Paving the way for methane hydrate formation on metal–organic frameworks (MOFs)
The presence of a highly tunable porous structure and surface chemistry makes metal–organic framework (MOF) materials excellent candidates for artificial methane hydrate formation under mild temperature and pressure conditions (2 °C and 3–5 MPa). Experimental results using MOFs with a different pore...
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Royal Society of Chemistry
2016
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Online Access: | http://hdl.handle.net/10045/55368 https://doi.org/10.1039/C6SC00272B |
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ftunivalicante:oai:rua.ua.es:10045/55368 2023-05-15T17:11:36+02:00 Paving the way for methane hydrate formation on metal–organic frameworks (MOFs) Casco, Mirian Elizabeth Rey, Fernando Jordá, José L. Rudić, Svemir Fauth, François Martinez-Escandell, Manuel Rodríguez Reinoso, Francisco Ramos-Fernández, Enrique V. Silvestre-Albero, Joaquín Universidad de Alicante. Departamento de Química Inorgánica Universidad de Alicante. Instituto Universitario de Materiales Materiales Avanzados 2016-02-19 http://hdl.handle.net/10045/55368 https://doi.org/10.1039/C6SC00272B eng eng Royal Society of Chemistry http://dx.doi.org/10.1039/C6SC00272B info:eu-repo/grantAgreement/EC/FP7/283883 Chemical Science. 2016, 7: 3658-3666. doi:10.1039/C6SC00272B 2041-6520 (Print) 2041-6539 (Online) http://hdl.handle.net/10045/55368 doi:10.1039/C6SC00272B This article is licensed under a Creative Commons Attribution 3.0 Unported Licence info:eu-repo/semantics/openAccess CC-BY Metal–organic frameworks (MOFs) Methane hydrate Química Inorgánica info:eu-repo/semantics/article 2016 ftunivalicante https://doi.org/10.1039/C6SC00272B 2020-06-05T13:11:06Z The presence of a highly tunable porous structure and surface chemistry makes metal–organic framework (MOF) materials excellent candidates for artificial methane hydrate formation under mild temperature and pressure conditions (2 °C and 3–5 MPa). Experimental results using MOFs with a different pore structure and chemical nature (MIL-100 (Fe) and ZIF-8) clearly show that the water–framework interactions play a crucial role in defining the extent and nature of the gas hydrates formed. Whereas the hydrophobic MOF promotes methane hydrate formation with a high yield, the hydrophilic one does not. The formation of these methane hydrates on MOFs has been identified for the first time using inelastic neutron scattering (INS) and synchrotron X-ray powder diffraction (SXRPD). The results described in this work pave the way towards the design of new MOF structures able to promote artificial methane hydrate formation upon request (confined or non-confined) and under milder conditions than in nature. We acknowledge the UK Science and Technology Facilities Council for the provision of beam time on the TOSCA spectrometer (Project RB1510448) and financial support from the European Commission under the 7th Framework Programme through the “Research Infrastructures” action of the “Capacities” Programme (NMI3-II Grant number 283883). J. S.-A. acknowledges financial support from MINECO Projects: MAT2013-45008-p and CONCERT Project-NASEMS (PCIN-2013-057) and from Generalitat Valenciana (PROMETEO2009/002). The authors acknowledge the Spanish synchrotron ALBA for beam time availability. E. V. R.-F. gratefully acknowledges a Ramon y Cajal grant (RyC-2012-11427). F. R. and J. L. J. acknowledge financial support from MINECO through projects MAT2012-38567-C02-01, Consolider Ingenio 2010-Multicat CSD-2009-00050 and Severo Ochoa SEV-2012-0267, and Generalitat Valenciana (Prometeo). Article in Journal/Newspaper Methane hydrate RUA - Repositorio Institucional de la Universidad de Alicante Chemical Science 7 6 3658 3666 |
institution |
Open Polar |
collection |
RUA - Repositorio Institucional de la Universidad de Alicante |
op_collection_id |
ftunivalicante |
language |
English |
topic |
Metal–organic frameworks (MOFs) Methane hydrate Química Inorgánica |
spellingShingle |
Metal–organic frameworks (MOFs) Methane hydrate Química Inorgánica Casco, Mirian Elizabeth Rey, Fernando Jordá, José L. Rudić, Svemir Fauth, François Martinez-Escandell, Manuel Rodríguez Reinoso, Francisco Ramos-Fernández, Enrique V. Silvestre-Albero, Joaquín Paving the way for methane hydrate formation on metal–organic frameworks (MOFs) |
topic_facet |
Metal–organic frameworks (MOFs) Methane hydrate Química Inorgánica |
description |
The presence of a highly tunable porous structure and surface chemistry makes metal–organic framework (MOF) materials excellent candidates for artificial methane hydrate formation under mild temperature and pressure conditions (2 °C and 3–5 MPa). Experimental results using MOFs with a different pore structure and chemical nature (MIL-100 (Fe) and ZIF-8) clearly show that the water–framework interactions play a crucial role in defining the extent and nature of the gas hydrates formed. Whereas the hydrophobic MOF promotes methane hydrate formation with a high yield, the hydrophilic one does not. The formation of these methane hydrates on MOFs has been identified for the first time using inelastic neutron scattering (INS) and synchrotron X-ray powder diffraction (SXRPD). The results described in this work pave the way towards the design of new MOF structures able to promote artificial methane hydrate formation upon request (confined or non-confined) and under milder conditions than in nature. We acknowledge the UK Science and Technology Facilities Council for the provision of beam time on the TOSCA spectrometer (Project RB1510448) and financial support from the European Commission under the 7th Framework Programme through the “Research Infrastructures” action of the “Capacities” Programme (NMI3-II Grant number 283883). J. S.-A. acknowledges financial support from MINECO Projects: MAT2013-45008-p and CONCERT Project-NASEMS (PCIN-2013-057) and from Generalitat Valenciana (PROMETEO2009/002). The authors acknowledge the Spanish synchrotron ALBA for beam time availability. E. V. R.-F. gratefully acknowledges a Ramon y Cajal grant (RyC-2012-11427). F. R. and J. L. J. acknowledge financial support from MINECO through projects MAT2012-38567-C02-01, Consolider Ingenio 2010-Multicat CSD-2009-00050 and Severo Ochoa SEV-2012-0267, and Generalitat Valenciana (Prometeo). |
author2 |
Universidad de Alicante. Departamento de Química Inorgánica Universidad de Alicante. Instituto Universitario de Materiales Materiales Avanzados |
format |
Article in Journal/Newspaper |
author |
Casco, Mirian Elizabeth Rey, Fernando Jordá, José L. Rudić, Svemir Fauth, François Martinez-Escandell, Manuel Rodríguez Reinoso, Francisco Ramos-Fernández, Enrique V. Silvestre-Albero, Joaquín |
author_facet |
Casco, Mirian Elizabeth Rey, Fernando Jordá, José L. Rudić, Svemir Fauth, François Martinez-Escandell, Manuel Rodríguez Reinoso, Francisco Ramos-Fernández, Enrique V. Silvestre-Albero, Joaquín |
author_sort |
Casco, Mirian Elizabeth |
title |
Paving the way for methane hydrate formation on metal–organic frameworks (MOFs) |
title_short |
Paving the way for methane hydrate formation on metal–organic frameworks (MOFs) |
title_full |
Paving the way for methane hydrate formation on metal–organic frameworks (MOFs) |
title_fullStr |
Paving the way for methane hydrate formation on metal–organic frameworks (MOFs) |
title_full_unstemmed |
Paving the way for methane hydrate formation on metal–organic frameworks (MOFs) |
title_sort |
paving the way for methane hydrate formation on metal–organic frameworks (mofs) |
publisher |
Royal Society of Chemistry |
publishDate |
2016 |
url |
http://hdl.handle.net/10045/55368 https://doi.org/10.1039/C6SC00272B |
genre |
Methane hydrate |
genre_facet |
Methane hydrate |
op_relation |
http://dx.doi.org/10.1039/C6SC00272B info:eu-repo/grantAgreement/EC/FP7/283883 Chemical Science. 2016, 7: 3658-3666. doi:10.1039/C6SC00272B 2041-6520 (Print) 2041-6539 (Online) http://hdl.handle.net/10045/55368 doi:10.1039/C6SC00272B |
op_rights |
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence info:eu-repo/semantics/openAccess |
op_rightsnorm |
CC-BY |
op_doi |
https://doi.org/10.1039/C6SC00272B |
container_title |
Chemical Science |
container_volume |
7 |
container_issue |
6 |
container_start_page |
3658 |
op_container_end_page |
3666 |
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1766068385190248448 |