Simultaneous Determination of the 2H/1H, 17O/16O, and 18O/16O Isotope Abundance Ratios in Water by Means of Laser Spectrometry
We demonstrate the first successful application of infrared laser spectrometry to the accurate, simultaneous determination of the relative H-2/H-1, O-17/O-16, and O-18/O-16 isotope abundance ratios in water. The method uses a narrow Line width color center laser to record the direct absorption spect...
Published in: | Analytical Chemistry |
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Main Authors: | , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
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1999
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Online Access: | https://hdl.handle.net/11370/7d521457-d577-4369-9d3e-b014903523de https://research.rug.nl/en/publications/7d521457-d577-4369-9d3e-b014903523de https://doi.org/10.1021/ac990621e https://pure.rug.nl/ws/files/3166273/1999AnalChemKerstel.pdf |
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ftunigroningenpu:oai:pure.rug.nl:publications/7d521457-d577-4369-9d3e-b014903523de 2024-06-23T07:46:03+00:00 Simultaneous Determination of the 2H/1H, 17O/16O, and 18O/16O Isotope Abundance Ratios in Water by Means of Laser Spectrometry Kerstel, E.R.Th. Trigt, R. van Dam, N.J. Reuss, J. Meijer, H.A.J. 1999-12-01 application/pdf https://hdl.handle.net/11370/7d521457-d577-4369-9d3e-b014903523de https://research.rug.nl/en/publications/7d521457-d577-4369-9d3e-b014903523de https://doi.org/10.1021/ac990621e https://pure.rug.nl/ws/files/3166273/1999AnalChemKerstel.pdf eng eng https://research.rug.nl/en/publications/7d521457-d577-4369-9d3e-b014903523de info:eu-repo/semantics/openAccess Kerstel , E R T , Trigt , R V , Dam , N J , Reuss , J & Meijer , H A J 1999 , ' Simultaneous Determination of the 2H/1H, 17O/16O, and 18O/16O Isotope Abundance Ratios in Water by Means of Laser Spectrometry ' , Analytical Chemistry , vol. 71 , no. 23 , pp. 5297-5303 . https://doi.org/10.1021/ac990621e ATMOSPHERIC CARBON-DIOXIDE ICE CORE ABSORPTION SPECTROMETER MASS-SPECTROMETRY DEUTERIUM EXCESS METHANE TEMPERATURE PROFILES SNOW article 1999 ftunigroningenpu https://doi.org/10.1021/ac990621e 2024-06-03T16:08:16Z We demonstrate the first successful application of infrared laser spectrometry to the accurate, simultaneous determination of the relative H-2/H-1, O-17/O-16, and O-18/O-16 isotope abundance ratios in water. The method uses a narrow Line width color center laser to record the direct absorption spectrum of low-pressure gas-phase water samples (presently 10 mu L of liquid) in the 3-mu m spectral region. It thus avoids the laborious chemical preparations of the sample that are required in the case of the conventional isotope ratio mass spectrometer measurement. The precision of the spectroscopic technique is shown to be 0.7 parts per thousand for delta(2)H and 0.5 parts per thousand for delta(17)O and delta(18)O (delta represents the relative deviation of a sample's isotope abundance ratio with respect to that of a calibration material), while the calibrated accuracy amounts to about 3 and 1 parts per thousand, respectively, for water with an isotopic composition in the range of the Standard Light Antarctic Precipitation and Vienna Standard Mean Ocean Water international standards. Article in Journal/Newspaper Antarc* Antarctic ice core University of Groningen research database Antarctic Analytical Chemistry 71 23 5297 5303 |
institution |
Open Polar |
collection |
University of Groningen research database |
op_collection_id |
ftunigroningenpu |
language |
English |
topic |
ATMOSPHERIC CARBON-DIOXIDE ICE CORE ABSORPTION SPECTROMETER MASS-SPECTROMETRY DEUTERIUM EXCESS METHANE TEMPERATURE PROFILES SNOW |
spellingShingle |
ATMOSPHERIC CARBON-DIOXIDE ICE CORE ABSORPTION SPECTROMETER MASS-SPECTROMETRY DEUTERIUM EXCESS METHANE TEMPERATURE PROFILES SNOW Kerstel, E.R.Th. Trigt, R. van Dam, N.J. Reuss, J. Meijer, H.A.J. Simultaneous Determination of the 2H/1H, 17O/16O, and 18O/16O Isotope Abundance Ratios in Water by Means of Laser Spectrometry |
topic_facet |
ATMOSPHERIC CARBON-DIOXIDE ICE CORE ABSORPTION SPECTROMETER MASS-SPECTROMETRY DEUTERIUM EXCESS METHANE TEMPERATURE PROFILES SNOW |
description |
We demonstrate the first successful application of infrared laser spectrometry to the accurate, simultaneous determination of the relative H-2/H-1, O-17/O-16, and O-18/O-16 isotope abundance ratios in water. The method uses a narrow Line width color center laser to record the direct absorption spectrum of low-pressure gas-phase water samples (presently 10 mu L of liquid) in the 3-mu m spectral region. It thus avoids the laborious chemical preparations of the sample that are required in the case of the conventional isotope ratio mass spectrometer measurement. The precision of the spectroscopic technique is shown to be 0.7 parts per thousand for delta(2)H and 0.5 parts per thousand for delta(17)O and delta(18)O (delta represents the relative deviation of a sample's isotope abundance ratio with respect to that of a calibration material), while the calibrated accuracy amounts to about 3 and 1 parts per thousand, respectively, for water with an isotopic composition in the range of the Standard Light Antarctic Precipitation and Vienna Standard Mean Ocean Water international standards. |
format |
Article in Journal/Newspaper |
author |
Kerstel, E.R.Th. Trigt, R. van Dam, N.J. Reuss, J. Meijer, H.A.J. |
author_facet |
Kerstel, E.R.Th. Trigt, R. van Dam, N.J. Reuss, J. Meijer, H.A.J. |
author_sort |
Kerstel, E.R.Th. |
title |
Simultaneous Determination of the 2H/1H, 17O/16O, and 18O/16O Isotope Abundance Ratios in Water by Means of Laser Spectrometry |
title_short |
Simultaneous Determination of the 2H/1H, 17O/16O, and 18O/16O Isotope Abundance Ratios in Water by Means of Laser Spectrometry |
title_full |
Simultaneous Determination of the 2H/1H, 17O/16O, and 18O/16O Isotope Abundance Ratios in Water by Means of Laser Spectrometry |
title_fullStr |
Simultaneous Determination of the 2H/1H, 17O/16O, and 18O/16O Isotope Abundance Ratios in Water by Means of Laser Spectrometry |
title_full_unstemmed |
Simultaneous Determination of the 2H/1H, 17O/16O, and 18O/16O Isotope Abundance Ratios in Water by Means of Laser Spectrometry |
title_sort |
simultaneous determination of the 2h/1h, 17o/16o, and 18o/16o isotope abundance ratios in water by means of laser spectrometry |
publishDate |
1999 |
url |
https://hdl.handle.net/11370/7d521457-d577-4369-9d3e-b014903523de https://research.rug.nl/en/publications/7d521457-d577-4369-9d3e-b014903523de https://doi.org/10.1021/ac990621e https://pure.rug.nl/ws/files/3166273/1999AnalChemKerstel.pdf |
geographic |
Antarctic |
geographic_facet |
Antarctic |
genre |
Antarc* Antarctic ice core |
genre_facet |
Antarc* Antarctic ice core |
op_source |
Kerstel , E R T , Trigt , R V , Dam , N J , Reuss , J & Meijer , H A J 1999 , ' Simultaneous Determination of the 2H/1H, 17O/16O, and 18O/16O Isotope Abundance Ratios in Water by Means of Laser Spectrometry ' , Analytical Chemistry , vol. 71 , no. 23 , pp. 5297-5303 . https://doi.org/10.1021/ac990621e |
op_relation |
https://research.rug.nl/en/publications/7d521457-d577-4369-9d3e-b014903523de |
op_rights |
info:eu-repo/semantics/openAccess |
op_doi |
https://doi.org/10.1021/ac990621e |
container_title |
Analytical Chemistry |
container_volume |
71 |
container_issue |
23 |
container_start_page |
5297 |
op_container_end_page |
5303 |
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1802643714081816576 |