The distribution of 227Ac along the GA01 section in the North Atlantic

• Published in: Marine Chemistry
• Main Authors: Le Roy, Emilie, van Beek, Pieter, Lacan, François, Souhaut, Marc, Sanial, Virginie, Charette, Matthew, A, Henderson, Paul, B, Deng, Feifei
• Other Authors: Laboratoire des Sciences de l'Environnement Marin (LEMAR) (LEMAR), Institut de Recherche pour le Développement (IRD)-Institut Français de Recherche pour l'Exploitation de la Mer (IFREMER)-Université de Brest (UBO)-Institut Universitaire Européen de la Mer (IUEM), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire d'études en Géophysique et océanographie spatiales (LEGOS), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales Toulouse (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France-Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales Toulouse (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France-Centre National de la Recherche Scientifique (CNRS), Institut méditerranéen d'océanologie (MIO), Institut de Recherche pour le Développement (IRD)-Aix Marseille Université (AMU)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Toulon (UTLN)-Centre National de la Recherche Scientifique (CNRS), Department of Marine Chemistry and Geochemistry (WHOI), Woods Hole Oceanographic Institution (WHOI), Max-Planck-Institut, ANR-13-BS06-0014,GEOVIDE,GEOVIDE, Une étude internationale GEOTRACES le long de la section OVIDE en Atlantique Nord et en Mer du Labrador(2013), ANR-12-PDOC-0025,BITMAP,Biodisponibilité du fer et des métaux traces dans les particules marines(2012), ANR-10-LABX-0019,LabexMER,LabexMER Marine Excellence Research: a changing ocean(2010)
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2023
• Subjects: GEOTRACES; Actinium; Actinium-227; North Atlantic; [SDU.STU.OC]Sciences of the Universe [physics]/Earth Sciences/Oceanography; [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry; Canada; Greenland; Irminger Basin
• Online Access: https://hal.science/hal-03959500; https://hal.science/hal-03959500/document; https://hal.science/hal-03959500/file/1-s2.0-S0304420323000038-main%20%283%29.pdf; https://doi.org/10.1016/j.marchem.2023.104207

International audience Actinium-227 is a powerful tool to study vertical mixing in the ocean, and was more recently proposed as a tracer of hydrothermal plumes. However, because 227 Ac activities are especially low in the ocean, relatively few studies have been conducted to date, and none has been done on the large scale, as is reported in the present study. Here, we report a section of dissolved 227 Ac in the North Atlantic Ocean between Portugal-Greenland-Canada based on nine full-depth profiles obtained in the framework of the international GEOTRACES program (GA01 section-GEOVIDE cruise, May-July 2014). The simultaneous determination of 231 Pa, the parent nuclide of 227 Ac, along the section allowed us to report a section of excess 227 Ac activities (227 Ac ex). Actinium-227 activities were especially low along the section (< 0.4 dpm m 3) compared to other ocean basins. In most cases, 227 Ac activities reached secular equilibrium with 231 Pa in the water column 500 m above the seafloor. Secular equilibrium is considered reached after ~five half-lives of the daughter. Secular equilibrium therefore suggests no external input over the last ~100 years. The highest 227 Ac activities were often found close to the seafloor, indicating that 227 Ac diffuses out of the sediments. However, two different patterns question the traditional one-dimensional vertical mixing model typically applied to 227 Ac released by deep-sea sediments: first, significant 227 Ac ex were found in the upper 500 m of the water column at several stations located near the Iberian margin. In the upper 500 m, the high 227 Ac ex activities could indicate lateral advection of waters that interacted with the margins. Second, mid-water peaks of 227 Ac ex were occasionally observed along the transect. At station 44 in the Irminger Basin, a peak of 227 Ac ex activity at 2500 m that was co-located with high dissolved Fe concentrations could be interpreted as the signature of a hydrothermal plume. Near the seafloor, we often observed bottom nepheloid ...