Synthesis of Organic Carbamates without Using Phosgene: Carbonylation of Amines with Carbonic Acid Diesters

Aminolysis of organic carbonates is a suitable phosgene-free synthetic route to carbamate esters. The paper reviews recent advances in this field. Emphasis is laid on the reaction of amines with industrially relevant carbonic acid diesters, (MeO)2CO, (PhO)2CO, MeOC(O)OPh, currently obtainable withou...

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Bibliographic Details
Main Authors: M. CARAFA, QUARANTA, Eugenio
Other Authors: M., Carafa, Quaranta, Eugenio
Format: Article in Journal/Newspaper
Language:English
Published: 2009
Subjects:
carbamate
organic carbonate
phosgene substitution
carbonylation
catalysis
Carbonic acid
Online Access:http://hdl.handle.net/11586/49516
id ftunivbari:oai:ricerca.uniba.it:11586/49516
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spelling ftunivbari:oai:ricerca.uniba.it:11586/49516 2024-02-11T10:02:51+01:00 Synthesis of Organic Carbamates without Using Phosgene: Carbonylation of Amines with Carbonic Acid Diesters M. CARAFA QUARANTA, Eugenio M., Carafa Quaranta, Eugenio 2009 http://hdl.handle.net/11586/49516 eng eng info:eu-repo/semantics/altIdentifier/wos/000268913100002 volume:6 firstpage:168 lastpage:183 numberofpages:16 journal:MINI-REVIEWS IN ORGANIC CHEMISTRY http://hdl.handle.net/11586/49516 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-67651167979 carbamate organic carbonate phosgene substitution carbonylation catalysis info:eu-repo/semantics/article 2009 ftunivbari 2024-01-17T17:31:19Z Aminolysis of organic carbonates is a suitable phosgene-free synthetic route to carbamate esters. The paper reviews recent advances in this field. Emphasis is laid on the reaction of amines with industrially relevant carbonic acid diesters, (MeO)2CO, (PhO)2CO, MeOC(O)OPh, currently obtainable without using phosgene. The carbonylation process may require a catalyst. The use of effective catalytic systems is highlighted and their mode of action is discussed. Article in Journal/Newspaper Carbonic acid Università degli Studi di Bari Aldo Moro: CINECA IRIS
institution Open Polar
collection Università degli Studi di Bari Aldo Moro: CINECA IRIS
op_collection_id ftunivbari
language English
topic carbamate
organic carbonate
phosgene substitution
carbonylation
catalysis
spellingShingle carbamate
organic carbonate
phosgene substitution
carbonylation
catalysis
M. CARAFA
QUARANTA, Eugenio
Synthesis of Organic Carbamates without Using Phosgene: Carbonylation of Amines with Carbonic Acid Diesters
topic_facet carbamate
organic carbonate
phosgene substitution
carbonylation
catalysis
description Aminolysis of organic carbonates is a suitable phosgene-free synthetic route to carbamate esters. The paper reviews recent advances in this field. Emphasis is laid on the reaction of amines with industrially relevant carbonic acid diesters, (MeO)2CO, (PhO)2CO, MeOC(O)OPh, currently obtainable without using phosgene. The carbonylation process may require a catalyst. The use of effective catalytic systems is highlighted and their mode of action is discussed.
author2 M., Carafa
Quaranta, Eugenio
format Article in Journal/Newspaper
author M. CARAFA
QUARANTA, Eugenio
author_facet M. CARAFA
QUARANTA, Eugenio
author_sort M. CARAFA
title Synthesis of Organic Carbamates without Using Phosgene: Carbonylation of Amines with Carbonic Acid Diesters
title_short Synthesis of Organic Carbamates without Using Phosgene: Carbonylation of Amines with Carbonic Acid Diesters
title_full Synthesis of Organic Carbamates without Using Phosgene: Carbonylation of Amines with Carbonic Acid Diesters
title_fullStr Synthesis of Organic Carbamates without Using Phosgene: Carbonylation of Amines with Carbonic Acid Diesters
title_full_unstemmed Synthesis of Organic Carbamates without Using Phosgene: Carbonylation of Amines with Carbonic Acid Diesters
title_sort synthesis of organic carbamates without using phosgene: carbonylation of amines with carbonic acid diesters
publishDate 2009
url http://hdl.handle.net/11586/49516
genre Carbonic acid
genre_facet Carbonic acid
op_relation info:eu-repo/semantics/altIdentifier/wos/000268913100002
volume:6
firstpage:168
lastpage:183
numberofpages:16
journal:MINI-REVIEWS IN ORGANIC CHEMISTRY
http://hdl.handle.net/11586/49516
info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-67651167979
_version_ 1790598929962762240

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