A biocatalytic approach towards sustainable furanic-aliphatic polyesters
An eco-friendly approach towards furanic-aliphatic polyesters as sustainable alternatives to aromatic-aliphatic polyesters is presented. In this approach, biobased dimethyl 2,5-furandicarboxylate (DMFDCA) is polymerized with various (potentially) renewable aliphatic diols via Candida antarctica Lipa...
Published in: | Polymer Chemistry |
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Language: | English |
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2015
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Online Access: | https://hdl.handle.net/11370/81af2cbf-3313-46ca-ad84-0d21d099b6f9 https://research.rug.nl/en/publications/81af2cbf-3313-46ca-ad84-0d21d099b6f9 https://doi.org/10.1039/c5py00629e https://pure.rug.nl/ws/files/82943060/A_biocatalytic_approach_towards_sustainable_furanic_aliphatic_polyesters.pdf |
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ftunigroningenpu:oai:pure.rug.nl:publications/81af2cbf-3313-46ca-ad84-0d21d099b6f9 2024-09-15T17:45:50+00:00 A biocatalytic approach towards sustainable furanic-aliphatic polyesters Jiang, Yi Woortman, Albert J. J. van Ekenstein, Gert O. R. Alberda Loos, Katja 2015 application/pdf https://hdl.handle.net/11370/81af2cbf-3313-46ca-ad84-0d21d099b6f9 https://research.rug.nl/en/publications/81af2cbf-3313-46ca-ad84-0d21d099b6f9 https://doi.org/10.1039/c5py00629e https://pure.rug.nl/ws/files/82943060/A_biocatalytic_approach_towards_sustainable_furanic_aliphatic_polyesters.pdf eng eng https://research.rug.nl/en/publications/81af2cbf-3313-46ca-ad84-0d21d099b6f9 info:eu-repo/semantics/openAccess Jiang , Y , Woortman , A J J , van Ekenstein , G O R A & Loos , K 2015 , ' A biocatalytic approach towards sustainable furanic-aliphatic polyesters ' , Polymer Chemistry , vol. 6 , no. 29 , pp. 5198-5211 . https://doi.org/10.1039/c5py00629e ANTARCTICA LIPASE B GLYCOL DIMETHACRYLATE) RESINS RENEWABLE RESOURCES CATALYZED SYNTHESIS ENZYME IMMOBILIZATION BIOBASED POLYESTERS AROMATIC POLYESTERS POLYMERIC MATERIALS BUILDING-BLOCK IONIC LIQUIDS article 2015 ftunigroningenpu https://doi.org/10.1039/c5py00629e 2024-06-24T15:49:09Z An eco-friendly approach towards furanic-aliphatic polyesters as sustainable alternatives to aromatic-aliphatic polyesters is presented. In this approach, biobased dimethyl 2,5-furandicarboxylate (DMFDCA) is polymerized with various (potentially) renewable aliphatic diols via Candida antarctica Lipase B (CALB)-catalyzed polymerization using a two-stage method in diphenyl ether. A series of furanic-aliphatic polyesters and oligoesters is successfully produced via enzymatic polymerization. Some products reach very high (M-w) over bar (weight average molecular weight) values of around 100 000 g mol(-1). Studies on the effect of the diol structure on the enzymatic polymerization indicate that CALB prefers long-chain alkane-alpha,omega-aliphatic linear diols containing more than 3 carbons. We also found that the molecular weights of the obtained furanic-aliphatic polyesters increase steadily with the increase of reaction temperature from 80 to 140 degrees C. MALDI-ToF MS analysis reveals that five polyester species may be present in the final products. They were terminated with the ester/-OH, ester/ester, -OH/-OH, no end groups (cyclic), and ester/aldehyde groups, respectively. Furthermore, the structure-property relationships were studied by comparing the crystalline/thermal properties of a series of relevant furanic-aliphatic polyesters. Article in Journal/Newspaper Antarc* Antarctica University of Groningen research database Polymer Chemistry 6 29 5198 5211 |
institution |
Open Polar |
collection |
University of Groningen research database |
op_collection_id |
ftunigroningenpu |
language |
English |
topic |
ANTARCTICA LIPASE B GLYCOL DIMETHACRYLATE) RESINS RENEWABLE RESOURCES CATALYZED SYNTHESIS ENZYME IMMOBILIZATION BIOBASED POLYESTERS AROMATIC POLYESTERS POLYMERIC MATERIALS BUILDING-BLOCK IONIC LIQUIDS |
spellingShingle |
ANTARCTICA LIPASE B GLYCOL DIMETHACRYLATE) RESINS RENEWABLE RESOURCES CATALYZED SYNTHESIS ENZYME IMMOBILIZATION BIOBASED POLYESTERS AROMATIC POLYESTERS POLYMERIC MATERIALS BUILDING-BLOCK IONIC LIQUIDS Jiang, Yi Woortman, Albert J. J. van Ekenstein, Gert O. R. Alberda Loos, Katja A biocatalytic approach towards sustainable furanic-aliphatic polyesters |
topic_facet |
ANTARCTICA LIPASE B GLYCOL DIMETHACRYLATE) RESINS RENEWABLE RESOURCES CATALYZED SYNTHESIS ENZYME IMMOBILIZATION BIOBASED POLYESTERS AROMATIC POLYESTERS POLYMERIC MATERIALS BUILDING-BLOCK IONIC LIQUIDS |
description |
An eco-friendly approach towards furanic-aliphatic polyesters as sustainable alternatives to aromatic-aliphatic polyesters is presented. In this approach, biobased dimethyl 2,5-furandicarboxylate (DMFDCA) is polymerized with various (potentially) renewable aliphatic diols via Candida antarctica Lipase B (CALB)-catalyzed polymerization using a two-stage method in diphenyl ether. A series of furanic-aliphatic polyesters and oligoesters is successfully produced via enzymatic polymerization. Some products reach very high (M-w) over bar (weight average molecular weight) values of around 100 000 g mol(-1). Studies on the effect of the diol structure on the enzymatic polymerization indicate that CALB prefers long-chain alkane-alpha,omega-aliphatic linear diols containing more than 3 carbons. We also found that the molecular weights of the obtained furanic-aliphatic polyesters increase steadily with the increase of reaction temperature from 80 to 140 degrees C. MALDI-ToF MS analysis reveals that five polyester species may be present in the final products. They were terminated with the ester/-OH, ester/ester, -OH/-OH, no end groups (cyclic), and ester/aldehyde groups, respectively. Furthermore, the structure-property relationships were studied by comparing the crystalline/thermal properties of a series of relevant furanic-aliphatic polyesters. |
format |
Article in Journal/Newspaper |
author |
Jiang, Yi Woortman, Albert J. J. van Ekenstein, Gert O. R. Alberda Loos, Katja |
author_facet |
Jiang, Yi Woortman, Albert J. J. van Ekenstein, Gert O. R. Alberda Loos, Katja |
author_sort |
Jiang, Yi |
title |
A biocatalytic approach towards sustainable furanic-aliphatic polyesters |
title_short |
A biocatalytic approach towards sustainable furanic-aliphatic polyesters |
title_full |
A biocatalytic approach towards sustainable furanic-aliphatic polyesters |
title_fullStr |
A biocatalytic approach towards sustainable furanic-aliphatic polyesters |
title_full_unstemmed |
A biocatalytic approach towards sustainable furanic-aliphatic polyesters |
title_sort |
biocatalytic approach towards sustainable furanic-aliphatic polyesters |
publishDate |
2015 |
url |
https://hdl.handle.net/11370/81af2cbf-3313-46ca-ad84-0d21d099b6f9 https://research.rug.nl/en/publications/81af2cbf-3313-46ca-ad84-0d21d099b6f9 https://doi.org/10.1039/c5py00629e https://pure.rug.nl/ws/files/82943060/A_biocatalytic_approach_towards_sustainable_furanic_aliphatic_polyesters.pdf |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
Jiang , Y , Woortman , A J J , van Ekenstein , G O R A & Loos , K 2015 , ' A biocatalytic approach towards sustainable furanic-aliphatic polyesters ' , Polymer Chemistry , vol. 6 , no. 29 , pp. 5198-5211 . https://doi.org/10.1039/c5py00629e |
op_relation |
https://research.rug.nl/en/publications/81af2cbf-3313-46ca-ad84-0d21d099b6f9 |
op_rights |
info:eu-repo/semantics/openAccess |
op_doi |
https://doi.org/10.1039/c5py00629e |
container_title |
Polymer Chemistry |
container_volume |
6 |
container_issue |
29 |
container_start_page |
5198 |
op_container_end_page |
5211 |
_version_ |
1810493749268054016 |