Atmospheric mercury in the Southern Hemisphere – Part 1: Trend and inter-annual variations in atmospheric mercury at Cape Point, South Africa, in 2007–2017, and on Amsterdam Island in 2012–2017

• Published in: Atmospheric Chemistry and Physics
• Main Authors: Slemr, Franz, Martin, Lynwill, Labuschagne, Casper, Mkololo, Thumeka, Angot, Helene, Magand, Olivier, Dommergue, Aurélien, Garat, Philippe, Ramonet, Michel, Bieser, Johannes
• Other Authors: Atmospheric Chemistry Department MPIC, Max Planck Institute for Chemistry (MPIC), Max-Planck-Gesellschaft-Max-Planck-Gesellschaft, South African Weather Service (SAWS), Institute of Arctic Alpine Research University of Colorado Boulder (INSTAAR), University of Colorado Boulder, Institut des Géosciences de l’Environnement (IGE), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Observatoire des Sciences de l'Univers de Grenoble (Fédération OSUG)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP), Université Grenoble Alpes (UGA), Statistique pour le Vivant et l’Homme (SVH), Laboratoire Jean Kuntzmann (LJK), Institut National de Recherche en Informatique et en Automatique (Inria)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP), Université Grenoble Alpes (UGA)-Institut National de Recherche en Informatique et en Automatique (Inria)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP), Laboratoire des Sciences du Climat et de l'Environnement Gif-sur-Yvette (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA), ICOS-RAMCES (ICOS-RAMCES), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Helmholtz-Zentrum Geesthacht (GKSS), ANR-10-LABX-0056,OSUG@2020,Innovative strategies for observing and modelling natural systems(2010)
• Format: Article in Journal/Newspaper
• Language: English
• Published: CCSD 2020
• Subjects: [SDU.OCEAN]Sciences of the Universe [physics]/Ocean; Atmosphere; Indian; Amsterdam Island
• Online Access: https://hal.science/hal-02897103; https://hal.science/hal-02897103v1/document; https://hal.science/hal-02897103v1/file/acp-20-7683-2020.pdf; https://doi.org/10.5194/acp-20-7683-2020

International audience The Minamata Convention on Mercury (Hg) entered into force in 2017, committing its 116 parties (as of January 2019) to curb anthropogenic emissions. Monitoring of atmospheric concentrations and trends is an important part of the effectiveness evaluation of the convention. A few years ago (in 2017) we reported an increasing trend in atmospheric Hg concentrations at the Cape Point Global Atmosphere Watch (GAW) station in South Africa (34.3535∘ S, 18.4897∘ E) for the 2007–2015 period. With 2 more years of measurements at Cape Point and the 2012–2017 data from Amsterdam Island (37.7983∘ S, 77.5378∘ E) in the remote southern Indian Ocean, a more complex picture emerges: at Cape Point the upward trend for the 2007–2017 period is still significant, but no trend or a slightly downward trend was detected for the period 2012–2017 at both Cape Point and Amsterdam Island. The upward trend at Cape Point is driven mainly by the Hg concentration minimum in 2009 and maxima in 2014 and 2012. Using ancillary data on 222Rn, CO, O3, CO2, and CH4 from Cape Point and Amsterdam Island, the possible reasons for the trend and its change are investigated. In a companion paper this analysis is extended for the Cape Point station by calculations of source and sink regions using backward-trajectory analysis.