Geochemical signatures of sediments documenting Arctic sea-ice and water mass export through Fram Strait since the Last Glacial Maximum

• Published in: Quaternary Science Reviews
• Main Authors: Maccali, Jenny, Hillaire-Marcel, Claude, Carignan, Jean, Reisberg, Laurie
• Other Authors: Centre de recherche sur la dynamique du système Terre (GEOTOP), École Polytechnique de Montréal (EPM)-McGill University = Université McGill Montréal, Canada -Université de Montréal (UdeM)-Université du Québec en Abitibi-Témiscamingue (UQAT)-Université du Québec à Rimouski (UQAR)-Concordia University Montreal -Université du Québec à Montréal = University of Québec in Montréal (UQAM), Centre de Recherches Pétrographiques et Géochimiques (CRPG), Institut national des sciences de l'Univers (INSU - CNRS)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS), Takuvik Joint International Laboratory ULAVAL-CNRS, Université Laval Québec (ULaval)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2013
• Subjects: Arctic Ocean; Marine geochemistry; Paleoceanography; [SDU.STU]Sciences of the Universe [physics]/Earth Sciences; Arctic; Fram Strait; Greenland; Sea ice
• Online Access: https://hal.univ-lorraine.fr/hal-01762149; https://doi.org/10.1016/j.quascirev.2012.10.029

International audience Elemental (Ca, Zr, Th, etc.) and radiogenic isotope (Pb, Nd, Sr) measurements in leachates and residues from deep-sea sediments of core MC16 (WarmPast Program) in central Fram Strait were used to document the geochemical signatures of outflowing Arctic water masses and ice rafted debris (IRD) since the Last Glacial Maximum. In addition, the elemental distribution among the three main sedimentary fractions (terrigenous, biogenic and authigenic) was quantified. Elements dominated by the terrigenous fraction display a change at ∼13 ka assigned to an early Younger Dryas (YD) event. In the authigenic fraction, migration of the redox front, perhaps spurred by discontinuous delivery of organic matter to the sediment, has led to the mobility of elements such as Mn. Fe contents display lesser variability within the sediment suggesting that Fe experienced only minor redox-related redistribution. Authigenic Pb and Nd, thought to be hosted primarily by Fe-oxyhydroxides, also show little evidence of mobility, suggesting that their isotopic compositions should reliably record the isotopic compositions of past bottom water.We have broadly identified the isotopic signatures of the three major source areas of IRD, the Russian, Canadian and Greenland margins. The elemental and isotopic residue records from core MC16 display distinct trends prior to and after the YD. The pre-YD interval, with ɛNd values between −10.1 and −13.2, and 87Sr/86Sr ratios from 0.715 to 0721, reflects a mixture of IRD from the Russian and Canadian margins. The YD episode stands out with sediments originating mostly from the Canadian end-member, displaying the lowest ɛNd values and highest 87Sr/86Sr ratios. This suggests enhanced sea-ice production and/or drifting along the Beaufort Gyre at that time. The post-YD interval, i.e. the Holocene, is characterized by a less variable mixture of IRD material, with ɛNd values and 87Sr/86Sr ratios centred at −12.2 and 0.718 respectively. This material was derived from several sources ...