarm (∼2.4 Ga). This SCLM keel was preserved during Caledonian orogenesis, although some addition of material and/or metasomatism probably also occurred, as recorded by Rinibar xenoliths. Rinibar and Streap xenoliths were entrained in Permo-Carboniferous magmas and thus were isolated from the SCLM ∼200 Ma before Loch Roag xenoliths (in an Eocene dyke). Crucially, despite their geographical location, lithospheric mantle peridotite samples from Loch Roag show no evidence of recent melting or refertilization during the Palaeogene opening of the Atlantic. H.S.R. Hughes was funded by the Natural Environment Research Council (NERC) studentship NE/J50029X/1
format Article in Journal/Newspaper
genre North Atlantic
genre_facet North Atlantic
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op_doi https://doi.org/10.1180/minmag.2015.079.4.03
op_relation doi:10.1180/minmag.2015.079.4.03
http://hdl.handle.net/10871/31735
Mineralogical Magazine
op_rights Copyright © The Mineralogical Society of Great Britain and Ireland 2015. This is an Open Access article, distributed under the terms of the Creative Commons Attribution license. (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.
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spelling ftunivexeter:oai:ore.exeter.ac.uk:10871/31735 2025-04-06T15:00:03+00:00 Trace-element abundances in the shallow lithospheric mantle of the North Atlantic Craton margin: Implications for melting and metasomatism beneath Northern Scotland Hughes, HSR McDonald, I Faithfull, JW Upton, BGJ Downes, H 2015 http://hdl.handle.net/10871/31735 https://doi.org/10.1180/minmag.2015.079.4.03 en eng Mineralogical Society doi:10.1180/minmag.2015.079.4.03 http://hdl.handle.net/10871/31735 Mineralogical Magazine Copyright © The Mineralogical Society of Great Britain and Ireland 2015. This is an Open Access article, distributed under the terms of the Creative Commons Attribution license. (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited. North Atlantic Craton spinel lherzolite xenolith REE clinopyroxene Article 2015 ftunivexeter https://doi.org/10.1180/minmag.2015.079.4.03 2025-03-11T01:39:58Z This is the final version of the article. Available from Mineralogical Society via the DOI in this record. Bulk rock geochemistry and major- and trace-element compositions of clinopyroxene have been determined for three suites of peridotitic mantle xenoliths from the North Atlantic Craton (NAC) in northern Scotland, to establish the magmatic and metasomatic history of subcontinental lithospheric mantle (SCLM) below this region. Spinel lherzolites from the southernmost locality (Streap Com'laidh) have non-NAC mantle compositions, while the two northern xenolith suites (Loch Roag and Rinibar) are derived from the thinned NAC marginal keel. Clinopyroxene compositions have characteristic trace-element signatures which show both 'primary' and 'metasomatic' origins. We use Zr and Hf abundances to identify ancient cryptic refertilization in 'primary' clinopyroxenes. We suggest that Loch Roag and Rinibar peridotite xenoliths represent an ancient Archaean-Palaeoproterozoic SCLM with original depleted cratonic signatures which were overprinted by metasomatism around the time of intrusion of the Scourie Dyke Swarm (∼2.4 Ga). This SCLM keel was preserved during Caledonian orogenesis, although some addition of material and/or metasomatism probably also occurred, as recorded by Rinibar xenoliths. Rinibar and Streap xenoliths were entrained in Permo-Carboniferous magmas and thus were isolated from the SCLM ∼200 Ma before Loch Roag xenoliths (in an Eocene dyke). Crucially, despite their geographical location, lithospheric mantle peridotite samples from Loch Roag show no evidence of recent melting or refertilization during the Palaeogene opening of the Atlantic. H.S.R. Hughes was funded by the Natural Environment Research Council (NERC) studentship NE/J50029X/1 Article in Journal/Newspaper North Atlantic University of Exeter: Open Research Exeter (ORE) Mineralogical Magazine 79 4 877 907
spellingShingle North Atlantic Craton
spinel lherzolite
xenolith
REE
clinopyroxene
Hughes, HSR
McDonald, I
Faithfull, JW
Upton, BGJ
Downes, H
Trace-element abundances in the shallow lithospheric mantle of the North Atlantic Craton margin: Implications for melting and metasomatism beneath Northern Scotland
title Trace-element abundances in the shallow lithospheric mantle of the North Atlantic Craton margin: Implications for melting and metasomatism beneath Northern Scotland
title_full Trace-element abundances in the shallow lithospheric mantle of the North Atlantic Craton margin: Implications for melting and metasomatism beneath Northern Scotland
title_fullStr Trace-element abundances in the shallow lithospheric mantle of the North Atlantic Craton margin: Implications for melting and metasomatism beneath Northern Scotland
title_full_unstemmed Trace-element abundances in the shallow lithospheric mantle of the North Atlantic Craton margin: Implications for melting and metasomatism beneath Northern Scotland
title_short Trace-element abundances in the shallow lithospheric mantle of the North Atlantic Craton margin: Implications for melting and metasomatism beneath Northern Scotland
title_sort trace-element abundances in the shallow lithospheric mantle of the north atlantic craton margin: implications for melting and metasomatism beneath northern scotland
topic North Atlantic Craton
spinel lherzolite
xenolith
REE
clinopyroxene
topic_facet North Atlantic Craton
spinel lherzolite
xenolith
REE
clinopyroxene
url http://hdl.handle.net/10871/31735
https://doi.org/10.1180/minmag.2015.079.4.03