Beryllium-7 and lead-210 in aerosol and snow in the dye 3 gas, aerosol and snow sampling program

• Published in: Atmospheric Environment. Part A. General Topics
• Main Authors: Dibb, Jack E., Jaffrezo, J L
• Format: Text
• Language: unknown
• Published: University of New Hampshire Scholars' Repository 1993
• Subjects: Greenland; arctic aerosol; arctic precipitation; 7Be; 210Pb; Atmospheric Sciences; Arctic; Dye 3; Dye-3; Ice Sheet
• Online Access: https://scholars.unh.edu/earthsci_facpub/63; https://doi.org/10.1016/0960-1686(93)90307-K

Concentrations of cosmogenic 7Be and the radon daughter 210Pb were determined in surface-level aerosols and fresh and aging snow throughout DGASP. The distinct sources, yet common association with submicron aerosols, of these atmospheric radionuclides makes them valuable tracers of the transport, depositional and post-depositional processes leading to incorporation of submicron aerosols (and associated species) into the Greenland Ice Sheet. The aerosol concentrations of atmospheric radionuclides tended to covary on the 1–7 day time scale of individual samples (r = 0.57, n = 114, p = 0.001) and were also highly correlated when averaged by month (r = 0.80, p = 0.002). The year-long time series of both 7Be and 210Pb showed concentration peaks in spring (April) and fall (September–October) and minima in summer (July) and winter (November–February). This finding is in stark contrast to results from other arctic sites, where both radionuclides, but particularly 210Pb, show pronounced concentration peaks in the winter. This indicates that the air masses over the Greenland Ice Sheet may be distinct from the air in the polar basin, or boundary layer processes strongly bias surface-level aerosol characteristics over the ice sheet, or, likely, some combination of these factors are operating. The concentrations of 7Be and 210Pb in fresh snow at Dye 3 show wide variability between snow fall events. The lack of any obvious correlation between concentrations in aerosol and fresh snow support the contention that surface-level air at this site is often not reflecting air aloft. Aging snow studies did not reveal consistent trends in concentration, suggesting important heterogeneity in the initial concentrations of 7Be and 210Pb in surface snow over small spatial scales. Poor agreement between the 210Pb profile in a 2 m snowpit sampled at the end of the project and the observed deposition of 210Pb through the year indicate the potential importance of post-depositional processes in modifying the atmospheric “signals” preserved in ...