From chemical gardens to chemobrionics
Chemical gardens in laboratory chemistries ranging from silicates to polyoxometalates, in applications ranging from corrosion products to the hydration of Portland cement, and in natural settings ranging from hydrothermal vents in the ocean depths to brinicles beneath sea ice. In many chemical-garde...
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ftunivbruxelles:oai:dipot.ulb.ac.be:2013/218171 2023-05-15T18:18:26+02:00 From chemical gardens to chemobrionics Barge, Laura L.M. Haudin, Florence Jones, David E H Mackay, Alan A.L. Maselko, Jerzy Pagano, Jason J.J. Pantaleone, James Russell, Michael John Sainz-Díaz, Claro Ignacio Steinbock, Oliver Stone, David D.A. Cardoso, Silvana S S Tanimoto, Yoshifumi Thomas, Noreen N.L. Cartwright, Julyan J.H.E. Cooper, Geoffrey J T Cronin, Leroy De Wit, Anne Doloboff, Ivria I.J. Escribano, Bruno Goldstein, Raymond Ethan 2015 1 full-text file(s): application/pdf http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/218171 https://dipot.ulb.ac.be/dspace/bitstream/2013/218171/3/15.Chem_review.pdf en eng uri/info:doi/10.1021/acs.chemrev.5b00014 uri/info:scp/84940513992 https://dipot.ulb.ac.be/dspace/bitstream/2013/218171/3/15.Chem_review.pdf http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/218171 1 full-text file(s): info:eu-repo/semantics/restrictedAccess Chemical reviews, 115 (16 Chimie info:eu-repo/semantics/article info:ulb-repo/semantics/articlePeerReview info:ulb-repo/semantics/openurl/article 2015 ftunivbruxelles 2022-06-12T21:27:33Z Chemical gardens in laboratory chemistries ranging from silicates to polyoxometalates, in applications ranging from corrosion products to the hydration of Portland cement, and in natural settings ranging from hydrothermal vents in the ocean depths to brinicles beneath sea ice. In many chemical-garden experiments, the structure forms as a solid seed of a soluble ionic compound dissolves in a solution containing another reactive ion. In general any alkali silicate solution can be used due to their high solubility at high pH. The cation should not precipitate with the counterion of the metal salt used as seed. A main property of seed chemical-garden experiments is that initially, when the fluid is not moving under buoyancy or osmosis, the delivery of the inner reactant is diffusion controlled. Another experimental technique that isolates one aspect of chemical-garden formation is to produce precipitation membranes between different aqueous solutions by introducing the two solutions on either side of an inert carrier matrix. Chemical gardens may be grown upon injection of solutions into a so-called Hele-Shaw cell, a quasi-two-dimensional reactor consisting in two parallel plates separated by a small gap. SCOPUS: ar.j info:eu-repo/semantics/published Article in Journal/Newspaper Sea ice DI-fusion : dépôt institutionnel de l'Université libre de Bruxelles (ULB) |
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DI-fusion : dépôt institutionnel de l'Université libre de Bruxelles (ULB) |
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ftunivbruxelles |
language |
English |
topic |
Chimie |
spellingShingle |
Chimie Barge, Laura L.M. Haudin, Florence Jones, David E H Mackay, Alan A.L. Maselko, Jerzy Pagano, Jason J.J. Pantaleone, James Russell, Michael John Sainz-Díaz, Claro Ignacio Steinbock, Oliver Stone, David D.A. Cardoso, Silvana S S Tanimoto, Yoshifumi Thomas, Noreen N.L. Cartwright, Julyan J.H.E. Cooper, Geoffrey J T Cronin, Leroy De Wit, Anne Doloboff, Ivria I.J. Escribano, Bruno Goldstein, Raymond Ethan From chemical gardens to chemobrionics |
topic_facet |
Chimie |
description |
Chemical gardens in laboratory chemistries ranging from silicates to polyoxometalates, in applications ranging from corrosion products to the hydration of Portland cement, and in natural settings ranging from hydrothermal vents in the ocean depths to brinicles beneath sea ice. In many chemical-garden experiments, the structure forms as a solid seed of a soluble ionic compound dissolves in a solution containing another reactive ion. In general any alkali silicate solution can be used due to their high solubility at high pH. The cation should not precipitate with the counterion of the metal salt used as seed. A main property of seed chemical-garden experiments is that initially, when the fluid is not moving under buoyancy or osmosis, the delivery of the inner reactant is diffusion controlled. Another experimental technique that isolates one aspect of chemical-garden formation is to produce precipitation membranes between different aqueous solutions by introducing the two solutions on either side of an inert carrier matrix. Chemical gardens may be grown upon injection of solutions into a so-called Hele-Shaw cell, a quasi-two-dimensional reactor consisting in two parallel plates separated by a small gap. SCOPUS: ar.j info:eu-repo/semantics/published |
format |
Article in Journal/Newspaper |
author |
Barge, Laura L.M. Haudin, Florence Jones, David E H Mackay, Alan A.L. Maselko, Jerzy Pagano, Jason J.J. Pantaleone, James Russell, Michael John Sainz-Díaz, Claro Ignacio Steinbock, Oliver Stone, David D.A. Cardoso, Silvana S S Tanimoto, Yoshifumi Thomas, Noreen N.L. Cartwright, Julyan J.H.E. Cooper, Geoffrey J T Cronin, Leroy De Wit, Anne Doloboff, Ivria I.J. Escribano, Bruno Goldstein, Raymond Ethan |
author_facet |
Barge, Laura L.M. Haudin, Florence Jones, David E H Mackay, Alan A.L. Maselko, Jerzy Pagano, Jason J.J. Pantaleone, James Russell, Michael John Sainz-Díaz, Claro Ignacio Steinbock, Oliver Stone, David D.A. Cardoso, Silvana S S Tanimoto, Yoshifumi Thomas, Noreen N.L. Cartwright, Julyan J.H.E. Cooper, Geoffrey J T Cronin, Leroy De Wit, Anne Doloboff, Ivria I.J. Escribano, Bruno Goldstein, Raymond Ethan |
author_sort |
Barge, Laura L.M. |
title |
From chemical gardens to chemobrionics |
title_short |
From chemical gardens to chemobrionics |
title_full |
From chemical gardens to chemobrionics |
title_fullStr |
From chemical gardens to chemobrionics |
title_full_unstemmed |
From chemical gardens to chemobrionics |
title_sort |
from chemical gardens to chemobrionics |
publishDate |
2015 |
url |
http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/218171 https://dipot.ulb.ac.be/dspace/bitstream/2013/218171/3/15.Chem_review.pdf |
genre |
Sea ice |
genre_facet |
Sea ice |
op_source |
Chemical reviews, 115 (16 |
op_relation |
uri/info:doi/10.1021/acs.chemrev.5b00014 uri/info:scp/84940513992 https://dipot.ulb.ac.be/dspace/bitstream/2013/218171/3/15.Chem_review.pdf http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/218171 |
op_rights |
1 full-text file(s): info:eu-repo/semantics/restrictedAccess |
_version_ |
1766195010826403840 |