Deep ice as a geochemical reactor: Insights from iron speciation and mineralogy of dust in the Talos Dome ice core (East Antarctica)
International audience Thanks to its insolubility, mineral dust is considered a stable proxy in polar ice cores. With this study we show that the Talos Dome ice core (TALDICE, Ross Sea sector of East Antarctica) displays evident and progressive signs of post-depositional processes affecting the mine...
Published in: | The Cryosphere |
---|---|
Main Authors: | , , , , , , , , , |
Other Authors: | , , , , , , , , , , , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
HAL CCSD
2021
|
Subjects: | |
Online Access: | https://hal.science/hal-03434954 https://hal.science/hal-03434954/document https://hal.science/hal-03434954/file/bacc1.pdf https://doi.org/10.5194/tc-15-4807-2021 |
id |
ftuniversailles:oai:HAL:hal-03434954v1 |
---|---|
record_format |
openpolar |
institution |
Open Polar |
collection |
Université de Versailles Saint-Quentin-en-Yvelines: HAL-UVSQ |
op_collection_id |
ftuniversailles |
language |
English |
topic |
[SDU]Sciences of the Universe [physics] |
spellingShingle |
[SDU]Sciences of the Universe [physics] Baccolo, Giovanni Delmonte, Barbara Di Stefano, Elena Cibin, Giannantonio Crotti, Ilaria Frezzotti, Massimo Hampai, Dariush Iizuka, Yoshinori Marcelli, Augusto Maggi, Valter Deep ice as a geochemical reactor: Insights from iron speciation and mineralogy of dust in the Talos Dome ice core (East Antarctica) |
topic_facet |
[SDU]Sciences of the Universe [physics] |
description |
International audience Thanks to its insolubility, mineral dust is considered a stable proxy in polar ice cores. With this study we show that the Talos Dome ice core (TALDICE, Ross Sea sector of East Antarctica) displays evident and progressive signs of post-depositional processes affecting the mineral dust record below 1000g m deep. We apply a suite of established and cutting-edge techniques to investigate the properties of dust in TALDICE, ranging from concentration and grain size to elemental composition and Fe mineralogy. Results show that through acidic/oxidative weathering, the conditions of deep ice at Talos Dome promote the dissolution of specific minerals and the englacial formation of others, affecting primitive dust features. The expulsion of acidic atmospheric species from ice grains and their concentration in localized environments is likely the main process responsible for englacial reactions. Deep ice can be seen as a "geochemical reactor"capable of fostering complex reactions which involve both soluble and insoluble impurities. Fe-bearing minerals can efficiently help in exploring such transformations. |
author2 |
Department of Earth and Environmental Sciences Milano Università degli Studi di Milano-Bicocca = University of Milano-Bicocca (UNIMIB) DIAMOND Light source Laboratoire des Sciences du Climat et de l'Environnement Gif-sur-Yvette (LSCE) Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)) Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA) Department of Earth Sciences Roma Università degli Studi di Roma "La Sapienza" = Sapienza University Rome (UNIROMA) Laboratori Nazionali di Frascati = National Laboratory of Frascati (LNF) Istituto Nazionale di Fisica Nucleare (INFN) Institute of Low Temperature Science Sapporo Hokkaido University Sapporo, Japan RICMASS Rome Int Ctr Mat Sci Superstripes, I-00185 Rome, Italy This research has been supported by the Ministero dell'Istruzione, dell'Università e della Ricerca (grant no. PNRA18-00098); Horizon 2020 (grant no. Beyond EPICA (815384)); and Diamond Light Source (grant nos. sp7314, sp8372 and sp9050). Primary logistical support was provided by PNRA at Talos Dome. This is TALDICE publication no. 62. This publication was generated in the frame of Beyond EPICA. The project has received funding from the European Union’s Horizon 2020 Research And Innovation Programme under grant agreement no. 815384 (Oldest Ice Core). It is supported by national partners and funding agencies in Belgium, Denmark, France, Germany, Italy, Norway, Sweden, Switzerland, the Netherlands and the United Kingdom. Logistic support is mainly provided by PNRA and IPEV through the Concordia Station system. The opinions expressed and arguments employed herein do not necessarily reflect the official views of the European Union funding agency or other national funding bodies. This is Beyond EPICA publication number 22. We thank Paolo Gentile for providing mineral standards and also Paul Niles and Tanya Peretyazhko for the fruitful discussions. European Project: 331615,EC:FP7:PEOPLE,FP7-PEOPLE-2012-IIF,TALDICE HOLOCENE(2013) European Project: 815384,Beyond EPICA |
format |
Article in Journal/Newspaper |
author |
Baccolo, Giovanni Delmonte, Barbara Di Stefano, Elena Cibin, Giannantonio Crotti, Ilaria Frezzotti, Massimo Hampai, Dariush Iizuka, Yoshinori Marcelli, Augusto Maggi, Valter |
author_facet |
Baccolo, Giovanni Delmonte, Barbara Di Stefano, Elena Cibin, Giannantonio Crotti, Ilaria Frezzotti, Massimo Hampai, Dariush Iizuka, Yoshinori Marcelli, Augusto Maggi, Valter |
author_sort |
Baccolo, Giovanni |
title |
Deep ice as a geochemical reactor: Insights from iron speciation and mineralogy of dust in the Talos Dome ice core (East Antarctica) |
title_short |
Deep ice as a geochemical reactor: Insights from iron speciation and mineralogy of dust in the Talos Dome ice core (East Antarctica) |
title_full |
Deep ice as a geochemical reactor: Insights from iron speciation and mineralogy of dust in the Talos Dome ice core (East Antarctica) |
title_fullStr |
Deep ice as a geochemical reactor: Insights from iron speciation and mineralogy of dust in the Talos Dome ice core (East Antarctica) |
title_full_unstemmed |
Deep ice as a geochemical reactor: Insights from iron speciation and mineralogy of dust in the Talos Dome ice core (East Antarctica) |
title_sort |
deep ice as a geochemical reactor: insights from iron speciation and mineralogy of dust in the talos dome ice core (east antarctica) |
publisher |
HAL CCSD |
publishDate |
2021 |
url |
https://hal.science/hal-03434954 https://hal.science/hal-03434954/document https://hal.science/hal-03434954/file/bacc1.pdf https://doi.org/10.5194/tc-15-4807-2021 |
genre |
Antarc* Antarctica East Antarctica ice core Ross Sea The Cryosphere |
genre_facet |
Antarc* Antarctica East Antarctica ice core Ross Sea The Cryosphere |
op_source |
ISSN: 1994-0424 EISSN: 1994-0416 The Cryosphere https://hal.science/hal-03434954 The Cryosphere, 2021, 15 (10), pp.4807-4822. ⟨10.5194/tc-15-4807-2021⟩ https://tc.copernicus.org/articles/15/4807/2021/ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.5194/tc-15-4807-2021 info:eu-repo/grantAgreement/EC/FP7/331615/EU/Holocene climate variability at Talos Dome, Antarctica/TALDICE HOLOCENE info:eu-repo/grantAgreement//815384/EU/Beyond EPICA Oldest Ice Core: 1,5 Myr of greenhouse gas – climate feedbacks - H2020-EU.3.5. H2020-EU.3.5.1./Beyond EPICA hal-03434954 https://hal.science/hal-03434954 https://hal.science/hal-03434954/document https://hal.science/hal-03434954/file/bacc1.pdf doi:10.5194/tc-15-4807-2021 |
op_rights |
http://creativecommons.org/licenses/by/ info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.5194/tc-15-4807-2021 |
container_title |
The Cryosphere |
container_volume |
15 |
container_issue |
10 |
container_start_page |
4807 |
op_container_end_page |
4822 |
_version_ |
1797572755370016768 |
spelling |
ftuniversailles:oai:HAL:hal-03434954v1 2024-04-28T08:00:36+00:00 Deep ice as a geochemical reactor: Insights from iron speciation and mineralogy of dust in the Talos Dome ice core (East Antarctica) Baccolo, Giovanni Delmonte, Barbara Di Stefano, Elena Cibin, Giannantonio Crotti, Ilaria Frezzotti, Massimo Hampai, Dariush Iizuka, Yoshinori Marcelli, Augusto Maggi, Valter Department of Earth and Environmental Sciences Milano Università degli Studi di Milano-Bicocca = University of Milano-Bicocca (UNIMIB) DIAMOND Light source Laboratoire des Sciences du Climat et de l'Environnement Gif-sur-Yvette (LSCE) Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)) Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA) Department of Earth Sciences Roma Università degli Studi di Roma "La Sapienza" = Sapienza University Rome (UNIROMA) Laboratori Nazionali di Frascati = National Laboratory of Frascati (LNF) Istituto Nazionale di Fisica Nucleare (INFN) Institute of Low Temperature Science Sapporo Hokkaido University Sapporo, Japan RICMASS Rome Int Ctr Mat Sci Superstripes, I-00185 Rome, Italy This research has been supported by the Ministero dell'Istruzione, dell'Università e della Ricerca (grant no. PNRA18-00098); Horizon 2020 (grant no. Beyond EPICA (815384)); and Diamond Light Source (grant nos. sp7314, sp8372 and sp9050). Primary logistical support was provided by PNRA at Talos Dome. This is TALDICE publication no. 62. This publication was generated in the frame of Beyond EPICA. The project has received funding from the European Union’s Horizon 2020 Research And Innovation Programme under grant agreement no. 815384 (Oldest Ice Core). It is supported by national partners and funding agencies in Belgium, Denmark, France, Germany, Italy, Norway, Sweden, Switzerland, the Netherlands and the United Kingdom. Logistic support is mainly provided by PNRA and IPEV through the Concordia Station system. The opinions expressed and arguments employed herein do not necessarily reflect the official views of the European Union funding agency or other national funding bodies. This is Beyond EPICA publication number 22. We thank Paolo Gentile for providing mineral standards and also Paul Niles and Tanya Peretyazhko for the fruitful discussions. European Project: 331615,EC:FP7:PEOPLE,FP7-PEOPLE-2012-IIF,TALDICE HOLOCENE(2013) European Project: 815384,Beyond EPICA 2021 https://hal.science/hal-03434954 https://hal.science/hal-03434954/document https://hal.science/hal-03434954/file/bacc1.pdf https://doi.org/10.5194/tc-15-4807-2021 en eng HAL CCSD Copernicus info:eu-repo/semantics/altIdentifier/doi/10.5194/tc-15-4807-2021 info:eu-repo/grantAgreement/EC/FP7/331615/EU/Holocene climate variability at Talos Dome, Antarctica/TALDICE HOLOCENE info:eu-repo/grantAgreement//815384/EU/Beyond EPICA Oldest Ice Core: 1,5 Myr of greenhouse gas – climate feedbacks - H2020-EU.3.5. H2020-EU.3.5.1./Beyond EPICA hal-03434954 https://hal.science/hal-03434954 https://hal.science/hal-03434954/document https://hal.science/hal-03434954/file/bacc1.pdf doi:10.5194/tc-15-4807-2021 http://creativecommons.org/licenses/by/ info:eu-repo/semantics/OpenAccess ISSN: 1994-0424 EISSN: 1994-0416 The Cryosphere https://hal.science/hal-03434954 The Cryosphere, 2021, 15 (10), pp.4807-4822. ⟨10.5194/tc-15-4807-2021⟩ https://tc.copernicus.org/articles/15/4807/2021/ [SDU]Sciences of the Universe [physics] info:eu-repo/semantics/article Journal articles 2021 ftuniversailles https://doi.org/10.5194/tc-15-4807-2021 2024-04-04T17:31:50Z International audience Thanks to its insolubility, mineral dust is considered a stable proxy in polar ice cores. With this study we show that the Talos Dome ice core (TALDICE, Ross Sea sector of East Antarctica) displays evident and progressive signs of post-depositional processes affecting the mineral dust record below 1000g m deep. We apply a suite of established and cutting-edge techniques to investigate the properties of dust in TALDICE, ranging from concentration and grain size to elemental composition and Fe mineralogy. Results show that through acidic/oxidative weathering, the conditions of deep ice at Talos Dome promote the dissolution of specific minerals and the englacial formation of others, affecting primitive dust features. The expulsion of acidic atmospheric species from ice grains and their concentration in localized environments is likely the main process responsible for englacial reactions. Deep ice can be seen as a "geochemical reactor"capable of fostering complex reactions which involve both soluble and insoluble impurities. Fe-bearing minerals can efficiently help in exploring such transformations. Article in Journal/Newspaper Antarc* Antarctica East Antarctica ice core Ross Sea The Cryosphere Université de Versailles Saint-Quentin-en-Yvelines: HAL-UVSQ The Cryosphere 15 10 4807 4822 |