Investigation into the impact of solid surfaces in aqueous systems
Global warming is upon us. The scientific community is searching for methods of slowing down, preventing and reversing its effects. Carbon dioxide have been at the center of attention the last few decades, being the main contributor to man-made global warming. Carbon capture and sequestration is one...
Published in: | Molecular Physics |
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Main Author: | |
Format: | Doctoral or Postdoctoral Thesis |
Language: | English |
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The University of Bergen
2016
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Online Access: | https://hdl.handle.net/1956/11929 |
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openpolar |
institution |
Open Polar |
collection |
University of Bergen: Bergen Open Research Archive (BORA-UiB) |
op_collection_id |
ftunivbergen |
language |
English |
description |
Global warming is upon us. The scientific community is searching for methods of slowing down, preventing and reversing its effects. Carbon dioxide have been at the center of attention the last few decades, being the main contributor to man-made global warming. Carbon capture and sequestration is one of the potential tools in this under- taking of mitigation. By capturing carbon dioxide and transporting it to injection sites for subsurface storage the amount released can be reduced. This thesis approaches several of the topics involved in transport and sequestration of carbon dioxide. Carbon dioxide transport to injection site will likely be by pipelines. In arctic regions the potential for ice-like structures known as clathrates, or hydrates, to form due to the high pressure and low temperature conditions is significant. Reducing the risks of hydrate formation calls for knowledge of the decisive factors. Thus, this work participates in the development of more robust strategies for hydrate prediction and consequently prevention. In pipelines, oxidized carbon steel surfaces are readily available. These have proven to be excellent adsorption sites for water in the gas stream. Carbon dioxide is an hydrate former, capable of stabilizing hydrate cavities of water molecules as a guest molecule. Here the chemical potential of water, carbon dioxide and hydrogen sulfide is examined under realistic pipeline conditions. These results are used to predict if, in which phase, and from which phases, hydrate will form. It was found that water will adsorb onto the hematite (rust) surface. The water layers closest to the hematite have too low chemical potential for hydrates to form. However, as the distance to the hematite increases, water regains more and more of its bulk properties, where hydrates are possible. Adsorbed impurities like hydrogen sulfide is shown to assist carbon dioxide in forming stable hydrates. We draw the conclusion that relying solely on dew-point calculations may underestimate the risk of hydrate formation. ... |
format |
Doctoral or Postdoctoral Thesis |
author |
Jensen, Bjørnar |
spellingShingle |
Jensen, Bjørnar Investigation into the impact of solid surfaces in aqueous systems |
author_facet |
Jensen, Bjørnar |
author_sort |
Jensen, Bjørnar |
title |
Investigation into the impact of solid surfaces in aqueous systems |
title_short |
Investigation into the impact of solid surfaces in aqueous systems |
title_full |
Investigation into the impact of solid surfaces in aqueous systems |
title_fullStr |
Investigation into the impact of solid surfaces in aqueous systems |
title_full_unstemmed |
Investigation into the impact of solid surfaces in aqueous systems |
title_sort |
investigation into the impact of solid surfaces in aqueous systems |
publisher |
The University of Bergen |
publishDate |
2016 |
url |
https://hdl.handle.net/1956/11929 |
geographic |
Arctic |
geographic_facet |
Arctic |
genre |
Arctic Global warming |
genre_facet |
Arctic Global warming |
op_relation |
Paper I: P. V. Cuong, B. Kvamme, T. Kuznetsova, and B. Jensen. “Molecular dynamics study of calcite, hydrate and the temperature effect on CO2 transport and adsorption stability in geological formations”. Molecular Physics 110, 11-12, pp. 1097–1106, (2012) This article is not available in BORA. The published version is available at: 10.1080/00268976.2012.679629 Paper II: B. Kvamme, T. Kuznetsova, B. Jensen, S. Stensholt, J. Bauman, S. Sjöblom, and K. Nes Lervik. “Consequences of CO2 solubility for hydrate formation from carbon dioxide containing water and other impurities”. Physical Chemistry Chemical Physics. 16, 18, pp. 8623–8638, (2014) This article is not available in BORA. The published version is available at: 10.1039/C3CP53858C Paper III: T. Kuznetsova, B. Jensen, B. Kvamme, and S. Sjöblom. “Water-wetting surfaces as hydrate promoters during transport of carbon dioxide with impurities”.Physical Chemistry Chemical Physics 17, 19, pp. 12683–12697, (2015) This article is not available in BORA. The published version is available at: 10.1039/C5CP00660K Paper IV: B. Jensen, T. Kuznetsova, B. Kvamme, and R. Olsen. “The impact of electrostatics in bulk Linde Type A zeolites”. Microporous and Mesoporous Materials 201, 0, pp. 105-115, (2015) The published version is available at: 10.1016/j.micromeso.2014.09.009 Paper V: B. Jensen, B. Kvamme, and T. Kuznetsova. “The effect of interfacial charge distributions and terminations in LTA zeolites”. Microporous and Mesoporous Materials N/A. Status: Accepted manuscript, N/A. (2015) This article is not available in BORA. https://hdl.handle.net/1956/11929 |
op_rights |
Copyright the author. All rights reserved. |
op_doi |
https://doi.org/10.1080/00268976.2012.67962910.1039/C3CP53858C10.1039/C5CP00660K10.1016/j.micromeso.2014.09.009 |
container_title |
Molecular Physics |
container_volume |
110 |
container_issue |
11-12 |
container_start_page |
1097 |
op_container_end_page |
1106 |
_version_ |
1766347236463083520 |
spelling |
ftunivbergen:oai:bora.uib.no:1956/11929 2023-05-15T15:16:57+02:00 Investigation into the impact of solid surfaces in aqueous systems Jensen, Bjørnar 2016-03-03 application/pdf https://hdl.handle.net/1956/11929 eng eng The University of Bergen Paper I: P. V. Cuong, B. Kvamme, T. Kuznetsova, and B. Jensen. “Molecular dynamics study of calcite, hydrate and the temperature effect on CO2 transport and adsorption stability in geological formations”. Molecular Physics 110, 11-12, pp. 1097–1106, (2012) This article is not available in BORA. The published version is available at: 10.1080/00268976.2012.679629 Paper II: B. Kvamme, T. Kuznetsova, B. Jensen, S. Stensholt, J. Bauman, S. Sjöblom, and K. Nes Lervik. “Consequences of CO2 solubility for hydrate formation from carbon dioxide containing water and other impurities”. Physical Chemistry Chemical Physics. 16, 18, pp. 8623–8638, (2014) This article is not available in BORA. The published version is available at: 10.1039/C3CP53858C Paper III: T. Kuznetsova, B. Jensen, B. Kvamme, and S. Sjöblom. “Water-wetting surfaces as hydrate promoters during transport of carbon dioxide with impurities”.Physical Chemistry Chemical Physics 17, 19, pp. 12683–12697, (2015) This article is not available in BORA. The published version is available at: 10.1039/C5CP00660K Paper IV: B. Jensen, T. Kuznetsova, B. Kvamme, and R. Olsen. “The impact of electrostatics in bulk Linde Type A zeolites”. Microporous and Mesoporous Materials 201, 0, pp. 105-115, (2015) The published version is available at: 10.1016/j.micromeso.2014.09.009 Paper V: B. Jensen, B. Kvamme, and T. Kuznetsova. “The effect of interfacial charge distributions and terminations in LTA zeolites”. Microporous and Mesoporous Materials N/A. Status: Accepted manuscript, N/A. (2015) This article is not available in BORA. https://hdl.handle.net/1956/11929 Copyright the author. All rights reserved. Doctoral thesis 2016 ftunivbergen https://doi.org/10.1080/00268976.2012.67962910.1039/C3CP53858C10.1039/C5CP00660K10.1016/j.micromeso.2014.09.009 2023-03-14T17:41:15Z Global warming is upon us. The scientific community is searching for methods of slowing down, preventing and reversing its effects. Carbon dioxide have been at the center of attention the last few decades, being the main contributor to man-made global warming. Carbon capture and sequestration is one of the potential tools in this under- taking of mitigation. By capturing carbon dioxide and transporting it to injection sites for subsurface storage the amount released can be reduced. This thesis approaches several of the topics involved in transport and sequestration of carbon dioxide. Carbon dioxide transport to injection site will likely be by pipelines. In arctic regions the potential for ice-like structures known as clathrates, or hydrates, to form due to the high pressure and low temperature conditions is significant. Reducing the risks of hydrate formation calls for knowledge of the decisive factors. Thus, this work participates in the development of more robust strategies for hydrate prediction and consequently prevention. In pipelines, oxidized carbon steel surfaces are readily available. These have proven to be excellent adsorption sites for water in the gas stream. Carbon dioxide is an hydrate former, capable of stabilizing hydrate cavities of water molecules as a guest molecule. Here the chemical potential of water, carbon dioxide and hydrogen sulfide is examined under realistic pipeline conditions. These results are used to predict if, in which phase, and from which phases, hydrate will form. It was found that water will adsorb onto the hematite (rust) surface. The water layers closest to the hematite have too low chemical potential for hydrates to form. However, as the distance to the hematite increases, water regains more and more of its bulk properties, where hydrates are possible. Adsorbed impurities like hydrogen sulfide is shown to assist carbon dioxide in forming stable hydrates. We draw the conclusion that relying solely on dew-point calculations may underestimate the risk of hydrate formation. ... Doctoral or Postdoctoral Thesis Arctic Global warming University of Bergen: Bergen Open Research Archive (BORA-UiB) Arctic Molecular Physics 110 11-12 1097 1106 |