Monitoring of food spoilage by high resolution THz analysis
International audience High resolution rotational Terahertz (THz) spectroscopy has been widely applied to the studies of numerous polar gas phase molecules, in particular volatile organic compounds (VOCs). During the storage of foodstuffs packed under a protective atmosphere, microbial activity will...
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ftuniparissaclay:oai:HAL:hal-01891950v1 2024-05-19T07:37:47+00:00 Monitoring of food spoilage by high resolution THz analysis Hindle, Francis Kuuliala, Lotta Mouelhi, Meriem Cuisset, Arnaud Bray, Cédric Vanwolleghem, Mathias Devlieghere, Frank Mouret, Gael Bocquet, Robin Laboratoire de Physico-Chimie de l'Atmosphère (LPCA) Université du Littoral Côte d'Opale (ULCO) Laboratoire de Photophysique Moléculaire (PPM) Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS) Laboratoire de Dynamique Interactions et Réactivité (LADIR) Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 (IEMN) Centrale Lille-Institut supérieur de l'électronique et du numérique (ISEN)-Université de Valenciennes et du Hainaut-Cambrésis (UVHC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université Polytechnique Hauts-de-France (UPHF) Photonique THz - IEMN (PHOTONIQUE THZ - IEMN) Centrale Lille-Institut supérieur de l'électronique et du numérique (ISEN)-Université de Valenciennes et du Hainaut-Cambrésis (UVHC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université Polytechnique Hauts-de-France (UPHF)-Centrale Lille-Institut supérieur de l'électronique et du numérique (ISEN)-Université de Valenciennes et du Hainaut-Cambrésis (UVHC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université Polytechnique Hauts-de-France (UPHF) Food Safety and Food Quality Universiteit Gent = Ghent University (UGENT) 2018-11-21 https://hal.science/hal-01891950 https://hal.science/hal-01891950v1/document https://hal.science/hal-01891950v1/file/Monitoring%20of%20food%20spoilage%20by%20high%20resolution%20THz%20analysis%20v13.pdf https://doi.org/10.1039/C8AN01180J en eng HAL CCSD Royal Society of Chemistry info:eu-repo/semantics/altIdentifier/doi/10.1039/C8AN01180J hal-01891950 https://hal.science/hal-01891950 https://hal.science/hal-01891950v1/document https://hal.science/hal-01891950v1/file/Monitoring%20of%20food%20spoilage%20by%20high%20resolution%20THz%20analysis%20v13.pdf doi:10.1039/C8AN01180J info:eu-repo/semantics/OpenAccess ISSN: 0003-2654 EISSN: 1364-5528 Analyst https://hal.science/hal-01891950 Analyst, 2018, 143 (22), pp.5536-5544. ⟨10.1039/C8AN01180J⟩ [PHYS.PHYS.PHYS-INS-DET]Physics [physics]/Physics [physics]/Instrumentation and Detectors [physics.ins-det] [CHIM.ANAL]Chemical Sciences/Analytical chemistry info:eu-repo/semantics/article Journal articles 2018 ftuniparissaclay https://doi.org/10.1039/C8AN01180J 2024-04-30T03:20:43Z International audience High resolution rotational Terahertz (THz) spectroscopy has been widely applied to the studies of numerous polar gas phase molecules, in particular volatile organic compounds (VOCs). During the storage of foodstuffs packed under a protective atmosphere, microbial activity will lead to the generation of a complex mixture of trace gases that could be used as food spoilage indicators. Here we have demonstrated that the THz instrumentation presently available provides sufficient sensitivity and selectivity to monitor the generation of hydrogen sulfide (H2S) in the headspace of packed Atlantic salmon (Salmo salar) fillet portions. A comprehensive comparison was made by selective-ion flow-tube mass spectrometry (SIFT-MS) in order to validate the THz measurements and protocol. The detectivity of a range of alternative compounds for this application is also provided, based on the experimental detection limit observed and molecular spectroscopic properties. Molecules like ethanol, methyl mercaptan and ammonia are suitable indicators with the presently available sensitivity levels, while dimethyl sulfide, acetone and butanone may be considered with a sensitivity improvement of 2 orders of magnitude. Article in Journal/Newspaper Atlantic salmon Salmo salar Archives ouvertes de Paris-Saclay The Analyst 143 22 5536 5544 |
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Open Polar |
collection |
Archives ouvertes de Paris-Saclay |
op_collection_id |
ftuniparissaclay |
language |
English |
topic |
[PHYS.PHYS.PHYS-INS-DET]Physics [physics]/Physics [physics]/Instrumentation and Detectors [physics.ins-det] [CHIM.ANAL]Chemical Sciences/Analytical chemistry |
spellingShingle |
[PHYS.PHYS.PHYS-INS-DET]Physics [physics]/Physics [physics]/Instrumentation and Detectors [physics.ins-det] [CHIM.ANAL]Chemical Sciences/Analytical chemistry Hindle, Francis Kuuliala, Lotta Mouelhi, Meriem Cuisset, Arnaud Bray, Cédric Vanwolleghem, Mathias Devlieghere, Frank Mouret, Gael Bocquet, Robin Monitoring of food spoilage by high resolution THz analysis |
topic_facet |
[PHYS.PHYS.PHYS-INS-DET]Physics [physics]/Physics [physics]/Instrumentation and Detectors [physics.ins-det] [CHIM.ANAL]Chemical Sciences/Analytical chemistry |
description |
International audience High resolution rotational Terahertz (THz) spectroscopy has been widely applied to the studies of numerous polar gas phase molecules, in particular volatile organic compounds (VOCs). During the storage of foodstuffs packed under a protective atmosphere, microbial activity will lead to the generation of a complex mixture of trace gases that could be used as food spoilage indicators. Here we have demonstrated that the THz instrumentation presently available provides sufficient sensitivity and selectivity to monitor the generation of hydrogen sulfide (H2S) in the headspace of packed Atlantic salmon (Salmo salar) fillet portions. A comprehensive comparison was made by selective-ion flow-tube mass spectrometry (SIFT-MS) in order to validate the THz measurements and protocol. The detectivity of a range of alternative compounds for this application is also provided, based on the experimental detection limit observed and molecular spectroscopic properties. Molecules like ethanol, methyl mercaptan and ammonia are suitable indicators with the presently available sensitivity levels, while dimethyl sulfide, acetone and butanone may be considered with a sensitivity improvement of 2 orders of magnitude. |
author2 |
Laboratoire de Physico-Chimie de l'Atmosphère (LPCA) Université du Littoral Côte d'Opale (ULCO) Laboratoire de Photophysique Moléculaire (PPM) Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS) Laboratoire de Dynamique Interactions et Réactivité (LADIR) Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS) Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 (IEMN) Centrale Lille-Institut supérieur de l'électronique et du numérique (ISEN)-Université de Valenciennes et du Hainaut-Cambrésis (UVHC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université Polytechnique Hauts-de-France (UPHF) Photonique THz - IEMN (PHOTONIQUE THZ - IEMN) Centrale Lille-Institut supérieur de l'électronique et du numérique (ISEN)-Université de Valenciennes et du Hainaut-Cambrésis (UVHC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université Polytechnique Hauts-de-France (UPHF)-Centrale Lille-Institut supérieur de l'électronique et du numérique (ISEN)-Université de Valenciennes et du Hainaut-Cambrésis (UVHC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université Polytechnique Hauts-de-France (UPHF) Food Safety and Food Quality Universiteit Gent = Ghent University (UGENT) |
format |
Article in Journal/Newspaper |
author |
Hindle, Francis Kuuliala, Lotta Mouelhi, Meriem Cuisset, Arnaud Bray, Cédric Vanwolleghem, Mathias Devlieghere, Frank Mouret, Gael Bocquet, Robin |
author_facet |
Hindle, Francis Kuuliala, Lotta Mouelhi, Meriem Cuisset, Arnaud Bray, Cédric Vanwolleghem, Mathias Devlieghere, Frank Mouret, Gael Bocquet, Robin |
author_sort |
Hindle, Francis |
title |
Monitoring of food spoilage by high resolution THz analysis |
title_short |
Monitoring of food spoilage by high resolution THz analysis |
title_full |
Monitoring of food spoilage by high resolution THz analysis |
title_fullStr |
Monitoring of food spoilage by high resolution THz analysis |
title_full_unstemmed |
Monitoring of food spoilage by high resolution THz analysis |
title_sort |
monitoring of food spoilage by high resolution thz analysis |
publisher |
HAL CCSD |
publishDate |
2018 |
url |
https://hal.science/hal-01891950 https://hal.science/hal-01891950v1/document https://hal.science/hal-01891950v1/file/Monitoring%20of%20food%20spoilage%20by%20high%20resolution%20THz%20analysis%20v13.pdf https://doi.org/10.1039/C8AN01180J |
genre |
Atlantic salmon Salmo salar |
genre_facet |
Atlantic salmon Salmo salar |
op_source |
ISSN: 0003-2654 EISSN: 1364-5528 Analyst https://hal.science/hal-01891950 Analyst, 2018, 143 (22), pp.5536-5544. ⟨10.1039/C8AN01180J⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1039/C8AN01180J hal-01891950 https://hal.science/hal-01891950 https://hal.science/hal-01891950v1/document https://hal.science/hal-01891950v1/file/Monitoring%20of%20food%20spoilage%20by%20high%20resolution%20THz%20analysis%20v13.pdf doi:10.1039/C8AN01180J |
op_rights |
info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.1039/C8AN01180J |
container_title |
The Analyst |
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143 |
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22 |
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5536 |
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5544 |
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