High-accuracy 14 C measurements for atmospheric CO 2 samples by AMS

• Published in: Radiocarbon
• Main Authors: Meijer, H. A.J., Pertuisot, M. H., van der Plicht, J.
• Format: Article in Journal/Newspaper
• Language: English
• Published: 2006
• Subjects: Neumayer; Norway; South Pole; Antarc*; Antarctica; Barrow; Northern Norway; Point Barrow; South pole; Alaska
• Online Access: https://hdl.handle.net/11370/85ffaa1b-1a61-48c2-886b-b295ba117ae9; https://research.rug.nl/en/publications/85ffaa1b-1a61-48c2-886b-b295ba117ae9; https://doi.org/10.1017/S0033822200038807; https://pure.rug.nl/ws/files/870575812/high-accuracy-14c-measurements-for-atmospheric-co2-samples-by-ams.pdf; http://www.scopus.com/inward/record.url?scp=48249153695&partnerID=8YFLogxK

In this paper, we investigate how to achieve high-accuracy radiocarbon measurements by accelerator mass spectrometry (AMS) and present measurement series (performed on archived CO 2 ) of 14 CO 2 between 1985 and 1991 for Point Barrow (Alaska) and the South Pole. We report in detail the measurement plan, the error sources, and the calibration scheme that enabled us to reach a combined uncertainty of better than ±3‰. The Δ 13 C correction and a suggestion for a span (or 2-point) calibration for the 14 C scale are discussed in detail. In addition, we report new, accurate values for the calibration and reference materials Ox2 and IAEA-C6 with respect to Ox1. The atmospheric 14 CO 2 records (1985-1991) are presented as well and are compared with other existing records for that period. The Point Barrow record agrees very well with the existing Fruholmen (northern Norway) record from the same latitude. The South Pole record shows a small seasonal cycle but with an extreme phase with a maximum on January 1st (±13 days). Together with its generally elevated 14 C level compared to the Neumayer record (coastal Antarctica), this makes our South Pole data set a valuable additional source of information for global carbon cycle modeling using 14 CO 2 as a constraint.